[CPMD-list] Full response version of TDDFT

Juerg Hutter hutter at pci.uzh.ch
Wed Jan 23 14:06:03 CET 2008


Hi

I'm sorry but I can't remember if the number in the
output is scaled by the volume.
However, that can easily be chacked by calculating
a molecule with different box sizes.

regards

Juerg Hutter

----------------------------------------------------------
Juerg Hutter                   Phone : ++41 44 635 4491
Physical Chemistry Institute   FAX   : ++41 44 635 6838
University of Zurich           E-mail: hutter at pci.uzh.ch
Winterthurerstrasse 190
CH-8057 Zurich, Switzerland
----------------------------------------------------------


On Fri, 18 Jan 2008, Emiliano Ippoliti wrote:

> Thanks for your reply.
>
> Regarding the oscillator strength f which I obtain with a Tamm-Dancoff
> calculation, is the same as in
>
> B = (4 pi^2 e^2 f)/(m h v c)      (1)
> (with obvious notation)
>
> to calculate experimental Einstein absorption coefficient B?
>
> Or does it depend on some computational features, such as volume cell for
> example, and in this case I should accordingly correct it to get the value
> to insert in (1)?
>
> Regards,
> Emiliano
>
> On Wed, 16 Jan 2008, Juerg Hutter wrote:
>
>> Hi
>>
>> oscillator strength with the full LR TDDFT has never been
>> implemented in CPMD.
>> The implementation for the Tamm-Dancoff approximation
>> for periodic system (works also for non-periodic) can be found
>> in the paper by Bernasconi and Sprik.
>>
>> regards
>>
>> Juerg Hutter
>>
>> ----------------------------------------------------------
>> Juerg Hutter                   Phone : ++41 44 635 4491
>> Physical Chemistry Institute   FAX   : ++41 44 635 6838
>> University of Zurich           E-mail: hutter at pci.uzh.ch
>> Winterthurerstrasse 190
>> CH-8057 Zurich, Switzerland
>> ----------------------------------------------------------
>>
>>
>> On Wed, 16 Jan 2008, Emiliano Ippoliti wrote:
>>
>>> Dear CPMD users,
>>>
>>> I'm using the TDDFT routines implemented in the last version of CPMD to
>>> calculate electronic excitation energies in QM/MM simulations. Recently I
>>> have tried to use the keyword LR-TDDFT to perform the "exact" calculation
>>> without the Tamm-Dancoff approximation.
>>> What I don't understand is the fact that in the output file I cannot find
>>> the oscillator strength (the "f") together with the value of the excitation
>>> energies. What is the reason? How can I have a measure of the intensity of
>>> excitation transitions? How is calculate the oscillator strength in the
>>> default setup with the Tamm-Dancoff approximation?
>>> Below, I report an example of output file.
>>>
>>> Best regards,
>>> Emiliano
>>>
>>>
>>> ...
>>>
>>>
>>> ****************************************************************************
>>> **
>>> **                              INPUT FILE
>>> **
>>>
>>> ****************************************************************************
>>> **
>>> ** &QMMM
>>> **
>>> ** TOPOLOGY
>>> **
>>> ** gromos.top
>>> **
>>> ** COORDINATES
>>> **
>>> ** gromos.g96
>>> **
>>> ** INPUT
>>> **
>>> ** gromos.inp
>>> **
>>> ** ELECTROSTATIC COUPLING LONG RANGE
>>> **
>>> ** RCUT_NN
>>> **
>>> ** 10
>>> **
>>> ** RCUT_MIX
>>> **
>>> ** 15
>>> **
>>> ** RCUT_ESP
>>> **
>>> ** 20
>>> **
>>> ** UPDATE LIST
>>> **
>>> ** 100
>>> **
>>> ** SPLIT
>>> **
>>> ** SAMPLE_INTERACTING
>>> **
>>> ** 1000
>>> **
>>> ** AMBER
>>> **
>>> ** ARRAYSIZES
>>> **
>>> **
>>> **
>>> **  MAXATT 17
>>> **
>>> **  MAXAA2 11
>>> **
>>> **  MAXNRP 26
>>> **
>>> **  MAXNBT 21
>>> **
>>> **  MAXBNH 17
>>> **
>>> **  MAXBON 20
>>> **
>>> **  MAXTTY 23
>>> **
>>> **  MXQHEH 24
>>> **
>>> **  MAXTH  23
>>> **
>>> **  MAXQTY 10
>>> **
>>> **  MAXHIH 10
>>> **
>>> **  MAXQHI 10
>>> **
>>> **  MAXPTY 15
>>> **
>>> **  MXPHIH 38
>>> **
>>> **  MAXPHI 27
>>> **
>>> **  MAXCAG 16
>>> **
>>> **  MAXAEX 20044
>>> **
>>> **  MXEX14 42
>>> **
>>> **
>>> **
>>> ** END ARRAYSIZES
>>> **
>>> ** &END
>>> **
>>> **
>>> **
>>> ** &CPMD
>>> **
>>> **  RESTART WAVEFUNCTION COORDINATES
>>> **
>>> **  QMMM
>>> **
>>> **  ELECTRONIC SPECTRA
>>> **
>>> **  LANCZOS DIAGONALIZATION
>>> **
>>> **  LANCZOS PARAMETER
>>> **
>>> **   3000 8 0 1E-6
>>> **
>>> **  MAXSTEP
>>> **
>>> **   999999
>>> **
>>> **  COMPRESS WRITE32
>>> **
>>> **  MIRROR
>>> **
>>> **  RESTFILE
>>> **
>>> **   3
>>> **
>>> ** &END
>>> **
>>> **
>>> **
>>> ** &TDDFT
>>> **
>>> **  STATES SINGLET
>>> **
>>> **   5
>>> **
>>> **  tAMM-DANCOFF
>>> **
>>> **  LR-TDDFT
>>> **
>>> **  DAVIDSON PARAMETER
>>> **
>>> **   200 1.D-7 69
>>> **
>>> ** &END
>>> **
>>> **
>>> **
>>> ** &SYSTEM
>>> **
>>> **  POISSON SOLVER TUCKERMAN
>>> **
>>> **  SYMMETRY
>>> **
>>> **   0
>>> **
>>> **  CELL
>>> **
>>> **   22.282343   .9144899  1.0576992  0  0  0
>>> **
>>> **  CUTOFF
>>> **
>>> **   70.
