[CPMD-list] Full response version of TDDFT

Emiliano Ippoliti ippoliti at sissa.it
Fri Jan 18 16:34:01 CET 2008


Thanks for your reply.

Regarding the oscillator strength f which I obtain with a Tamm-Dancoff 
calculation, is the same as in

B = (4 pi^2 e^2 f)/(m h v c)      (1)
(with obvious notation)

to calculate experimental Einstein absorption coefficient B?

Or does it depend on some computational features, such as volume cell for 
example, and in this case I should accordingly correct it to get the value 
to insert in (1)?

Regards,
Emiliano

On Wed, 16 Jan 2008, Juerg Hutter wrote:

> Hi
>
> oscillator strength with the full LR TDDFT has never been
> implemented in CPMD.
> The implementation for the Tamm-Dancoff approximation
> for periodic system (works also for non-periodic) can be found
> in the paper by Bernasconi and Sprik.
>
> regards
>
> Juerg Hutter
>
> ----------------------------------------------------------
> Juerg Hutter                   Phone : ++41 44 635 4491
> Physical Chemistry Institute   FAX   : ++41 44 635 6838
> University of Zurich           E-mail: hutter at pci.uzh.ch
> Winterthurerstrasse 190
> CH-8057 Zurich, Switzerland
> ----------------------------------------------------------
>
>
> On Wed, 16 Jan 2008, Emiliano Ippoliti wrote:
>
>> Dear CPMD users,
>> 
>> I'm using the TDDFT routines implemented in the last version of CPMD to
>> calculate electronic excitation energies in QM/MM simulations. Recently I
>> have tried to use the keyword LR-TDDFT to perform the "exact" calculation
>> without the Tamm-Dancoff approximation.
>> What I don't understand is the fact that in the output file I cannot find
>> the oscillator strength (the "f") together with the value of the excitation
>> energies. What is the reason? How can I have a measure of the intensity of
>> excitation transitions? How is calculate the oscillator strength in the
>> default setup with the Tamm-Dancoff approximation?
>> Below, I report an example of output file.
>> 
>> Best regards,
>> Emiliano
>> 
>> 
>> ...
>> 
>> 
>> ****************************************************************************
>> **
>> **                              INPUT FILE
>> **
>> 
>> ****************************************************************************
>> **
>> ** &QMMM
>> **
>> ** TOPOLOGY
>> **
>> ** gromos.top
>> **
>> ** COORDINATES
>> **
>> ** gromos.g96
>> **
>> ** INPUT
>> **
>> ** gromos.inp
>> **
>> ** ELECTROSTATIC COUPLING LONG RANGE
>> **
>> ** RCUT_NN
>> **
>> ** 10
>> **
>> ** RCUT_MIX
>> **
>> ** 15
>> **
>> ** RCUT_ESP
>> **
>> ** 20
>> **
>> ** UPDATE LIST
>> **
>> ** 100
>> **
>> ** SPLIT
>> **
>> ** SAMPLE_INTERACTING
>> **
>> ** 1000
>> **
>> ** AMBER
>> **
>> ** ARRAYSIZES
>> **
>> **
>> **
>> **  MAXATT 17
>> **
>> **  MAXAA2 11
>> **
>> **  MAXNRP 26
>> **
>> **  MAXNBT 21
>> **
>> **  MAXBNH 17
>> **
>> **  MAXBON 20
>> **
>> **  MAXTTY 23
>> **
>> **  MXQHEH 24
>> **
>> **  MAXTH  23
>> **
>> **  MAXQTY 10
>> **
>> **  MAXHIH 10
>> **
>> **  MAXQHI 10
>> **
>> **  MAXPTY 15
>> **
>> **  MXPHIH 38
>> **
>> **  MAXPHI 27
>> **
>> **  MAXCAG 16
>> **
>> **  MAXAEX 20044
>> **
>> **  MXEX14 42
>> **
>> **
>> **
>> ** END ARRAYSIZES
>> **
>> ** &END
>> **
>> **
>> **
>> ** &CPMD
>> **
>> **  RESTART WAVEFUNCTION COORDINATES
>> **
>> **  QMMM
>> **
>> **  ELECTRONIC SPECTRA
>> **
>> **  LANCZOS DIAGONALIZATION
>> **
>> **  LANCZOS PARAMETER
>> **
>> **   3000 8 0 1E-6
>> **
>> **  MAXSTEP
>> **
>> **   999999
>> **
>> **  COMPRESS WRITE32
>> **
>> **  MIRROR
>> **
>> **  RESTFILE
>> **
>> **   3
>> **
>> ** &END
>> **
>> **
>> **
>> ** &TDDFT
>> **
>> **  STATES SINGLET
>> **
>> **   5
>> **
>> **  tAMM-DANCOFF
>> **
>> **  LR-TDDFT
>> **
>> **  DAVIDSON PARAMETER
>> **
>> **   200 1.D-7 69
>> **
>> ** &END
>> **
>> **
>> **
>> ** &SYSTEM
>> **
>> **  POISSON SOLVER TUCKERMAN
>> **
>> **  SYMMETRY
>> **
>> **   0
>> **
>> **  CELL
>> **
>> **   22.282343   .9144899  1.0576992  0  0  0
>> **
>> **  CUTOFF
>> **
>> **   70.
>> **
>> **  CHARGE
>> **
>> **   0.0
>> **
>> ** &END
>> **
>> **
>> **
>> ** &ATOMS
>> **
>> **
>> **
>> ** *H_MT_PBE.psp KLEINMAN-BYLANDER
>> **
>> **    LMAX=P
>> **
>> **      7
>> **
>> ** 2   4   6   9  11  13  15
>> **
>> **
>> **
>> ** *N_MT_PBE.psp KLEINMAN-BYLANDER
>> **
>> **    LMAX=D
>> **
>> **      1
>> **
>> ** 5
>> **
>> **
>> **
>> ** *C_MT_PBE.psp KLEINMAN-BYLANDER
>> **
>> **    LMAX=D
>> **
>> **      8
>> **
>> ** 1   3   7   8  10  12  14  16
>> **
>> **
>> **
>> ** &END
>> **
>> **
>> **
>> ** &DFT
>> **
>> **   FUNCTIONAL PBE
>> **
>> **   GC-CUTOFF
>> **
>> **   1.0E-06
>> **
>> ** &END
>> **
>> 
>> ****************************************************************************
>> **
>> 
>> ****************************************************************************
>> **
>> 
>> CALCULATE ELECTRONIC SPECTRA
>> PATH TO THE RESTART FILES:                                    ./
>> RESTART WITH OLD ORBITALS
>> RESTART WITH OLD ION POSITIONS
>> GRAM-SCHMIDT ORTHOGONALIZATION
>> MAXIMUM NUMBER OF STEPS:                            999999 STEPS
>> WRITE WAVEFUNCTIONS IN COMPRESSED FORM TO FILE
>>   COMPRESSION FACTOR IS   2
>> PRINT INTERMEDIATE RESULTS EVERY                   1000000 STEPS
>> STORE INTERMEDIATE RESULTS EVERY                   1000000 STEPS
>> NUMBER OF DISTINCT RESTART FILES:                              3
>> TEMPERATURE IS CALCULATED ASSUMING EXTENDED BULK BEHAVIOR
>> FICTITIOUS ELECTRON MASS:                               400.0000
>> TIME STEP FOR ELECTRONS:                                  5.0000
>> TIME STEP FOR IONS:                                       5.0000
>> CONVERGENCE CRITERIA FOR WAVEFUNCTION OPTIMIZATION:   1.0000E-05
>> WAVEFUNCTION OPTIMIZATION BY PRECONDITIONED DIIS
>> THRESHOLD FOR THE WF-HESSIAN IS                            .5000
>> MAXIMUM NUMBER OF VECTORS RETAINED FOR DIIS:                  10
>> STEPS UNTIL DIIS RESET ON POOR PROGRESS:                      10
>> FULL ELECTRONIC GRADIENT IS USED
>> SPLINE INTERPOLATION IN G-SPACE FOR PSEUDOPOTENTIAL FUNCTIONS
>>    NUMBER OF SPLINE POINTS:                                 5000
>> 
>> EXCHANGE CORRELATION FUNCTIONALS
>>    LDA EXCHANGE:                                            NONE
>>    LDA XC THROUGH PADE APPROXIMATION
>>    S.GOEDECKER, J.HUTTER, M.TETER PRB 54 1703 (1996)
>>    GRADIENT CORRECTED FUNCTIONAL
>>    DENSITY THRESHOLD:                                1.00000E-06
>>    EXCHANGE ENERGY
>>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>>    CORRELATION ENERGY
>>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>>
>>  WARNING: ISOLATED CLUSTER OPTION NEEDED IN QMMM
>>           NOW TCLUST WILL BE SET TO .TRUE.