>>> **
>>> **  CHARGE
>>> **
>>> **   0.0
>>> **
>>> ** &END
>>> **
>>> **
>>> **
>>> ** &ATOMS
>>> **
>>> **
>>> **
>>> ** *H_MT_PBE.psp KLEINMAN-BYLANDER
>>> **
>>> **    LMAX=P
>>> **
>>> **      7
>>> **
>>> ** 2   4   6   9  11  13  15
>>> **
>>> **
>>> **
>>> ** *N_MT_PBE.psp KLEINMAN-BYLANDER
>>> **
>>> **    LMAX=D
>>> **
>>> **      1
>>> **
>>> ** 5
>>> **
>>> **
>>> **
>>> ** *C_MT_PBE.psp KLEINMAN-BYLANDER
>>> **
>>> **    LMAX=D
>>> **
>>> **      8
>>> **
>>> ** 1   3   7   8  10  12  14  16
>>> **
>>> **
>>> **
>>> ** &END
>>> **
>>> **
>>> **
>>> ** &DFT
>>> **
>>> **   FUNCTIONAL PBE
>>> **
>>> **   GC-CUTOFF
>>> **
>>> **   1.0E-06
>>> **
>>> ** &END
>>> **
>>>
>>> ****************************************************************************
>>> **
>>>
>>> ****************************************************************************
>>> **
>>>
>>> CALCULATE ELECTRONIC SPECTRA
>>> PATH TO THE RESTART FILES:                                    ./
>>> RESTART WITH OLD ORBITALS
>>> RESTART WITH OLD ION POSITIONS
>>> GRAM-SCHMIDT ORTHOGONALIZATION
>>> MAXIMUM NUMBER OF STEPS:                            999999 STEPS
>>> WRITE WAVEFUNCTIONS IN COMPRESSED FORM TO FILE
>>>   COMPRESSION FACTOR IS   2
>>> PRINT INTERMEDIATE RESULTS EVERY                   1000000 STEPS
>>> STORE INTERMEDIATE RESULTS EVERY                   1000000 STEPS
>>> NUMBER OF DISTINCT RESTART FILES:                              3
>>> TEMPERATURE IS CALCULATED ASSUMING EXTENDED BULK BEHAVIOR
>>> FICTITIOUS ELECTRON MASS:                               400.0000
>>> TIME STEP FOR ELECTRONS:                                  5.0000
>>> TIME STEP FOR IONS:                                       5.0000
>>> CONVERGENCE CRITERIA FOR WAVEFUNCTION OPTIMIZATION:   1.0000E-05
>>> WAVEFUNCTION OPTIMIZATION BY PRECONDITIONED DIIS
>>> THRESHOLD FOR THE WF-HESSIAN IS                            .5000
>>> MAXIMUM NUMBER OF VECTORS RETAINED FOR DIIS:                  10
>>> STEPS UNTIL DIIS RESET ON POOR PROGRESS:                      10
>>> FULL ELECTRONIC GRADIENT IS USED
>>> SPLINE INTERPOLATION IN G-SPACE FOR PSEUDOPOTENTIAL FUNCTIONS
>>>    NUMBER OF SPLINE POINTS:                                 5000
>>>
>>> EXCHANGE CORRELATION FUNCTIONALS
>>>    LDA EXCHANGE:                                            NONE
>>>    LDA XC THROUGH PADE APPROXIMATION
>>>    S.GOEDECKER, J.HUTTER, M.TETER PRB 54 1703 (1996)
>>>    GRADIENT CORRECTED FUNCTIONAL
>>>    DENSITY THRESHOLD:                                1.00000E-06
>>>    EXCHANGE ENERGY
>>>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>>>    CORRELATION ENERGY
>>>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>>>
>>>  WARNING: ISOLATED CLUSTER OPTION NEEDED IN QMMM
>>>           NOW TCLUST WILL BE SET TO .TRUE.
>>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>>>  qmmm by Alessandro Laio,
>>>  qmmm    Joost VandeVondele, and
>>>  qmmm    Ursula Rothlisberger
>>>  qmmm
>>>  qmmm Revised DYNA version:
>>>  qmmm                    Tsukuba, 20 November 2005
>>>  qmmm        Bochum/Philadelphia, 27 November 2005
>>>  qmmm (Rewritten and vectorized for ES & Co.)
>>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>>>  qmmm
>>>  qmmm GROMOS TOPOLOGY FILE    : gromos.top
>>>  qmmm GROMOS COORDINATES FILE : gromos.g96
>>>  qmmm GROMOS INPUT FILE       : gromos.inp
>>>  qmmm
>>>  qmmm USING AMBER FUNCTIONAL FORM
>>>  qmmm
>>>  qmmm QM AND MM TASKS PERFORMED IN THE SAME GROUP
>>>  qmmm
>>>  qmmm ELECTROSTATIC COUPLING WITH THE NN ATOMS
>>>  qmmm MULTIPOLE COUPLING WITH THE FAR MM ATOMS
>>>  qmmm
>>>  qmmm CUTOFFS FOR THE ELECTROSTATIC COUPLING [A.U.]:
>>>  qmmm {RCUT_NN}  RCUT_NN  =   10.00
>>>  qmmm {RCUT_MIX} RCUT_MIX =   15.00
>>>  qmmm {RCUT_ESP} RCUT_ESP =   20.00
>>>  qmmm
>>>  qmmm {UPDATE LIST} NN LIST UPDATED EVERY    100 STEPS
>>>  qmmm {MAXNN} MAXIMUM NUMBER OF NN ATOMS   5000
>>>  qmmm {ESPWEIGHT} WEIGHT FOR THE ESP FIT =      .1000
>>>  qmmm {SAMPLE INTERACTING} DATA SAVED EVERY   1000 STEPS
>>>  qmmm
>>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>>>
>>> ***     DETSP| SIZE OF THE PROGRAM IS  7640 KBytes ***
>>> ***ALLOC_GROM| SIZE OF THE PROGRAM IS  7800 KBytes ***
>>> promd.f,v 1.55 1996/11/25 14:49:50 wscott Exp
>>> Present revision: Tsukuba, 13 July 2005
>>>
>>> PROGRAM PROMD PERFORMS EITHER
>>>   AN ENERGY MINIMISATION,
>>>   A MOLECULAR DYNAMICS RUN,
>>>   OR A STOCHASTIC DYNAMICS RUN
>>> IN THREE OR FOUR DIMENSIONS FOR A NUMBER OF SOLUTE
>>> (PROTEIN) MOLECULES PLUS SOLVENT MOLECULES, USING:
>>>
>>>  A: SPECIFICATION DATA
>>> -----------------------
>>>  1. A MOLECULAR TOPOLOGY FILE
>>>  2. DATA CHARACTERIZING THE RUN
>>>  3. DATA DETERMINING THE FREE ENERGY PERTURBATION (IF NTG>0)
>>>  4. RE(CON)STRAINED ATOM SEQUENCE NUMBERS (IF NTR>0)
>>>  5. DISTANCE RESTRAINT ATOM PAIRS (IF NTDR>0)
>>>  6. RESTRAINED DIHEDRALS (IF NTDLR>0)
>>>  7. J-VALUE RESTRAINING DIHEDRALS (IF NTJR >0)
>>>  8. LOCAL ELEVATION DIHEDRALS (IF NTLE > 0)
>>>  9. 4th DIMENSION ATOM INDICATORS (IF NT4DIM >0)
>>>
>>>  B: STARTUP DATA
>>> -----------------
>>> 10. INITIAL ATOMIC COORDINATES AND VELOCITIES
>>> 11. ATOMIC FRICTION COEFFICIENTS (IF NTFR=2)
>>> 12. REFERENCE ATOM COORDINATES FOR RE(CON)STRAINING (IF NTR>0)
>>>
>>>
>>>
>>> 1. M O L E C U L A R   T O P O L O G Y
>>>
>>> TOPOLOGY TITLE
>>> IND
>>>
>>>
>>>
>>> 2. D A T A   C H A R A C T E R I Z I N G   T H E   RUN
>>>
>>> TITLE
>>>  Input generated by QMMM interface
>>>
>>> SYSTEM
>>>       NPM       NSM
>>>         1      1376
>>> START
>>>       NTX      INIT        IG     TEMPI      HEAT NTXO       BOLTZ
>>>         1         1    210185   300.000      .000    1  .83144E-02
>>>    INITIAL COORDINATES ARE READ FROM FILE
>>>    INITIAL VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>>>       WITH TEMPERATURE TEMPI
>>>    INITIAL COORDINATES ARE SHAKEN
>>>    INITIAL VELOCITIES ARE SHAKEN
>>>    FORMATTED OUTPUT OF:
>>>       FINAL COORDINATES AND VELOCITIES
>>>    BOLTZ VALUE IS IN KJ/MOL
>>>
>>> STEP
>>>    NSTLIM         T        DT
>>>        10    .00000    .00200
>>>
>>> BOUNDARY
>>>       NTB    BOX(1)    BOX(2)    BOX(3)      BETA    NRDBOX
>>>         0  3.368147  3.510064  3.559402    90.000         0
>>>    NO PERIODICITY IS APPLIED
>>>
>>> SUBMOLECULES
>>>      NSPM
>>>         1
>>>        NSP(1..NSPM)
>>>        16
>>>
>>> TCOUPLE
>>>       NTT     TEMP0      TAUT
>>>         0   300.000      .100
>>>         0   300.000      .100
>>>         0   300.000      .100
>>>
>>>    NO PRESSURE COUPLING
>>>
>>> CENTREOFMASS
>>>    NDFMIN      NTCM      NSCM
>>>         0         0   1000000
>>>    INITIAL C.O.M. MOTION IS NOT REMOVED
>>>
>>> PRINT
>>>      NTPR      NTPL      NTPP
>>>        20       100         0
>>>    NO DIHEDRAL ANGLE MONITORING
>>>
>>> SHAKE
>>>       NTC       TOL
>>>         1 .1000E-03
>>>    NO SHAKE IS PERFORMED
>>>
>>> FORCE
>>>          NTF(1..10)
>>>     BONDS  BND-ANGL  IMP-DIHE  DIHEDRAL   NONBOND
>>>     H         H         H         H       CHG ALL
>>>     1   1     1   1     1   1     1   1     1   1
>>>      NEGR        NRE(1..NEGR)
>>>         2        16      4144
>>>    FORCE CALCULATION
>>>    INCLUDES         BOND FORCES INVOLVING H-ATOMS
>>>    INCLUDES         BOND FORCES NOT INVOLVING H-ATOMS
>>>    INCLUDES         BOND ANGLE FORCES INVOLVING H-ATOMS
>>>    INCLUDES         BOND ANGLE FORCES NOT INVOLVING H-ATOMS
>>>    INCLUDES         IMPROPER DIHEDRAL FORCES INVOLVING H-ATOMS
>>>    INCLUDES         IMPROPER DIHEDRAL FORCES NOT INVOLVING H-ATOMS
>>>    INCLUDES         DIHEDRAL ANGLE FORCES INVOLVING H-ATOMS
>>>    INCLUDES         DIHEDRAL ANGLE FORCES NOT INVOLVING H-ATOMS
>>>    INCLUDES         CHARGES IN NON-BONDED INTERACTION
>>>    INCLUDES         NON-BONDED INTERACTION
>>>
>>> PLIST
>>>      NTNB      NSNB     RCUTP     RCUTL
>>>         1        10     1.000     1.000
>>>    A PAIRLIST IS CONSTRUCTED IN THE FIRST STEP
>>>    NO LONGRANGE CONTRIBUTION IS CALCULATED ON PL CONSTRUCTION
>>>
>>> LONGRANGE
>>>     EPSRF     APPAK      RCRF
>>>    50.000      .000  .700E+10
>>>    A REACTION FIELD CORRECTION IS APPLIED
>>>
>>> POSREST
>>>       NTR       CHO     NRDRX
>>>         0 .2500E+05         1
>>>    NO POSITION RESTRAINING
>>>    ATOM RESTRAINING REFERENCE POSITIONS ARE READ FROM FILE
>>>
>>>    NO DISTANCE RESTRAINING
>>>
>>>    NO DIHEDRAL RESTRAINING
>>>
>>>    NO J-VALUE RESTRAINING
>>>
>>>    NO LOCAL ELEVATION INTERACTION
>>>
>>>    SIMULATION PERFORMED IN 3 DIMENSIONS
>>>
>>>    NO PERTURBATION PERFORMED
>>>
>>> LATSUM
>>>    NLATSM     KXMAX     KYMAX     KZMAX     K2MAX     ALPHA     PBETA
>>> NGHTUP
>>>         2        32        32        32         0      .800     1.330
>>> 100000
>>>     THE PPPM METHOD WILL BE USED
>>>
>>>
>>>
>>> 3. O P T I O N A L   D A T A   F I L E S
>>>
>>>
>>>
>>> 4. A T O M I C   C O O R D I N A T E S   A N D   V E L O C I T I E S
>>>
>>> SYSTEMBLOCK
>>>    NUMBER OF SOLUTE ATOMS         :      16
>>>    NUMBER OF SOLVENT ATOMS        :    4128
>>>    TOTAL NUMBER OF ATOMS          :    4144
>>>    NUMBER OF SOLUTE CHARGE GROUPS :       6
>>>    NUMBER OF SOLVENT CHARGE GROUPS:    1376
>>>    TOTAL NUMBER OF CHARGE GROUPS  :    1382
>>> END SYSTEMBLOCK
>>>
>>> 1021
>>> INITIAL CONFIGURATION TITLE
>>>  coordinates generated from amber coord file
>>>  rest_eq_reimaged.rst.1
>>>
>>> 3D VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>>>
>>>
>>>
>>> 5. I N I T I A L I Z E   R U N
>>>
>>> PERFORMING A MOLECULAR DYNAMICS RUN
>>>
>>> NDEGBLOCK
>>>    NUMBER OF POSITIONALLY CONSTRAINED ATOMS   :       0
>>>    NUMBER OF BONDS BETWEEN POS. CONSTR. ATOMS :       0
>>>    NUMBER OF SOLUTE CONSTRAINTS               :       0
>>>    NUMBER OF 3D SOLUTE (INT+ROT) D.O.F        :      45
>>>    NUMBER OF 3D SOLUTE C.O.M. TRANSL. D.O.F   :       3
>>>    NUMBER OF SOLVENT CONSTRAINTS              :       3
>>>    NUMBER OF 3D SOLVENT D.O.F.                :    8256
>>>    NUMBER OF 3D D.O.F. TO SUBTRACT (NDFMIN)   :       0
>>>    NUMBER OF TOTAL D.O.F. IN 3D               :    8304
>>> END NDEGBLOCK
>>>
>>> BATHBLOCK
>>>    TEMPERATURE COUPLING TO  0 BATH(S)
>>> END BATHBLOCK
>>>
>>> mm_SHAKE Solvent Coordinates, NITS =    1
>>> mm_SHAKE Solvent Velocities,  NITS =   10
>>>
>>> INITIAL TEMPERATURES ARE :
>>>                           TOTAL  .30315128E+03
>>>  SOLUTE INTERNAL AND ROTATIONAL  .37959703E+03
>>>  SOLUTE C.O.M. TRANSLATIONAL     .67213419E+01
>>>                        SOLVENT   .30284232E+03
>>>                   4th DIMENSION  .00000000E+00
>>>
>>>
>>>   QUANTUM SYSTEM:
>>>   NAX: 8
>>>   NSX: 3
>>>   FULL SYSTEM:
>>>   NAX: 36
>>>   NSX: 119
>>> ***MM_QM_TOPO| SIZE OF THE PROGRAM IS 16692 KBytes ***
>>> THE FOLLOWING INTERACTIONS ARE EXCLUDED FROM THE MM HAMILTONIAN:
>>>
>>> BONDS INVOLVING HYDROGEN:
>>>      14        15
>>>      12        13
>>>      10        11
>>>       8         9
>>>       5         6
>>>       3         4
>>>       1         2
>>>
>>> BONDS NOT INVOLVING HYDROGEN:
>>>      14        16
>>>      12        14
>>>      10        12
>>>       8        10
>>>       7         8
>>>       7        16
>>>       5         7
>>>       3         5
>>>       1         3
>>>       1        16
>>>
>>> ANGLES INVOLVING HYDROGEN:
>>>      15        14        16
>>>      13        12        14
>>>      12        14        15
>>>      11        10        12
>>>      10        12        13
>>>       9         8        10
>>>       8        10        11
>>>       7         8         9
>>>       6         5         7
>>>       4         3         5
>>>       3         5         6
>>>       2         1         3
>>>       2         1        16
>>>       1         3         4
>>>
>>> ANGLES NOT INVOLVING HYDROGEN:
>>>      12        14        16
>>>      10        12        14
>>>       8         7        16
>>>       8        10        12
>>>       7         8        10
>>>       7        16        14
>>>       5         7         8
>>>       5         7        16
>>>       3         1        16
>>>       3         5         7
>>>       1         3         5
>>>       1        16         7
>>>       1        16        14
>>>
>>> PROPER DIHEDRALS INVOLVING HYDROGEN:
>>>      13        12        14        15
>>>      13        12        14        16
>>>      11        10        12        13
>>>      11        10        12        14
>>>      10        12        14        15
>>>       9         8         7        16
>>>       9         8        10        11
>>>       9         8        10        12
>>>       8        10        12        13
>>>       7         8        10        11
>>>       7        16        14        15
>>>       6         5         7         8
>>>       6         5         7        16
>>>       5         7         8         9
>>>      16         1         3         4
>>>       4         3         5         6
>>>       4         3         5         7
>>>       2         1         3         4
>>>       2         1         3         5
>>>       2         1        16         7
>>>       2         1        16        14
>>>       1         3         5         6
>>>       1        16        14        15
>>>      12        16        14        15
>>>      10        14        12        13
>>>       8        12        10        11
>>>       7        10         8         9
>>>       3         7         5         6
>>>
>>> PROPER DIHEDRALS NOT INVOLVING HYDROGEN:
>>>      10         8         7        16
>>>      10        12        14        16
>>>       8         7        16        14
>>>       8        10        12        14
>>>       7         8        10        12
>>>       7        16        14        12
>>>      16         1         3         5
>>>       5         7         8        10
>>>       5         7        16        14
>>>       3         1        16         7
>>>       3         1        16        14
>>>       3         5         7         8