>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>>  qmmm by Alessandro Laio,
>>  qmmm    Joost VandeVondele, and
>>  qmmm    Ursula Rothlisberger
>>  qmmm
>>  qmmm Revised DYNA version:
>>  qmmm                    Tsukuba, 20 November 2005
>>  qmmm        Bochum/Philadelphia, 27 November 2005
>>  qmmm (Rewritten and vectorized for ES & Co.)
>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>>  qmmm
>>  qmmm GROMOS TOPOLOGY FILE    : gromos.top
>>  qmmm GROMOS COORDINATES FILE : gromos.g96
>>  qmmm GROMOS INPUT FILE       : gromos.inp
>>  qmmm
>>  qmmm USING AMBER FUNCTIONAL FORM
>>  qmmm
>>  qmmm QM AND MM TASKS PERFORMED IN THE SAME GROUP
>>  qmmm
>>  qmmm ELECTROSTATIC COUPLING WITH THE NN ATOMS
>>  qmmm MULTIPOLE COUPLING WITH THE FAR MM ATOMS
>>  qmmm
>>  qmmm CUTOFFS FOR THE ELECTROSTATIC COUPLING [A.U.]:
>>  qmmm {RCUT_NN}  RCUT_NN  =   10.00
>>  qmmm {RCUT_MIX} RCUT_MIX =   15.00
>>  qmmm {RCUT_ESP} RCUT_ESP =   20.00
>>  qmmm
>>  qmmm {UPDATE LIST} NN LIST UPDATED EVERY    100 STEPS
>>  qmmm {MAXNN} MAXIMUM NUMBER OF NN ATOMS   5000
>>  qmmm {ESPWEIGHT} WEIGHT FOR THE ESP FIT =      .1000
>>  qmmm {SAMPLE INTERACTING} DATA SAVED EVERY   1000 STEPS
>>  qmmm
>>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>> 
>> ***     DETSP| SIZE OF THE PROGRAM IS  7640 KBytes ***
>> ***ALLOC_GROM| SIZE OF THE PROGRAM IS  7800 KBytes ***
>> promd.f,v 1.55 1996/11/25 14:49:50 wscott Exp
>> Present revision: Tsukuba, 13 July 2005
>> 
>> PROGRAM PROMD PERFORMS EITHER
>>   AN ENERGY MINIMISATION,
>>   A MOLECULAR DYNAMICS RUN,
>>   OR A STOCHASTIC DYNAMICS RUN
>> IN THREE OR FOUR DIMENSIONS FOR A NUMBER OF SOLUTE
>> (PROTEIN) MOLECULES PLUS SOLVENT MOLECULES, USING:
>>
>>  A: SPECIFICATION DATA
>> -----------------------
>>  1. A MOLECULAR TOPOLOGY FILE
>>  2. DATA CHARACTERIZING THE RUN
>>  3. DATA DETERMINING THE FREE ENERGY PERTURBATION (IF NTG>0)
>>  4. RE(CON)STRAINED ATOM SEQUENCE NUMBERS (IF NTR>0)
>>  5. DISTANCE RESTRAINT ATOM PAIRS (IF NTDR>0)
>>  6. RESTRAINED DIHEDRALS (IF NTDLR>0)
>>  7. J-VALUE RESTRAINING DIHEDRALS (IF NTJR >0)
>>  8. LOCAL ELEVATION DIHEDRALS (IF NTLE > 0)
>>  9. 4th DIMENSION ATOM INDICATORS (IF NT4DIM >0)
>>
>>  B: STARTUP DATA
>> -----------------
>> 10. INITIAL ATOMIC COORDINATES AND VELOCITIES
>> 11. ATOMIC FRICTION COEFFICIENTS (IF NTFR=2)
>> 12. REFERENCE ATOM COORDINATES FOR RE(CON)STRAINING (IF NTR>0)
>> 
>> 
>> 
>> 1. M O L E C U L A R   T O P O L O G Y
>> 
>> TOPOLOGY TITLE
>> IND
>> 
>> 
>> 
>> 2. D A T A   C H A R A C T E R I Z I N G   T H E   RUN
>> 
>> TITLE
>>  Input generated by QMMM interface
>> 
>> SYSTEM
>>       NPM       NSM
>>         1      1376
>> START
>>       NTX      INIT        IG     TEMPI      HEAT NTXO       BOLTZ
>>         1         1    210185   300.000      .000    1  .83144E-02
>>    INITIAL COORDINATES ARE READ FROM FILE
>>    INITIAL VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>>       WITH TEMPERATURE TEMPI
>>    INITIAL COORDINATES ARE SHAKEN
>>    INITIAL VELOCITIES ARE SHAKEN
>>    FORMATTED OUTPUT OF:
>>       FINAL COORDINATES AND VELOCITIES
>>    BOLTZ VALUE IS IN KJ/MOL
>> 
>> STEP
>>    NSTLIM         T        DT
>>        10    .00000    .00200
>> 
>> BOUNDARY
>>       NTB    BOX(1)    BOX(2)    BOX(3)      BETA    NRDBOX
>>         0  3.368147  3.510064  3.559402    90.000         0
>>    NO PERIODICITY IS APPLIED
>> 
>> SUBMOLECULES
>>      NSPM
>>         1
>>        NSP(1..NSPM)
>>        16
>> 
>> TCOUPLE
>>       NTT     TEMP0      TAUT
>>         0   300.000      .100
>>         0   300.000      .100
>>         0   300.000      .100
>>
>>    NO PRESSURE COUPLING
>> 
>> CENTREOFMASS
>>    NDFMIN      NTCM      NSCM
>>         0         0   1000000
>>    INITIAL C.O.M. MOTION IS NOT REMOVED
>> 
>> PRINT
>>      NTPR      NTPL      NTPP
>>        20       100         0
>>    NO DIHEDRAL ANGLE MONITORING
>> 
>> SHAKE
>>       NTC       TOL
>>         1 .1000E-03
>>    NO SHAKE IS PERFORMED
>> 
>> FORCE
>>          NTF(1..10)
>>     BONDS  BND-ANGL  IMP-DIHE  DIHEDRAL   NONBOND
>>     H         H         H         H       CHG ALL
>>     1   1     1   1     1   1     1   1     1   1
>>      NEGR        NRE(1..NEGR)
>>         2        16      4144
>>    FORCE CALCULATION
>>    INCLUDES         BOND FORCES INVOLVING H-ATOMS
>>    INCLUDES         BOND FORCES NOT INVOLVING H-ATOMS
>>    INCLUDES         BOND ANGLE FORCES INVOLVING H-ATOMS
>>    INCLUDES         BOND ANGLE FORCES NOT INVOLVING H-ATOMS
>>    INCLUDES         IMPROPER DIHEDRAL FORCES INVOLVING H-ATOMS
>>    INCLUDES         IMPROPER DIHEDRAL FORCES NOT INVOLVING H-ATOMS
>>    INCLUDES         DIHEDRAL ANGLE FORCES INVOLVING H-ATOMS
>>    INCLUDES         DIHEDRAL ANGLE FORCES NOT INVOLVING H-ATOMS
>>    INCLUDES         CHARGES IN NON-BONDED INTERACTION
>>    INCLUDES         NON-BONDED INTERACTION
>> 
>> PLIST
>>      NTNB      NSNB     RCUTP     RCUTL
>>         1        10     1.000     1.000
>>    A PAIRLIST IS CONSTRUCTED IN THE FIRST STEP
>>    NO LONGRANGE CONTRIBUTION IS CALCULATED ON PL CONSTRUCTION
>> 
>> LONGRANGE
>>     EPSRF     APPAK      RCRF
>>    50.000      .000  .700E+10
>>    A REACTION FIELD CORRECTION IS APPLIED
>> 
>> POSREST
>>       NTR       CHO     NRDRX
>>         0 .2500E+05         1
>>    NO POSITION RESTRAINING
>>    ATOM RESTRAINING REFERENCE POSITIONS ARE READ FROM FILE
>>
>>    NO DISTANCE RESTRAINING
>>
>>    NO DIHEDRAL RESTRAINING
>>
>>    NO J-VALUE RESTRAINING
>>
>>    NO LOCAL ELEVATION INTERACTION
>>
>>    SIMULATION PERFORMED IN 3 DIMENSIONS
>>
>>    NO PERTURBATION PERFORMED
>> 
>> LATSUM
>>    NLATSM     KXMAX     KYMAX     KZMAX     K2MAX     ALPHA     PBETA
>> NGHTUP
>>         2        32        32        32         0      .800     1.330
>> 100000
>>     THE PPPM METHOD WILL BE USED
>> 
>> 
>> 
>> 3. O P T I O N A L   D A T A   F I L E S
>> 
>> 
>> 
>> 4. A T O M I C   C O O R D I N A T E S   A N D   V E L O C I T I E S
>> 
>> SYSTEMBLOCK
>>    NUMBER OF SOLUTE ATOMS         :      16
>>    NUMBER OF SOLVENT ATOMS        :    4128
>>    TOTAL NUMBER OF ATOMS          :    4144
>>    NUMBER OF SOLUTE CHARGE GROUPS :       6