>>>       3         5         7        16
>>>       1         3         5         7
>>>       1        16         7         5
>>>       1        16         7         8
>>>       1        16        14        12
>>>
>>> IMPROPER DIHEDRALS INVOLVING HYDROGEN:
>>>
>>> IMPROPER DIHEDRALS NOT INVOLVING HYDROGEN:
>>> NON BONDED INTERACTIONS EXCLUDED FROM THE MM HAMITONIAN
>>> NO ELECTROSTATIC EXCLUSION BETWEEN QM AND MM ATOMS
>>> best 1 1 677.212792866984046
>>> best 3 1 677.212792866983932
>>> Cell Volume 677.212792866983932
>>>
>>> NUMBER OF STATES:                                             22
>>> NUMBER OF ELECTRONS:                                    44.00000
>>> CHARGE:                                                   .00000
>>> ELECTRON TEMPERATURE(KELVIN):                             .00000
>>> OCCUPATION
>>>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>>>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>>>
>>> LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
>>>    MAX. KRYLOV BLOCK SIZE                                     22
>>>
>>>    ============================================================
>>>    |    Pseudopotential Report     Fri Feb 20 19:18:54 1998   |
>>>    ------------------------------------------------------------
>>>    |  Atomic Symbol                   :   H                   |
>>>    |  Atomic Number                   :   1                   |
>>>    |  Number of core states           :   0                   |
>>>    |  Number of valence states        :   1                   |
>>>    |  Exchange-Correlation Functional :                       |
>>>    |     Slater exchange :   .6667                            |
>>>    |     LDA correlation : Ceperley-Alder                     |
>>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>>    |  Electron Configuration :   N   L  Occupation            |
>>>    |                             1   S     .7000              |
>>>    |  Full Potential Total Energy     -.474341                |
>>>    |  Trouiller-Martins normconserving PP                     |
>>>    |     n    l        rc       energy                        |
>>>    |     1    S     .5000      -.37203                        |
>>>    |     2    P     .3828      -.37203                        |
>>>    |  Number of Mesh Points :   511                           |
>>>    |  Pseudoatom Total Energy    -.367794                     |
>>>    ============================================================
>>>
>>>    ============================================================
>>>    |    Pseudopotential Report                                |
>>>    ------------------------------------------------------------
>>>    |  Atomic Symbol                   :   N                   |
>>>    |  Atomic Number                   :   7                   |
>>>    |  Number of core states           :   1                   |
>>>    |  Number of valence states        :   2                   |
>>>    |  Exchange-Correlation Functional :                       |
>>>    |     Slater exchange :  0.6667                            |
>>>    |     LDA correlation : Ceperley-Alder                     |
>>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>>    |  Electron Configuration :   N   L  Occupation            |
>>>    |                             1   S    2.0000              |
>>>    |                             2   S    2.0000              |
>>>    |                             2   P    3.0000              |
>>>    |  Full Potential Total Energy =      -54.420394           |
>>>    |  Trouiller-Martins normconserving PP                     |
>>>    |     n    l        rc       energy                        |
>>>    |     2    S    1.1200     -0.68204                        |
>>>    |     2    P    1.1200     -0.26082                        |
>>>    |     3    D    0.6031     -0.26082                        |
>>>    |  Number of Mesh Points :   624                           |
>>>    |  Pseudoatom Total Energy =   -9.647042                   |
>>>    ============================================================
>>>
>>>    ============================================================
>>>    |    Pseudopotential Report                                |
>>>    ------------------------------------------------------------
>>>    |  Atomic Symbol                   :   C                   |
>>>    |  Atomic Number                   :   6                   |
>>>    |  Number of core states           :   1                   |
>>>    |  Number of valence states        :   2                   |
>>>    |  Exchange-Correlation Functional :                       |
>>>    |     Slater exchange :  0.6667                            |
>>>    |     LDA correlation : Ceperley-Alder                     |
>>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>>    |  Electron Configuration :   N   L  Occupation            |
>>>    |                             1   S    2.0000              |
>>>    |                             2   S    2.0000              |
>>>    |                             2   P    2.0000              |
>>>    |  Full Potential Total Energy   -37.748221                |
>>>    |  Trouiller-Martins normconserving PP                     |
>>>    |     n    l        rc       energy                        |
>>>    |     2    S    1.2300     -0.50506                        |
>>>    |     2    P    1.2300     -0.19451                        |
>>>    |     3    D    0.7159     -0.19451                        |
>>>    |  Number of Mesh Points :   615                           |
>>>    |  Pseudoatom Total Energy   -5.361882                     |
>>>    ============================================================
>>>
>>> ****************************************************************
>>> *   ATOM       MASS   RAGGIO NLCC              PSEUDOPOTENTIAL *
>>> *      H     1.0080   1.2000   NO    KLEINMAN      S  NONLOCAL *
>>> *                                                  P     LOCAL *
>>> *      N    14.0067   1.2000   NO    KLEINMAN      S  NONLOCAL *
>>> *                                                  P  NONLOCAL *
>>> *                                                  D     LOCAL *
>>> *      C    12.0112   1.2000   NO    KLEINMAN      S  NONLOCAL *
>>> *                                                  P  NONLOCAL *
>>> *                                                  D     LOCAL *
>>> ****************************************************************
>>>
>>>
>>> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>>>  NCPU     NGW     NHG  PLANES  GXRAYS  HXRAYS ORBITALS Z-PLANES
>>>     0   13225  105849      30     670    2674       5       1
>>>     1   13229  105829      30     670    2674       6       1
>>>     2   13224  105802      30     669    2673       5       1
>>>     3   13218  105844      30     672    2672       6       1
>>>                G=0 COMPONENT ON PROCESSOR :     2