>>    NUMBER OF SOLVENT CHARGE GROUPS:    1376
>>    TOTAL NUMBER OF CHARGE GROUPS  :    1382
>> END SYSTEMBLOCK
>> 
>> 1021
>> INITIAL CONFIGURATION TITLE
>>  coordinates generated from amber coord file
>>  rest_eq_reimaged.rst.1
>> 
>> 3D VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>> 
>> 
>> 
>> 5. I N I T I A L I Z E   R U N
>> 
>> PERFORMING A MOLECULAR DYNAMICS RUN
>> 
>> NDEGBLOCK
>>    NUMBER OF POSITIONALLY CONSTRAINED ATOMS   :       0
>>    NUMBER OF BONDS BETWEEN POS. CONSTR. ATOMS :       0
>>    NUMBER OF SOLUTE CONSTRAINTS               :       0
>>    NUMBER OF 3D SOLUTE (INT+ROT) D.O.F        :      45
>>    NUMBER OF 3D SOLUTE C.O.M. TRANSL. D.O.F   :       3
>>    NUMBER OF SOLVENT CONSTRAINTS              :       3
>>    NUMBER OF 3D SOLVENT D.O.F.                :    8256
>>    NUMBER OF 3D D.O.F. TO SUBTRACT (NDFMIN)   :       0
>>    NUMBER OF TOTAL D.O.F. IN 3D               :    8304
>> END NDEGBLOCK
>> 
>> BATHBLOCK
>>    TEMPERATURE COUPLING TO  0 BATH(S)
>> END BATHBLOCK
>> 
>> mm_SHAKE Solvent Coordinates, NITS =    1
>> mm_SHAKE Solvent Velocities,  NITS =   10
>> 
>> INITIAL TEMPERATURES ARE :
>>                           TOTAL  .30315128E+03
>>  SOLUTE INTERNAL AND ROTATIONAL  .37959703E+03
>>  SOLUTE C.O.M. TRANSLATIONAL     .67213419E+01
>>                        SOLVENT   .30284232E+03
>>                   4th DIMENSION  .00000000E+00
>> 
>>
>>   QUANTUM SYSTEM:
>>   NAX: 8
>>   NSX: 3
>>   FULL SYSTEM:
>>   NAX: 36
>>   NSX: 119
>> ***MM_QM_TOPO| SIZE OF THE PROGRAM IS 16692 KBytes ***
>> THE FOLLOWING INTERACTIONS ARE EXCLUDED FROM THE MM HAMILTONIAN:
>> 
>> BONDS INVOLVING HYDROGEN:
>>      14        15
>>      12        13
>>      10        11
>>       8         9
>>       5         6
>>       3         4
>>       1         2
>> 
>> BONDS NOT INVOLVING HYDROGEN:
>>      14        16
>>      12        14
>>      10        12
>>       8        10
>>       7         8
>>       7        16
>>       5         7
>>       3         5
>>       1         3
>>       1        16
>> 
>> ANGLES INVOLVING HYDROGEN:
>>      15        14        16
>>      13        12        14
>>      12        14        15
>>      11        10        12
>>      10        12        13
>>       9         8        10
>>       8        10        11
>>       7         8         9
>>       6         5         7
>>       4         3         5
>>       3         5         6
>>       2         1         3
>>       2         1        16
>>       1         3         4
>> 
>> ANGLES NOT INVOLVING HYDROGEN:
>>      12        14        16
>>      10        12        14
>>       8         7        16
>>       8        10        12
>>       7         8        10
>>       7        16        14
>>       5         7         8
>>       5         7        16
>>       3         1        16
>>       3         5         7
>>       1         3         5
>>       1        16         7
>>       1        16        14
>> 
>> PROPER DIHEDRALS INVOLVING HYDROGEN:
>>      13        12        14        15
>>      13        12        14        16
>>      11        10        12        13
>>      11        10        12        14
>>      10        12        14        15
>>       9         8         7        16
>>       9         8        10        11
>>       9         8        10        12
>>       8        10        12        13
>>       7         8        10        11
>>       7        16        14        15
>>       6         5         7         8
>>       6         5         7        16
>>       5         7         8         9
>>      16         1         3         4
>>       4         3         5         6
>>       4         3         5         7
>>       2         1         3         4
>>       2         1         3         5
>>       2         1        16         7
>>       2         1        16        14
>>       1         3         5         6
>>       1        16        14        15
>>      12        16        14        15
>>      10        14        12        13
>>       8        12        10        11
>>       7        10         8         9
>>       3         7         5         6
>> 
>> PROPER DIHEDRALS NOT INVOLVING HYDROGEN:
>>      10         8         7        16
>>      10        12        14        16
>>       8         7        16        14
>>       8        10        12        14
>>       7         8        10        12
>>       7        16        14        12
>>      16         1         3         5
>>       5         7         8        10
>>       5         7        16        14
>>       3         1        16         7
>>       3         1        16        14
>>       3         5         7         8
>>       3         5         7        16
>>       1         3         5         7
>>       1        16         7         5
>>       1        16         7         8
>>       1        16        14        12
>> 
>> IMPROPER DIHEDRALS INVOLVING HYDROGEN:
>> 
>> IMPROPER DIHEDRALS NOT INVOLVING HYDROGEN:
>> NON BONDED INTERACTIONS EXCLUDED FROM THE MM HAMITONIAN
>> NO ELECTROSTATIC EXCLUSION BETWEEN QM AND MM ATOMS
>> best 1 1 677.212792866984046
>> best 3 1 677.212792866983932
>> Cell Volume 677.212792866983932
>> 
>> NUMBER OF STATES:                                             22
>> NUMBER OF ELECTRONS:                                    44.00000
>> CHARGE:                                                   .00000
>> ELECTRON TEMPERATURE(KELVIN):                             .00000
>> OCCUPATION
>>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>> 
>> LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
>>    MAX. KRYLOV BLOCK SIZE                                     22
>>
>>    ============================================================
>>    |    Pseudopotential Report     Fri Feb 20 19:18:54 1998   |
>>    ------------------------------------------------------------
>>    |  Atomic Symbol                   :   H                   |
>>    |  Atomic Number                   :   1                   |
>>    |  Number of core states           :   0                   |
>>    |  Number of valence states        :   1                   |
>>    |  Exchange-Correlation Functional :                       |
>>    |     Slater exchange :   .6667                            |
>>    |     LDA correlation : Ceperley-Alder                     |
>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>    |  Electron Configuration :   N   L  Occupation            |
>>    |                             1   S     .7000              |
>>    |  Full Potential Total Energy     -.474341                |
>>    |  Trouiller-Martins normconserving PP                     |
>>    |     n    l        rc       energy                        |
>>    |     1    S     .5000      -.37203                        |
>>    |     2    P     .3828      -.37203                        |
>>    |  Number of Mesh Points :   511                           |
>>    |  Pseudoatom Total Energy    -.367794                     |
>>    ============================================================
>>
>>    ============================================================
>>    |    Pseudopotential Report                                |
>>    ------------------------------------------------------------
>>    |  Atomic Symbol                   :   N                   |
>>    |  Atomic Number                   :   7                   |
>>    |  Number of core states           :   1                   |
>>    |  Number of valence states        :   2                   |
>>    |  Exchange-Correlation Functional :                       |
>>    |     Slater exchange :  0.6667                            |
>>    |     LDA correlation : Ceperley-Alder                     |
>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>    |  Electron Configuration :   N   L  Occupation            |
>>    |                             1   S    2.0000              |
>>    |                             2   S    2.0000              |
>>    |                             2   P    3.0000              |
>>    |  Full Potential Total Energy =      -54.420394           |
>>    |  Trouiller-Martins normconserving PP                     |
>>    |     n    l        rc       energy                        |
>>    |     2    S    1.1200     -0.68204                        |
>>    |     2    P    1.1200     -0.26082                        |
>>    |     3    D    0.6031     -0.26082                        |
>>    |  Number of Mesh Points :   624                           |
>>    |  Pseudoatom Total Energy =   -9.647042                   |
>>    ============================================================
>>
>>    ============================================================
>>    |    Pseudopotential Report                                |
>>    ------------------------------------------------------------
>>    |  Atomic Symbol                   :   C                   |
>>    |  Atomic Number                   :   6                   |
>>    |  Number of core states           :   1                   |
>>    |  Number of valence states        :   2                   |
>>    |  Exchange-Correlation Functional :                       |
>>    |     Slater exchange :  0.6667                            |
>>    |     LDA correlation : Ceperley-Alder                     |
>>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>>    |  Electron Configuration :   N   L  Occupation            |
>>    |                             1   S    2.0000              |
>>    |                             2   S    2.0000              |
>>    |                             2   P    2.0000              |
>>    |  Full Potential Total Energy   -37.748221                |
>>    |  Trouiller-Martins normconserving PP                     |
>>    |     n    l        rc       energy                        |
>>    |     2    S    1.2300     -0.50506                        |
>>    |     2    P    1.2300     -0.19451                        |
>>    |     3    D    0.7159     -0.19451                        |
>>    |  Number of Mesh Points :   615                           |
>>    |  Pseudoatom Total Energy   -5.361882                     |
>>    ============================================================
>> 
>> ****************************************************************
>> *   ATOM       MASS   RAGGIO NLCC              PSEUDOPOTENTIAL *
>> *      H     1.0080   1.2000   NO    KLEINMAN      S  NONLOCAL *
>> *                                                  P     LOCAL *
>> *      N    14.0067   1.2000   NO    KLEINMAN      S  NONLOCAL *
>> *                                                  P  NONLOCAL *
>> *                                                  D     LOCAL *
>> *      C    12.0112   1.2000   NO    KLEINMAN      S  NONLOCAL *
>> *                                                  P  NONLOCAL *
>> *                                                  D     LOCAL *
>> ****************************************************************
>> 
>> 
>> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>>  NCPU     NGW     NHG  PLANES  GXRAYS  HXRAYS ORBITALS Z-PLANES
>>     0   13225  105849      30     670    2674       5       1
>>     1   13229  105829      30     670    2674       6       1
>>     2   13224  105802      30     669    2673       5       1
>>     3   13218  105844      30     672    2672       6       1
>>                G=0 COMPONENT ON PROCESSOR :     2
>> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>> 
>> ***    LOADPA| SIZE OF THE PROGRAM IS 23728 KBytes ***
>> 
>> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
>> NUMBER OF CPUS PER TASK                                        1
>> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
>> 
>> ***     RGGEN| SIZE OF THE PROGRAM IS 26348 KBytes ***
>> 
>> ************************** SUPERCELL ***************************
>> THIS IS AN ISOLATED SYSTEM CALCULATION
>> POISSON EQUATION SOLVER  :                   TUCKERMAN & MARTYNA
>> SHORT RANGE POTENTIAL LENGTH * BOX LENGTH                  7.000
>> SYMMETRY:                                           ORTHORHOMBIC
>> LATTICE CONSTANT(a.u.):                                 22.28234