>>> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>>>
>>> ***    LOADPA| SIZE OF THE PROGRAM IS 23728 KBytes ***
>>>
>>> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
>>> NUMBER OF CPUS PER TASK                                        1
>>> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
>>>
>>> ***     RGGEN| SIZE OF THE PROGRAM IS 26348 KBytes ***
>>>
>>> ************************** SUPERCELL ***************************
>>> THIS IS AN ISOLATED SYSTEM CALCULATION
>>> POISSON EQUATION SOLVER  :                   TUCKERMAN & MARTYNA
>>> SHORT RANGE POTENTIAL LENGTH * BOX LENGTH                  7.000
>>> SYMMETRY:                                           ORTHORHOMBIC
>>> LATTICE CONSTANT(a.u.):                                 22.28234
>>> CELL DIMENSION:  22.2823   .9145  1.0577   .0000   .0000   .0000
>>> VOLUME(OMEGA IN BOHR^3):                             10700.98252
>>> LATTICE VECTOR A1(BOHR):           22.2823      .0000      .0000
>>> LATTICE VECTOR A2(BOHR):             .0000    20.3770      .0000
>>> LATTICE VECTOR A3(BOHR):             .0000      .0000    23.5680
>>> RECIP. LAT. VEC. B1(2Pi/BOHR):       .0449      .0000      .0000
>>> RECIP. LAT. VEC. B2(2Pi/BOHR):       .0000      .0491      .0000
>>> RECIP. LAT. VEC. B3(2Pi/BOHR):       .0000      .0000      .0424
>>> REAL SPACE MESH:                   120          110          126
>>> WAVEFUNCTION CUTOFF(RYDBERG):                           70.00000
>>> DENSITY CUTOFF(RYDBERG):          (DUAL= 4.00)         280.00000
>>> NUMBER OF PLANE WAVES FOR WAVEFUNCTION CUTOFF:             52896
>>> NUMBER OF PLANE WAVES FOR DENSITY CUTOFF:                 423324
>>> ****************************************************************
>>>
>>> ***  RINFORCE| SIZE OF THE PROGRAM IS 39620 KBytes ***
>>> ***    FFTPRP| SIZE OF THE PROGRAM IS 53344 KBytes ***
>>> ***   CLUSTER| SIZE OF THE PROGRAM IS 61628 KBytes ***
>>>
>>> GENERATE ATOMIC BASIS SET
>>>      H        SLATER ORBITALS
>>>        1S        ALPHA=   1.0000      OCCUPATION= 1.00
>>>      N        SLATER ORBITALS
>>>        2S        ALPHA=   1.9237      OCCUPATION= 2.00
>>>        2P        ALPHA=   1.9170      OCCUPATION= 3.00
>>>      C        SLATER ORBITALS
>>>        2S        ALPHA=   1.6083      OCCUPATION= 2.00
>>>        2P        ALPHA=   1.5679      OCCUPATION= 2.00
>>>
>>>
>>> INITIALIZATION TIME:                                2.96 SECONDS
>>>
>>>
>>> *********************** LINEAR RESPONSE ************************
>>> Step size for numeric dmu/dn :                          .500E-03
>>> Number of calculations for dmu/dn :                            2
>>> Maximum number of optimisation steps:                       1000
>>> Threshold for Hessian (Preconditioner)                     .5000
>>> Optimizer for LR equations                             AUTOMATIC
>>>                    Size of ODIIS buffer                       10
>>>                    Size of ZDIIS buffer                        4
>>>                    Switch from PCG to ODIIS at         .1000E+00
>>>                    Switch to full preconditioning at   .1000E-02
>>> Step length                                                .1000
>>> Convergence criteria                                   .1000E-04
>>> ****************************************************************
>>>
>>> ***************************  TDDFT  ****************************
>>> Step size for numeric dmu/dn :                          .500E-03
>>> Number of calculations for dmu/dn :                            2
>>> Diagonalization Method                    NON-HERMITIAN DAVIDSON
>>>          Max. number of iterations                           200
>>>          Convergence criteria                           .100E-06
>>>          Max. size of Davidson matrix                         69
>>> Number of Singlet States                                       5
>>> Forces calculated for state                                    1
>>> ****************************************************************
>>> RV30! NUMBER OF STATES   HAS CHANGED                     22   27
>>>
>>> RESTART INFORMATION READ ON FILE                       ./RESTART
>>> ***     PHFAC| SIZE OF THE PROGRAM IS 85536 KBytes ***
>>> ATRHO| CHARGE(R-SPACE):   44.000000      (G-SPACE):   44.000000
>>> EWALD| SUM IN REAL SPACE OVER                      1* 1* 1 CELLS
>>>
>>> RE-CENTERING QM SYSTEM AT EVERY TIME STEP
>>>
>>>   BOX TOLERANCE [a.u.]   8.00000000000000000
>>>
>>> BOX SIZE [a.u.]                     QM SYSTEM SIZE [a.u.]
>>>  X DIRECTION:  CELLDIM =    22.2823; XMAX-XMIN=     4.3488
>>>  Y DIRECTION:  CELLDIM =    20.3770; YMAX-YMIN=    11.0220
>>>  Z DIRECTION:  CELLDIM =    23.5680; ZMAX-ZMIN=    10.3570
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 124624 KBytes ***
>>> ================================================================
>>> ==                        REFERENCE POINT                     ==
>>> ================================================================
>>> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124736 KBytes ***
>>>
>>>     !!!!!!!!!!!!!!!!!! WARNING !!!!!!!!!!!!!!!!!!!
>>>     THE QM SYSTEM DOES NOT HAVE AN INTEGER CHARGE.
>>>     A COMPENSATING CHARGE OF   -.000010 HAS BEEN
>>>     DISTRIBUTED OVER THE NN ATOMS.
>>>     !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>>>
>>> MM_ELSTAT: ELECTROSTATIC INTERACTION NN LIST UPDATED
>>> NN ATOMS =      496,  ESP COUPLED  ATOMS =      441
>>>
>>> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124920 KBytes ***
>>> ***MM_CHARGES| SIZE OF THE PROGRAM IS 125572 KBytes ***
>>> NBPML:     66387 ELEMENTS IN THE PAIRLIST
>>>
>>> PPPM USING NAG FFT ROUTINE , TWO real*8 GRIDS, PACKED GRID
>>> AND A SPHERICAL HAT FUNCTION
>>>
>>> GHAT FUNCTION HAS BEEN CALCULATED USING
>>> PBETA =     1.333 RESULTING IN Q =     .901232E-06
>>>
>>> A2 EVALUATED WITH LMAX =   44   TOL =  .00000047
>>> CONSTANT A1       =    -.01274135
>>> CONSTANT A2       =    1.69768358
>>> CONSTANT A3       =   -2.50000000
>>> CONSTANT XI       =   -2.74523413 = LX*(A1+A2+A3)
>>> EPSFAC*[SUM Q]**2 =   .138935E-07
>>> EPSFAC*SUM Q**2   =   .199556E+06
>>> ESELFL            =  -.813248E+05
>>>
>>>
>>> TOTAL INTEGRATED ELECTRONIC DENSITY
>>>    IN G-SPACE =                                        44.000000
>>>    IN R-SPACE =                                        44.000000
>>>
>>> (K+E1+L+N+X)           TOTAL ENERGY =          -63.33387972 A.U.
>>> (K)                  KINETIC ENERGY =           45.38116319 A.U.
>>> (E1=A-S+R)     ELECTROSTATIC ENERGY =          -49.67916341 A.U.
>>> (S)                           ESELF =           53.19230405 A.U.
>>> (R)                             ESR =            3.06373807 A.U.
>>> (L)    LOCAL PSEUDOPOTENTIAL ENERGY =          -41.17408788 A.U.
>>> (N)      N-L PSEUDOPOTENTIAL ENERGY =            4.84142028 A.U.
>>> (X)     EXCHANGE-CORRELATION ENERGY =          -18.95438051 A.U.
>>>         GRADIENT CORRECTION ENERGY =             -.28039967 A.U.