>> CELL DIMENSION:  22.2823   .9145  1.0577   .0000   .0000   .0000
>> VOLUME(OMEGA IN BOHR^3):                             10700.98252
>> LATTICE VECTOR A1(BOHR):           22.2823      .0000      .0000
>> LATTICE VECTOR A2(BOHR):             .0000    20.3770      .0000
>> LATTICE VECTOR A3(BOHR):             .0000      .0000    23.5680
>> RECIP. LAT. VEC. B1(2Pi/BOHR):       .0449      .0000      .0000
>> RECIP. LAT. VEC. B2(2Pi/BOHR):       .0000      .0491      .0000
>> RECIP. LAT. VEC. B3(2Pi/BOHR):       .0000      .0000      .0424
>> REAL SPACE MESH:                   120          110          126
>> WAVEFUNCTION CUTOFF(RYDBERG):                           70.00000
>> DENSITY CUTOFF(RYDBERG):          (DUAL= 4.00)         280.00000
>> NUMBER OF PLANE WAVES FOR WAVEFUNCTION CUTOFF:             52896
>> NUMBER OF PLANE WAVES FOR DENSITY CUTOFF:                 423324
>> ****************************************************************
>> 
>> ***  RINFORCE| SIZE OF THE PROGRAM IS 39620 KBytes ***
>> ***    FFTPRP| SIZE OF THE PROGRAM IS 53344 KBytes ***
>> ***   CLUSTER| SIZE OF THE PROGRAM IS 61628 KBytes ***
>> 
>> GENERATE ATOMIC BASIS SET
>>      H        SLATER ORBITALS
>>        1S        ALPHA=   1.0000      OCCUPATION= 1.00
>>      N        SLATER ORBITALS
>>        2S        ALPHA=   1.9237      OCCUPATION= 2.00
>>        2P        ALPHA=   1.9170      OCCUPATION= 3.00
>>      C        SLATER ORBITALS
>>        2S        ALPHA=   1.6083      OCCUPATION= 2.00
>>        2P        ALPHA=   1.5679      OCCUPATION= 2.00
>> 
>> 
>> INITIALIZATION TIME:                                2.96 SECONDS
>> 
>> 
>> *********************** LINEAR RESPONSE ************************
>> Step size for numeric dmu/dn :                          .500E-03
>> Number of calculations for dmu/dn :                            2
>> Maximum number of optimisation steps:                       1000
>> Threshold for Hessian (Preconditioner)                     .5000
>> Optimizer for LR equations                             AUTOMATIC
>>                    Size of ODIIS buffer                       10
>>                    Size of ZDIIS buffer                        4
>>                    Switch from PCG to ODIIS at         .1000E+00
>>                    Switch to full preconditioning at   .1000E-02
>> Step length                                                .1000
>> Convergence criteria                                   .1000E-04
>> ****************************************************************
>> 
>> ***************************  TDDFT  ****************************
>> Step size for numeric dmu/dn :                          .500E-03
>> Number of calculations for dmu/dn :                            2
>> Diagonalization Method                    NON-HERMITIAN DAVIDSON
>>          Max. number of iterations                           200
>>          Convergence criteria                           .100E-06
>>          Max. size of Davidson matrix                         69
>> Number of Singlet States                                       5
>> Forces calculated for state                                    1
>> ****************************************************************
>> RV30! NUMBER OF STATES   HAS CHANGED                     22   27
>> 
>> RESTART INFORMATION READ ON FILE                       ./RESTART
>> ***     PHFAC| SIZE OF THE PROGRAM IS 85536 KBytes ***
>> ATRHO| CHARGE(R-SPACE):   44.000000      (G-SPACE):   44.000000
>> EWALD| SUM IN REAL SPACE OVER                      1* 1* 1 CELLS
>> 
>> RE-CENTERING QM SYSTEM AT EVERY TIME STEP
>>
>>   BOX TOLERANCE [a.u.]   8.00000000000000000
>> 
>> BOX SIZE [a.u.]                     QM SYSTEM SIZE [a.u.]
>>  X DIRECTION:  CELLDIM =    22.2823; XMAX-XMIN=     4.3488
>>  Y DIRECTION:  CELLDIM =    20.3770; YMAX-YMIN=    11.0220
>>  Z DIRECTION:  CELLDIM =    23.5680; ZMAX-ZMIN=    10.3570
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 124624 KBytes ***
>> ================================================================
>> ==                        REFERENCE POINT                     ==
>> ================================================================
>> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124736 KBytes ***
>>
>>     !!!!!!!!!!!!!!!!!! WARNING !!!!!!!!!!!!!!!!!!!
>>     THE QM SYSTEM DOES NOT HAVE AN INTEGER CHARGE.
>>     A COMPENSATING CHARGE OF   -.000010 HAS BEEN
>>     DISTRIBUTED OVER THE NN ATOMS.
>>     !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>> 
>> MM_ELSTAT: ELECTROSTATIC INTERACTION NN LIST UPDATED
>> NN ATOMS =      496,  ESP COUPLED  ATOMS =      441
>> 
>> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124920 KBytes ***
>> ***MM_CHARGES| SIZE OF THE PROGRAM IS 125572 KBytes ***
>> NBPML:     66387 ELEMENTS IN THE PAIRLIST
>> 
>> PPPM USING NAG FFT ROUTINE , TWO real*8 GRIDS, PACKED GRID
>> AND A SPHERICAL HAT FUNCTION
>> 
>> GHAT FUNCTION HAS BEEN CALCULATED USING
>> PBETA =     1.333 RESULTING IN Q =     .901232E-06
>> 
>> A2 EVALUATED WITH LMAX =   44   TOL =  .00000047
>> CONSTANT A1       =    -.01274135
>> CONSTANT A2       =    1.69768358
>> CONSTANT A3       =   -2.50000000
>> CONSTANT XI       =   -2.74523413 = LX*(A1+A2+A3)
>> EPSFAC*[SUM Q]**2 =   .138935E-07
>> EPSFAC*SUM Q**2   =   .199556E+06
>> ESELFL            =  -.813248E+05
>> 
>> 
>> TOTAL INTEGRATED ELECTRONIC DENSITY
>>    IN G-SPACE =                                        44.000000
>>    IN R-SPACE =                                        44.000000
>> 
>> (K+E1+L+N+X)           TOTAL ENERGY =          -63.33387972 A.U.
>> (K)                  KINETIC ENERGY =           45.38116319 A.U.
>> (E1=A-S+R)     ELECTROSTATIC ENERGY =          -49.67916341 A.U.
>> (S)                           ESELF =           53.19230405 A.U.
>> (R)                             ESR =            3.06373807 A.U.
>> (L)    LOCAL PSEUDOPOTENTIAL ENERGY =          -41.17408788 A.U.
>> (N)      N-L PSEUDOPOTENTIAL ENERGY =            4.84142028 A.U.
>> (X)     EXCHANGE-CORRELATION ENERGY =          -18.95438051 A.U.
>>         GRADIENT CORRECTION ENERGY =             -.28039967 A.U.
>> 
>> NFI      GEMAX       CNORM           ETOT        DETOT      TCPU
>>   1  1.582E-03   1.941E-04     -63.333880    0.000E+00     11.46
>>   2  7.736E-04   7.495E-05     -63.339037   -5.157E-03      1.28
>>   3  5.034E-04   4.193E-05     -63.339617   -5.801E-04      1.29
>>   4  3.197E-04   2.216E-05     -63.339799   -1.819E-04      1.30
>>   5  1.613E-04   1.182E-05     -63.339857   -5.781E-05      1.31
>>   6  8.951E-05   6.529E-06     -63.339877   -2.043E-05      1.32
>>   7  5.419E-05   4.024E-06     -63.339885   -8.035E-06      1.32
>>   8  3.332E-05   2.665E-06     -63.339888   -3.376E-06      1.33
>>   9  1.798E-05   1.736E-06     -63.339890   -1.479E-06      1.34
>>  10  1.145E-05   1.139E-06     -63.339891   -7.199E-07      1.35
>>  11  8.176E-06   7.835E-07     -63.339891   -3.883E-07      1.34
>> 
>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.1
>> 
>> TIME FOR MINIMUM STRUCTURE :                      28.598 SECONDS
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 152720 KBytes ***
>> ================================================================
>> ==                END OF REFERENCE CALCULATION                ==
>> ==               GENERATE INITIAL GUESS VECTORS               ==
>> ================================================================
>> 
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 152724 KBytes ***
>> 
>> <<<<<<<<<<<<<<<<<<< LANCZOS DIAGONALIZATION <<<<<<<<<<<<<<<<<<<<
>> >> TIME FOR INITIAL SUBSPACE DIAGONALIZATION:                .57
>> >> CYCLE     NCONV        B2MAX        B2MIN     #HPSI      TIME
>>        1        22    7.534E-02    4.315E-10      2.30       .83
>>        2        22    6.405E-02    4.314E-10      1.30       .82
>>        3        22    3.739E-02    4.312E-10      1.30       .82
>>        4        22    3.703E-02    4.311E-10      1.30       .83
>>        5        22    2.207E-02    4.309E-10      1.30       .83
>>        6        22    2.649E-02    4.309E-10      1.30       .82
>>        7        22    2.905E-02    4.308E-10      1.30       .82
>>        8        22    3.196E-02    4.308E-10      1.30       .82
>>        9        22    3.057E-02    4.307E-10      1.30       .82
>>       10        22    2.965E-02    4.307E-10      1.30       .82
>>       11        22    2.497E-02    4.306E-10      1.30       .82
>>       12        22    2.201E-02    4.306E-10      1.30       .82
>>       13        22    1.723E-02    4.306E-10      1.30       .83
>>       14        22    1.456E-02    4.306E-10      1.30       .82
>>       15        22    1.117E-02    4.305E-10      1.30       .82
>>       16        22    8.860E-03    4.305E-10      1.30       .82
>>       17        22    4.720E-03    4.305E-10      1.30       .82
>>       18        22    6.282E-03    4.305E-10      1.30       .82
>>       19        22    5.300E-03    4.305E-10      1.30       .82
>>       20        22    4.964E-03    4.305E-10      1.30       .82
>>       21        22    4.155E-03    4.305E-10      1.30       .82
>>       22        22    3.913E-03    4.305E-10      1.30       .82
>>       23        22    3.321E-03    4.305E-10      1.30       .82
>>       24        22    3.148E-03    4.305E-10      1.30       .82
>>       25        22    2.691E-03    4.305E-10      1.30       .82
>>       26        22    2.556E-03    4.305E-10      1.30       .82
>>       27        22    2.192E-03    4.305E-10      1.30       .82
>>       28        22    2.081E-03    4.305E-10      1.30       .82
>>       29        22    1.788E-03    4.305E-10      1.30       .82
>>       30        22    1.695E-03    4.305E-10      1.30       .82
>>       31        22    1.458E-03    4.305E-10      1.30       .82
>>       32        22    1.381E-03    4.305E-10      1.30       .82
>>       33        22    1.190E-03    4.305E-10      1.30       .82
>>       34        22    1.127E-03    4.305E-10      1.30       .82
>>       35        22    1.023E-03    4.305E-10      1.30       .82
>>       36        22    9.216E-04    4.305E-10      1.30       .86
>>       37        22    1.092E-03    4.305E-10      1.30       .82
>>       38        22    9.192E-04    4.305E-10      1.30       .82
>>       39        22    1.165E-03    4.305E-10      1.30       .82
>>       40        22    9.791E-04    4.305E-10      1.30       .82
>>       41        22    1.239E-03    4.305E-10      1.30       .82
>>       42        23    1.039E-03    4.305E-10      1.11       .65
>>       43        23    1.312E-03    4.305E-10      1.04       .58
>>       44        23    1.097E-03    4.305E-10      1.04       .58
>>       45        23    1.381E-03    4.305E-10      1.04       .58
>>       46        23    1.150E-03    4.305E-10      1.04       .58
>>       47        23    1.443E-03    4.305E-10      1.04       .58
>>       48        23    1.197E-03    4.305E-10      1.04       .58
>>       49        23    1.494E-03    4.305E-10      1.04       .58
>>       50        23    1.233E-03    4.305E-10      1.04       .58
>>       51        23    1.533E-03    4.305E-10      1.04       .58
>>       52        23    1.258E-03    4.305E-10      1.04       .58
>>       53        23    1.556E-03    4.305E-10      1.04       .59
>>       54        23    1.270E-03    4.305E-10      1.04       .58
>>       55        23    1.562E-03    4.305E-10      1.04       .58
>>       56        23    1.267E-03    4.305E-10      1.04       .58
>>       57        23    1.550E-03    4.305E-10      1.04       .58
>>       58        23    1.249E-03    4.305E-10      1.04       .58
>>       59        23    1.520E-03    4.305E-10      1.04       .58
>>       60        23    1.218E-03    4.305E-10      1.04       .58
>>       61        23    1.473E-03    4.305E-10      1.04       .58
>>       62        23    1.173E-03    4.305E-10      1.04       .58
>>       63        23    1.411E-03    4.305E-10      1.04       .58
>>       64        24    1.117E-03    4.305E-10       .85       .59
>>       65        24    1.337E-03    4.305E-10       .78       .59
>>       66        24    1.052E-03    4.305E-10       .85       .58
>>       67        24    1.254E-03    4.305E-10       .78       .59
>>       68        24    9.810E-04    4.305E-10       .78       .59
>>       69        24    1.164E-03    4.305E-10       .85       .58
>>       70        24    9.057E-04    4.305E-10       .78       .59
>>       71        24    1.070E-03    4.305E-10       .78       .59
>>       72        24    8.286E-04    4.305E-10       .78       .59
>>       73        24    9.758E-04    4.305E-10       .78       .59
>>       74        24    7.518E-04    4.305E-10       .78       .59
>>       75        24    8.826E-04    4.305E-10       .78       .59
>>       76        24    6.769E-04    4.305E-10       .78       .59
>>       77        24    7.926E-04    4.305E-10       .78       .61
>>       78        24    6.053E-04    4.305E-10       .78       .60
>>       79        24    7.073E-04    4.305E-10       .78       .59
>>       80        24    5.380E-04    4.305E-10       .78       .59
>>       81        24    6.276E-04    4.305E-10       .78       .59
>>       82        24    4.756E-04    4.305E-10       .78       .59
>>       83        24    5.542E-04    4.305E-10       .78       .59
>>       84        24    4.186E-04    4.305E-10       .78       .59
>>       85        24    4.873E-04    4.305E-10       .78       .59
>>       86        24    3.669E-04    4.305E-10       .78       .59
>>       87        24    4.271E-04    4.305E-10       .78       .59
>>       88        24    3.207E-04    4.305E-10       .78       .59
>>       89        24    3.733E-04    4.305E-10       .78       .59
>>       90        24    2.797E-04    4.305E-10       .78       .59
>>       91        24    3.257E-04    4.305E-10       .78       .59
>>       92        24    2.435E-04    4.305E-10       .78       .59
>>       93        24    2.838E-04    4.305E-10       .78       .59
>>       94        24    2.118E-04    4.305E-10       .78       .59
>>       95        24    2.471E-04    4.305E-10       .78       .59
>>       96        24    1.842E-04    4.305E-10       .78       .59
>>       97        24    2.152E-04    4.305E-10       .78       .59