>>>
>>> NFI      GEMAX       CNORM           ETOT        DETOT      TCPU
>>>   1  1.582E-03   1.941E-04     -63.333880    0.000E+00     11.46
>>>   2  7.736E-04   7.495E-05     -63.339037   -5.157E-03      1.28
>>>   3  5.034E-04   4.193E-05     -63.339617   -5.801E-04      1.29
>>>   4  3.197E-04   2.216E-05     -63.339799   -1.819E-04      1.30
>>>   5  1.613E-04   1.182E-05     -63.339857   -5.781E-05      1.31
>>>   6  8.951E-05   6.529E-06     -63.339877   -2.043E-05      1.32
>>>   7  5.419E-05   4.024E-06     -63.339885   -8.035E-06      1.32
>>>   8  3.332E-05   2.665E-06     -63.339888   -3.376E-06      1.33
>>>   9  1.798E-05   1.736E-06     -63.339890   -1.479E-06      1.34
>>>  10  1.145E-05   1.139E-06     -63.339891   -7.199E-07      1.35
>>>  11  8.176E-06   7.835E-07     -63.339891   -3.883E-07      1.34
>>>
>>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.1
>>>
>>> TIME FOR MINIMUM STRUCTURE :                      28.598 SECONDS
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 152720 KBytes ***
>>> ================================================================
>>> ==                END OF REFERENCE CALCULATION                ==
>>> ==               GENERATE INITIAL GUESS VECTORS               ==
>>> ================================================================
>>>
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 152724 KBytes ***
>>>
>>> <<<<<<<<<<<<<<<<<<< LANCZOS DIAGONALIZATION <<<<<<<<<<<<<<<<<<<<
>>>>> TIME FOR INITIAL SUBSPACE DIAGONALIZATION:                .57
>>>>> CYCLE     NCONV        B2MAX        B2MIN     #HPSI      TIME
>>>        1        22    7.534E-02    4.315E-10      2.30       .83
>>>        2        22    6.405E-02    4.314E-10      1.30       .82
>>>        3        22    3.739E-02    4.312E-10      1.30       .82
>>>        4        22    3.703E-02    4.311E-10      1.30       .83
>>>        5        22    2.207E-02    4.309E-10      1.30       .83
>>>        6        22    2.649E-02    4.309E-10      1.30       .82
>>>        7        22    2.905E-02    4.308E-10      1.30       .82
>>>        8        22    3.196E-02    4.308E-10      1.30       .82
>>>        9        22    3.057E-02    4.307E-10      1.30       .82
>>>       10        22    2.965E-02    4.307E-10      1.30       .82
>>>       11        22    2.497E-02    4.306E-10      1.30       .82
>>>       12        22    2.201E-02    4.306E-10      1.30       .82
>>>       13        22    1.723E-02    4.306E-10      1.30       .83
>>>       14        22    1.456E-02    4.306E-10      1.30       .82
>>>       15        22    1.117E-02    4.305E-10      1.30       .82
>>>       16        22    8.860E-03    4.305E-10      1.30       .82
>>>       17        22    4.720E-03    4.305E-10      1.30       .82
>>>       18        22    6.282E-03    4.305E-10      1.30       .82
>>>       19        22    5.300E-03    4.305E-10      1.30       .82
>>>       20        22    4.964E-03    4.305E-10      1.30       .82
>>>       21        22    4.155E-03    4.305E-10      1.30       .82
>>>       22        22    3.913E-03    4.305E-10      1.30       .82
>>>       23        22    3.321E-03    4.305E-10      1.30       .82
>>>       24        22    3.148E-03    4.305E-10      1.30       .82
>>>       25        22    2.691E-03    4.305E-10      1.30       .82
>>>       26        22    2.556E-03    4.305E-10      1.30       .82
>>>       27        22    2.192E-03    4.305E-10      1.30       .82
>>>       28        22    2.081E-03    4.305E-10      1.30       .82
>>>       29        22    1.788E-03    4.305E-10      1.30       .82
>>>       30        22    1.695E-03    4.305E-10      1.30       .82
>>>       31        22    1.458E-03    4.305E-10      1.30       .82
>>>       32        22    1.381E-03    4.305E-10      1.30       .82
>>>       33        22    1.190E-03    4.305E-10      1.30       .82
>>>       34        22    1.127E-03    4.305E-10      1.30       .82
>>>       35        22    1.023E-03    4.305E-10      1.30       .82
>>>       36        22    9.216E-04    4.305E-10      1.30       .86
>>>       37        22    1.092E-03    4.305E-10      1.30       .82
>>>       38        22    9.192E-04    4.305E-10      1.30       .82
>>>       39        22    1.165E-03    4.305E-10      1.30       .82
>>>       40        22    9.791E-04    4.305E-10      1.30       .82
>>>       41        22    1.239E-03    4.305E-10      1.30       .82
>>>       42        23    1.039E-03    4.305E-10      1.11       .65
>>>       43        23    1.312E-03    4.305E-10      1.04       .58
>>>       44        23    1.097E-03    4.305E-10      1.04       .58
>>>       45        23    1.381E-03    4.305E-10      1.04       .58
>>>       46        23    1.150E-03    4.305E-10      1.04       .58
>>>       47        23    1.443E-03    4.305E-10      1.04       .58
>>>       48        23    1.197E-03    4.305E-10      1.04       .58
>>>       49        23    1.494E-03    4.305E-10      1.04       .58
>>>       50        23    1.233E-03    4.305E-10      1.04       .58
>>>       51        23    1.533E-03    4.305E-10      1.04       .58
>>>       52        23    1.258E-03    4.305E-10      1.04       .58
>>>       53        23    1.556E-03    4.305E-10      1.04       .59
>>>       54        23    1.270E-03    4.305E-10      1.04       .58
>>>       55        23    1.562E-03    4.305E-10      1.04       .58
>>>       56        23    1.267E-03    4.305E-10      1.04       .58
>>>       57        23    1.550E-03    4.305E-10      1.04       .58
>>>       58        23    1.249E-03    4.305E-10      1.04       .58
>>>       59        23    1.520E-03    4.305E-10      1.04       .58
>>>       60        23    1.218E-03    4.305E-10      1.04       .58
>>>       61        23    1.473E-03    4.305E-10      1.04       .58
>>>       62        23    1.173E-03    4.305E-10      1.04       .58
>>>       63        23    1.411E-03    4.305E-10      1.04       .58
>>>       64        24    1.117E-03    4.305E-10       .85       .59
>>>       65        24    1.337E-03    4.305E-10       .78       .59
>>>       66        24    1.052E-03    4.305E-10       .85       .58
>>>       67        24    1.254E-03    4.305E-10       .78       .59
>>>       68        24    9.810E-04    4.305E-10       .78       .59
>>>       69        24    1.164E-03    4.305E-10       .85       .58
>>>       70        24    9.057E-04    4.305E-10       .78       .59
>>>       71        24    1.070E-03    4.305E-10       .78       .59
>>>       72        24    8.286E-04    4.305E-10       .78       .59
>>>       73        24    9.758E-04    4.305E-10       .78       .59
>>>       74        24    7.518E-04    4.305E-10       .78       .59
>>>       75        24    8.826E-04    4.305E-10       .78       .59
>>>       76        24    6.769E-04    4.305E-10       .78       .59
>>>       77        24    7.926E-04    4.305E-10       .78       .61
>>>       78        24    6.053E-04    4.305E-10       .78       .60
>>>       79        24    7.073E-04    4.305E-10       .78       .59
>>>       80        24    5.380E-04    4.305E-10       .78       .59
>>>       81        24    6.276E-04    4.305E-10       .78       .59
>>>       82        24    4.756E-04    4.305E-10       .78       .59
>>>       83        24    5.542E-04    4.305E-10       .78       .59
>>>       84        24    4.186E-04    4.305E-10       .78       .59
>>>       85        24    4.873E-04    4.305E-10       .78       .59
>>>       86        24    3.669E-04    4.305E-10       .78       .59
>>>       87        24    4.271E-04    4.305E-10       .78       .59
>>>       88        24    3.207E-04    4.305E-10       .78       .59
>>>       89        24    3.733E-04    4.305E-10       .78       .59
>>>       90        24    2.797E-04    4.305E-10       .78       .59
>>>       91        24    3.257E-04    4.305E-10       .78       .59
>>>       92        24    2.435E-04    4.305E-10       .78       .59
>>>       93        24    2.838E-04    4.305E-10       .78       .59
>>>       94        24    2.118E-04    4.305E-10       .78       .59
>>>       95        24    2.471E-04    4.305E-10       .78       .59
>>>       96        24    1.842E-04    4.305E-10       .78       .59
>>>       97        24    2.152E-04    4.305E-10       .78       .59