>>       98        24    1.603E-04    4.305E-10       .78       .59
>>       99        24    1.875E-04    4.305E-10       .78       .59
>>      100        24    1.395E-04    4.305E-10       .78       .59
>>      101        24    1.635E-04    4.305E-10       .78       .59
>>      102        24    1.216E-04    4.305E-10       .78       .59
>>      103        24    1.428E-04    4.305E-10       .78       .59
>>      104        24    1.061E-04    4.305E-10       .78       .59
>>      105        24    1.248E-04    4.305E-10       .78       .59
>>      106        24    9.275E-05    4.305E-10       .78       .59
>>      107        24    1.093E-04    4.305E-10       .78       .59
>>      108        24    8.121E-05    4.305E-10       .78       .59
>>      109        24    9.585E-05    4.305E-10       .78       .59
>>      110        24    7.123E-05    4.305E-10       .78       .59
>>      111        24    8.422E-05    4.305E-10       .78       .59
>>      112        24    6.259E-05    4.305E-10       .78       .59
>>      113        24    7.413E-05    4.305E-10       .78       .59
>>      114        24    5.510E-05    4.305E-10       .78       .59
>>      115        24    6.537E-05    4.305E-10       .78       .59
>>      116        24    4.860E-05    4.305E-10       .78       .59
>>      117        24    5.774E-05    4.305E-10       .78       .59
>>      118        24    4.294E-05    4.305E-10       .78       .59
>>      119        24    5.109E-05    4.305E-10       .78       .59
>>      120        24    3.801E-05    4.305E-10       .78       .59
>>      121        24    4.528E-05    4.305E-10       .78       .60
>>      122        24    3.370E-05    4.305E-10       .78       .59
>>      123        24    4.020E-05    4.305E-10       .78       .59
>>      124        24    2.993E-05    4.305E-10       .78       .59
>>      125        24    3.575E-05    4.305E-10       .78       .59
>>      126        24    2.662E-05    4.305E-10       .78       .59
>>      127        24    3.183E-05    4.305E-10       .78       .59
>>      128        24    2.371E-05    4.305E-10       .78       .59
>>      129        24    2.838E-05    4.305E-10       .78       .59
>>      130        24    2.115E-05    4.305E-10       .78       .59
>>      131        24    2.535E-05    4.305E-10       .78       .59
>>      132        24    1.890E-05    4.305E-10       .78       .59
>>      133        24    2.266E-05    4.305E-10       .78       .59
>>      134        24    1.690E-05    4.305E-10       .78       .59
>>      135        24    2.029E-05    4.305E-10       .78       .59
>>      136        24    1.514E-05    4.305E-10       .78       .59
>>      137        24    1.818E-05    4.305E-10       .78       .59
>>      138        24    1.357E-05    4.305E-10       .78       .59
>>      139        24    1.632E-05    4.305E-10       .78       .59
>>      140        24    1.218E-05    4.305E-10       .78       .59
>>      141        24    1.466E-05    4.305E-10       .78       .59
>>      142        24    1.095E-05    4.305E-10       .78       .59
>>      143        24    1.318E-05    4.305E-10       .78       .59
>>      144        24    9.846E-06    4.305E-10       .78       .59
>>      145        25    1.186E-05    4.305E-10       .63       .45
>>      146        25    8.861E-06    4.305E-10       .52       .35
>>      147        25    1.069E-05    4.305E-10       .52       .35
>>      148        25    7.987E-06    4.305E-10       .52       .35
>>      149        25    9.644E-06    4.305E-10       .52       .35
>>      150        25    7.205E-06    4.305E-10       .52       .35
>>      151        25    8.706E-06    4.305E-10       .52       .35
>>      152        25    6.505E-06    4.305E-10       .52       .35
>>      153        25    7.866E-06    4.305E-10       .52       .35
>>      154        25    5.877E-06    4.305E-10       .52       .35
>>      155        25    7.113E-06    4.305E-10       .52       .35
>>      156        25    5.314E-06    4.305E-10       .52       .35
>>      157        25    6.436E-06    4.305E-10       .52       .35
>>      158        25    4.809E-06    4.305E-10       .52       .35
>>      159        25    5.828E-06    4.305E-10       .52       .35
>>      160        26    4.354E-06    4.305E-10       .33       .33
>>      161        26    5.277E-06    4.305E-10       .26       .32
>>      162        26    3.948E-06    4.305E-10       .26       .32
>>      163        26    4.785E-06    4.305E-10       .26       .32
>>      164        26    3.582E-06    4.305E-10       .26       .32
>>      165        26    4.341E-06    4.305E-10       .26       .32
>>      166        26    3.252E-06    4.305E-10       .26       .32
>>      167        26    3.940E-06    4.305E-10       .26       .32
>>      168        26    2.953E-06    4.305E-10       .26       .32
>>      169        26    3.578E-06    4.305E-10       .26       .32
>>      170        26    2.684E-06    4.305E-10       .26       .32
>>      171        26    3.251E-06    4.305E-10       .26       .32
>>      172        26    2.440E-06    4.305E-10       .26       .32
>>      173        26    2.955E-06    4.305E-10       .26       .32
>>      174        26    2.220E-06    4.305E-10       .26       .32
>>      175        26    2.688E-06    4.305E-10       .26       .32
>>      176        26    2.020E-06    4.305E-10       .26       .32
>>      177        26    2.446E-06    4.305E-10       .26       .32
>>      178        27    9.966E-07    4.305E-10       .19       .24
>> 
>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.2
>> 
>> EIGENVALUES(EV) AND OCCUPATION:
>>     1    -23.7335233       2.00000000        2    -19.9290529
>> 2.00000000
>>     3    -18.3902715       2.00000000        4    -17.2606686
>> 2.00000000
>>     5    -16.6676136       2.00000000        6    -14.4741075
>> 2.00000000
>>     7    -13.7418694       2.00000000        8    -13.2132617
>> 2.00000000
>>     9    -12.2511591       2.00000000       10    -10.7230135
>> 2.00000000
>>    11    -10.4904816       2.00000000       12     -9.8090984
>> 2.00000000
>>    13     -9.5347383       2.00000000       14     -9.4073271
>> 2.00000000
>>    15     -9.0064959       2.00000000       16     -8.5053970
>> 2.00000000
>>    17     -7.5545624       2.00000000       18     -7.3121930
>> 2.00000000
>>    19     -7.0592376       2.00000000       20     -5.9706919
>> 2.00000000
>>    21     -4.7579865       2.00000000       22     -4.1479453
>> 2.00000000
>>    23      -.5969499        .00000000       24      -.3720761
>> .00000000
>>    25       .3650124        .00000000       26       .3724612
>> .00000000
>>    27       .4402542        .00000000
>> CHEMICAL POTENTIAL =                            -4.1479469673 EV
>> ================================================================
>> ==                END OF STATE INITIALIZATION                 ==
>> ================================================================
>> 
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 161824 KBytes ***
>> ==                      SINGLET STATES                        ==
>> NUMBER OF STATES TO BE INITIALIZED                             5
>> TOTAL NUMBER OF TEST VECTORS                                  10
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 207492 KBytes ***
>> ================================================================
>> ==   NON-HERMITIAN DAVIDSON DIAGONALISATION OF TDDFT MATRIX   ==
>> ================================================================
>> Number of states initialized                                  10
>> Time for initialization                                    10.60
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           0            10        .15845565E-01       25.20
>>     2           0            20        .11376972E-01       25.99
>>     3           0            30        .86052357E-02       27.10
>>     4           0            40        .28366033E-01       28.49
>>     5           0            50        .86824638E-02       30.19
>>     6           0            60        .47491577E-02       32.24
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           0            10        .32825954E-02       24.97
>>     2           0            20        .12877815E-02       25.77
>>     3           0            30        .12378764E-02       26.84
>>     4           0            40        .86346371E-03       28.24
>>     5           0            50        .63720455E-03       29.94
>>     6           0            60        .47484767E-03       32.01
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           0            10        .38477936E-03       24.96
>>     2           0            20        .34007730E-03       25.76
>>     3           0            30        .33896785E-03       26.84
>>     4           0            40        .33335272E-03       28.25
>>     5           0            50        .32908877E-03       29.98
>>     6           0            60        .32421071E-03       32.03
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           0            10        .32168820E-03       24.94
>>     2           0            20        .31938491E-03       25.73
>>     3           0            30        .31889769E-03       26.82
>>     4           0            40        .31755839E-03       28.23
>>     5           0            50        .31660912E-03       29.93
>>     6           0            60        .31638267E-03       32.05
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           0            10        .13172735E-02       24.97
>>     2           0            20        .38287214E-03       25.75
>>     3           0            30        .37349499E-03       26.85
>>     4           0            40        .31639432E-03       28.22
>>     5           0            50        .31617519E-03       29.93
>>     6           0            60        .31599779E-03       32.01
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>>     1           1            10        .31589822E-03       24.97
>>     2           2            18        .31586838E-03       20.56
>>     3           3            24        .82191816E-04       16.06
>>     4           3            28        .91936763E-04       11.39
>>     5           3            32        .10357358E-03       11.81
>>     6           3            36        .10676478E-03       12.30
>>     7           3            40        .14164920E-03       12.80
>>     8           3            44        .21147763E-03       13.39
>>     9           3            48        .14641292E-03       13.98
>>    10           3            52        .11876749E-03       14.70
>>    11           3            56        .94534219E-04       15.42
>>    12           3            60        .71650384E-04       16.20
>>    13           3            64        .59567744E-04       17.03
>>    14           3            68        .51910420E-04       17.89
>> Number of states initialized                                  10
>> Time for initialization                                      .30
>>
>>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>> !! DAVIDSON| NOT ALL ROOTS ARE CONVERGED                      !!
>> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>> 
>> 
>> STATE=  1                               EIGENVALUE=     3.725 eV
>> 
>> 
>> STATE=  2                               EIGENVALUE=     4.108 eV
>> 
>> 
>> STATE=  3                               EIGENVALUE=     4.346 eV
>> 
>> 
>> STATE=  4                               EIGENVALUE=     4.485 eV
>> 
>> 
>> STATE=  5                               EIGENVALUE=     4.508 eV
>> ***   SPECTRA| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>> 
>> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.3
>> 
>> ================================================================
>>                      BIG MEMORY ALLOCATIONS
>> PME              3570830                CB              40733000
>> CSCR             4655200                C1               5819000
>> CATOM            1137350                CSP             40733000
>> GDE               892707                CSM             40733000
>> SCR              3482773                CR               1163800
>> ----------------------------------------------------------------
>> [PEAK NUMBER  110]      PEAK MEMORY    144366981 = 1154.9 MBytes
>> ================================================================
>> 
>> 
>> ****************************************************************
>> *                                                              *
>> *                            TIMING                            *
>> *                                                              *
>> ****************************************************************
>> SUBROUTINE            CALLS         CPU TIME        ELAPSED TIME
>>     GCENER              883           191.15              191.15
>>    FFT-G/S           142837           141.20              141.21
>>     FWFFTN            12010           136.94              136.94
>>   S_INVFFT            14045           127.79              127.78
>>    INVFFTN            12153           110.91              110.91
>>      FWFFT             3981            75.31               75.31
>>       VPSI             2553            53.65               53.66
>>    S_FWFFT             4685            53.23               53.23
>>     INVFFT             3098            46.18               46.18
>>    FNONLOC             2118            42.13               42.13
>>     XCENER              883            35.73               35.73
>>     RNLSM1             2118            27.13               27.13
>>     FFTCOM            25809            26.48               26.48
>>    RHO1OFR              435            25.46               25.46
>>   N-FFTCOM            24163            17.30               17.30
>>     GRADEN              883            12.82               12.82
>>      OVLAP             1288            11.13               11.13
>> MM_ELSTAT_                1             8.58                8.58
>>     ROTATE             1287             7.41                7.41
>>      PHASE             7079             7.29                7.30
>>      DD_XC              435             5.70                5.70
>>   FRIESNER                1             4.99                4.99
>>  VTDOFRHO1              435             4.82                4.82
>>     GLOSUM            30274             3.66                3.65
>>     OVLAP2              383             2.93                2.93
>>       HPSI             2090             2.33                2.33
>> ----------------------------------------------------------------
>> TOTAL TIME                           1182.25             1182.25
>> ****************************************************************
>>
>>       CPU TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
>>   ELAPSED TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
>> ***      CPMD| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>> 
>> PROGRAM CPMD ENDED AT:   Mon Oct  1 22:52:38 2007
>> 
>> 
>> ================================================================
>> = COMMUNICATION TASK  AVERAGE MESSAGE LENGTH  NUMBER OF CALLS  =
>> = SEND/RECEIVE              133074. BYTES               2559.  =
>> = BROADCAST                  21267. BYTES                639.  =
>> = GLOBAL SUMMATION             591. BYTES              32713.  =
>> = GLOBAL MULTIPLICATION          0. BYTES                  1.  =
>> = ALL TO ALL COMM          1834756. BYTES              49972.  =
>> =                             PERFORMANCE          TOTAL TIME  =
>> = SEND/RECEIVE              897.740  MB/S            .379 SEC  =
>> = BROADCAST                 432.366  MB/S            .031 SEC  =
>> = GLOBAL SUMMATION            9.594  MB/S           4.032 SEC  =
>> = GLOBAL MULTIPLICATION        .000  MB/S            .001 SEC  =
>> = ALL TO ALL COMM          2101.717  MB/S          43.625 SEC  =
>> = SYNCHRONISATION                                    .009 SEC  =
>> ================================================================
>> 
>> _______________________________________________
>> CPMD-list mailing list
>> CPMD-list at cpmd.org
>> http://cpmd.org/mailman/listinfo/cpmd-list
>> 
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