>>>       98        24    1.603E-04    4.305E-10       .78       .59
>>>       99        24    1.875E-04    4.305E-10       .78       .59
>>>      100        24    1.395E-04    4.305E-10       .78       .59
>>>      101        24    1.635E-04    4.305E-10       .78       .59
>>>      102        24    1.216E-04    4.305E-10       .78       .59
>>>      103        24    1.428E-04    4.305E-10       .78       .59
>>>      104        24    1.061E-04    4.305E-10       .78       .59
>>>      105        24    1.248E-04    4.305E-10       .78       .59
>>>      106        24    9.275E-05    4.305E-10       .78       .59
>>>      107        24    1.093E-04    4.305E-10       .78       .59
>>>      108        24    8.121E-05    4.305E-10       .78       .59
>>>      109        24    9.585E-05    4.305E-10       .78       .59
>>>      110        24    7.123E-05    4.305E-10       .78       .59
>>>      111        24    8.422E-05    4.305E-10       .78       .59
>>>      112        24    6.259E-05    4.305E-10       .78       .59
>>>      113        24    7.413E-05    4.305E-10       .78       .59
>>>      114        24    5.510E-05    4.305E-10       .78       .59
>>>      115        24    6.537E-05    4.305E-10       .78       .59
>>>      116        24    4.860E-05    4.305E-10       .78       .59
>>>      117        24    5.774E-05    4.305E-10       .78       .59
>>>      118        24    4.294E-05    4.305E-10       .78       .59
>>>      119        24    5.109E-05    4.305E-10       .78       .59
>>>      120        24    3.801E-05    4.305E-10       .78       .59
>>>      121        24    4.528E-05    4.305E-10       .78       .60
>>>      122        24    3.370E-05    4.305E-10       .78       .59
>>>      123        24    4.020E-05    4.305E-10       .78       .59
>>>      124        24    2.993E-05    4.305E-10       .78       .59
>>>      125        24    3.575E-05    4.305E-10       .78       .59
>>>      126        24    2.662E-05    4.305E-10       .78       .59
>>>      127        24    3.183E-05    4.305E-10       .78       .59
>>>      128        24    2.371E-05    4.305E-10       .78       .59
>>>      129        24    2.838E-05    4.305E-10       .78       .59
>>>      130        24    2.115E-05    4.305E-10       .78       .59
>>>      131        24    2.535E-05    4.305E-10       .78       .59
>>>      132        24    1.890E-05    4.305E-10       .78       .59
>>>      133        24    2.266E-05    4.305E-10       .78       .59
>>>      134        24    1.690E-05    4.305E-10       .78       .59
>>>      135        24    2.029E-05    4.305E-10       .78       .59
>>>      136        24    1.514E-05    4.305E-10       .78       .59
>>>      137        24    1.818E-05    4.305E-10       .78       .59
>>>      138        24    1.357E-05    4.305E-10       .78       .59
>>>      139        24    1.632E-05    4.305E-10       .78       .59
>>>      140        24    1.218E-05    4.305E-10       .78       .59
>>>      141        24    1.466E-05    4.305E-10       .78       .59
>>>      142        24    1.095E-05    4.305E-10       .78       .59
>>>      143        24    1.318E-05    4.305E-10       .78       .59
>>>      144        24    9.846E-06    4.305E-10       .78       .59
>>>      145        25    1.186E-05    4.305E-10       .63       .45
>>>      146        25    8.861E-06    4.305E-10       .52       .35
>>>      147        25    1.069E-05    4.305E-10       .52       .35
>>>      148        25    7.987E-06    4.305E-10       .52       .35
>>>      149        25    9.644E-06    4.305E-10       .52       .35
>>>      150        25    7.205E-06    4.305E-10       .52       .35
>>>      151        25    8.706E-06    4.305E-10       .52       .35
>>>      152        25    6.505E-06    4.305E-10       .52       .35
>>>      153        25    7.866E-06    4.305E-10       .52       .35
>>>      154        25    5.877E-06    4.305E-10       .52       .35
>>>      155        25    7.113E-06    4.305E-10       .52       .35
>>>      156        25    5.314E-06    4.305E-10       .52       .35
>>>      157        25    6.436E-06    4.305E-10       .52       .35
>>>      158        25    4.809E-06    4.305E-10       .52       .35
>>>      159        25    5.828E-06    4.305E-10       .52       .35
>>>      160        26    4.354E-06    4.305E-10       .33       .33
>>>      161        26    5.277E-06    4.305E-10       .26       .32
>>>      162        26    3.948E-06    4.305E-10       .26       .32
>>>      163        26    4.785E-06    4.305E-10       .26       .32
>>>      164        26    3.582E-06    4.305E-10       .26       .32
>>>      165        26    4.341E-06    4.305E-10       .26       .32
>>>      166        26    3.252E-06    4.305E-10       .26       .32
>>>      167        26    3.940E-06    4.305E-10       .26       .32
>>>      168        26    2.953E-06    4.305E-10       .26       .32
>>>      169        26    3.578E-06    4.305E-10       .26       .32
>>>      170        26    2.684E-06    4.305E-10       .26       .32
>>>      171        26    3.251E-06    4.305E-10       .26       .32
>>>      172        26    2.440E-06    4.305E-10       .26       .32
>>>      173        26    2.955E-06    4.305E-10       .26       .32
>>>      174        26    2.220E-06    4.305E-10       .26       .32
>>>      175        26    2.688E-06    4.305E-10       .26       .32
>>>      176        26    2.020E-06    4.305E-10       .26       .32
>>>      177        26    2.446E-06    4.305E-10       .26       .32
>>>      178        27    9.966E-07    4.305E-10       .19       .24
>>>
>>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.2
>>>
>>> EIGENVALUES(EV) AND OCCUPATION:
>>>     1    -23.7335233       2.00000000        2    -19.9290529
>>> 2.00000000
>>>     3    -18.3902715       2.00000000        4    -17.2606686
>>> 2.00000000
>>>     5    -16.6676136       2.00000000        6    -14.4741075
>>> 2.00000000
>>>     7    -13.7418694       2.00000000        8    -13.2132617
>>> 2.00000000
>>>     9    -12.2511591       2.00000000       10    -10.7230135
>>> 2.00000000
>>>    11    -10.4904816       2.00000000       12     -9.8090984
>>> 2.00000000
>>>    13     -9.5347383       2.00000000       14     -9.4073271
>>> 2.00000000
>>>    15     -9.0064959       2.00000000       16     -8.5053970
>>> 2.00000000
>>>    17     -7.5545624       2.00000000       18     -7.3121930
>>> 2.00000000
>>>    19     -7.0592376       2.00000000       20     -5.9706919
>>> 2.00000000
>>>    21     -4.7579865       2.00000000       22     -4.1479453
>>> 2.00000000
>>>    23      -.5969499        .00000000       24      -.3720761
>>> .00000000
>>>    25       .3650124        .00000000       26       .3724612
>>> .00000000
>>>    27       .4402542        .00000000
>>> CHEMICAL POTENTIAL =                            -4.1479469673 EV
>>> ================================================================
>>> ==                END OF STATE INITIALIZATION                 ==
>>> ================================================================
>>>
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 161824 KBytes ***
>>> ==                      SINGLET STATES                        ==
>>> NUMBER OF STATES TO BE INITIALIZED                             5
>>> TOTAL NUMBER OF TEST VECTORS                                  10
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 207492 KBytes ***
>>> ================================================================
>>> ==   NON-HERMITIAN DAVIDSON DIAGONALISATION OF TDDFT MATRIX   ==
>>> ================================================================
>>> Number of states initialized                                  10
>>> Time for initialization                                    10.60
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           0            10        .15845565E-01       25.20
>>>     2           0            20        .11376972E-01       25.99
>>>     3           0            30        .86052357E-02       27.10
>>>     4           0            40        .28366033E-01       28.49
>>>     5           0            50        .86824638E-02       30.19
>>>     6           0            60        .47491577E-02       32.24
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           0            10        .32825954E-02       24.97
>>>     2           0            20        .12877815E-02       25.77
>>>     3           0            30        .12378764E-02       26.84
>>>     4           0            40        .86346371E-03       28.24
>>>     5           0            50        .63720455E-03       29.94
>>>     6           0            60        .47484767E-03       32.01
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           0            10        .38477936E-03       24.96
>>>     2           0            20        .34007730E-03       25.76
>>>     3           0            30        .33896785E-03       26.84
>>>     4           0            40        .33335272E-03       28.25
>>>     5           0            50        .32908877E-03       29.98
>>>     6           0            60        .32421071E-03       32.03
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           0            10        .32168820E-03       24.94
>>>     2           0            20        .31938491E-03       25.73
>>>     3           0            30        .31889769E-03       26.82
>>>     4           0            40        .31755839E-03       28.23
>>>     5           0            50        .31660912E-03       29.93
>>>     6           0            60        .31638267E-03       32.05
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           0            10        .13172735E-02       24.97
>>>     2           0            20        .38287214E-03       25.75
>>>     3           0            30        .37349499E-03       26.85
>>>     4           0            40        .31639432E-03       28.22
>>>     5           0            50        .31617519E-03       29.93
>>>     6           0            60        .31599779E-03       32.01
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>>     1           1            10        .31589822E-03       24.97
>>>     2           2            18        .31586838E-03       20.56
>>>     3           3            24        .82191816E-04       16.06
>>>     4           3            28        .91936763E-04       11.39
>>>     5           3            32        .10357358E-03       11.81
>>>     6           3            36        .10676478E-03       12.30
>>>     7           3            40        .14164920E-03       12.80
>>>     8           3            44        .21147763E-03       13.39
>>>     9           3            48        .14641292E-03       13.98
>>>    10           3            52        .11876749E-03       14.70
>>>    11           3            56        .94534219E-04       15.42
>>>    12           3            60        .71650384E-04       16.20
>>>    13           3            64        .59567744E-04       17.03
>>>    14           3            68        .51910420E-04       17.89
>>> Number of states initialized                                  10
>>> Time for initialization                                      .30
>>>
>>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>>> !! DAVIDSON| NOT ALL ROOTS ARE CONVERGED                      !!
>>> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>>>
>>>
>>> STATE=  1                               EIGENVALUE=     3.725 eV
>>>
>>>
>>> STATE=  2                               EIGENVALUE=     4.108 eV
>>>
>>>
>>> STATE=  3                               EIGENVALUE=     4.346 eV
>>>
>>>
>>> STATE=  4                               EIGENVALUE=     4.485 eV
>>>
>>>
>>> STATE=  5                               EIGENVALUE=     4.508 eV
>>> ***   SPECTRA| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>>>
>>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.3
>>>
>>> ================================================================
>>>                      BIG MEMORY ALLOCATIONS
>>> PME              3570830                CB              40733000
>>> CSCR             4655200                C1               5819000
>>> CATOM            1137350                CSP             40733000
>>> GDE               892707                CSM             40733000
>>> SCR              3482773                CR               1163800
>>> ----------------------------------------------------------------
>>> [PEAK NUMBER  110]      PEAK MEMORY    144366981 = 1154.9 MBytes
>>> ================================================================
>>>
>>>
>>> ****************************************************************
>>> *                                                              *
>>> *                            TIMING                            *
>>> *                                                              *
>>> ****************************************************************
>>> SUBROUTINE            CALLS         CPU TIME        ELAPSED TIME
>>>     GCENER              883           191.15              191.15
>>>    FFT-G/S           142837           141.20              141.21
>>>     FWFFTN            12010           136.94              136.94
>>>   S_INVFFT            14045           127.79              127.78
>>>    INVFFTN            12153           110.91              110.91
>>>      FWFFT             3981            75.31               75.31
>>>       VPSI             2553            53.65               53.66
>>>    S_FWFFT             4685            53.23               53.23
>>>     INVFFT             3098            46.18               46.18
>>>    FNONLOC             2118            42.13               42.13
>>>     XCENER              883            35.73               35.73
>>>     RNLSM1             2118            27.13               27.13
>>>     FFTCOM            25809            26.48               26.48
>>>    RHO1OFR              435            25.46               25.46
>>>   N-FFTCOM            24163            17.30               17.30
>>>     GRADEN              883            12.82               12.82
>>>      OVLAP             1288            11.13               11.13
>>> MM_ELSTAT_                1             8.58                8.58
>>>     ROTATE             1287             7.41                7.41
>>>      PHASE             7079             7.29                7.30
>>>      DD_XC              435             5.70                5.70
>>>   FRIESNER                1             4.99                4.99
>>>  VTDOFRHO1              435             4.82                4.82
>>>     GLOSUM            30274             3.66                3.65
>>>     OVLAP2              383             2.93                2.93
>>>       HPSI             2090             2.33                2.33
>>> ----------------------------------------------------------------
>>> TOTAL TIME                           1182.25             1182.25
>>> ****************************************************************
>>>
>>>       CPU TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
>>>   ELAPSED TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
>>> ***      CPMD| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>>>
>>> PROGRAM CPMD ENDED AT:   Mon Oct  1 22:52:38 2007
>>>
>>>
>>> ================================================================
>>> = COMMUNICATION TASK  AVERAGE MESSAGE LENGTH  NUMBER OF CALLS  =
>>> = SEND/RECEIVE              133074. BYTES               2559.  =
>>> = BROADCAST                  21267. BYTES                639.  =
>>> = GLOBAL SUMMATION             591. BYTES              32713.  =
>>> = GLOBAL MULTIPLICATION          0. BYTES                  1.  =
>>> = ALL TO ALL COMM          1834756. BYTES              49972.  =
>>> =                             PERFORMANCE          TOTAL TIME  =
>>> = SEND/RECEIVE              897.740  MB/S            .379 SEC  =
>>> = BROADCAST                 432.366  MB/S            .031 SEC  =
>>> = GLOBAL SUMMATION            9.594  MB/S           4.032 SEC  =
>>> = GLOBAL MULTIPLICATION        .000  MB/S            .001 SEC  =
>>> = ALL TO ALL COMM          2101.717  MB/S          43.625 SEC  =
>>> = SYNCHRONISATION                                    .009 SEC  =
>>> ================================================================
>>>
>>> _______________________________________________
>>> CPMD-list mailing list
>>> CPMD-list at cpmd.org
>>> http://cpmd.org/mailman/listinfo/cpmd-list
>>>
>>
> _______________________________________________
> CPMD-list mailing list
> CPMD-list at cpmd.org
> http://cpmd.org/mailman/listinfo/cpmd-list
>


More information about the CPMD-list mailing list