[CPMD-list] Full response version of TDDFT

Juerg Hutter hutter at pci.uzh.ch
Wed Jan 16 09:49:00 CET 2008


Hi

oscillator strength with the full LR TDDFT has never been
implemented in CPMD.
The implementation for the Tamm-Dancoff approximation
for periodic system (works also for non-periodic) can be found
in the paper by Bernasconi and Sprik.

regards

Juerg Hutter

----------------------------------------------------------
Juerg Hutter                   Phone : ++41 44 635 4491
Physical Chemistry Institute   FAX   : ++41 44 635 6838
University of Zurich           E-mail: hutter at pci.uzh.ch
Winterthurerstrasse 190
CH-8057 Zurich, Switzerland
----------------------------------------------------------


On Wed, 16 Jan 2008, Emiliano Ippoliti wrote:

> Dear CPMD users,
>
> I'm using the TDDFT routines implemented in the last version of CPMD to
> calculate electronic excitation energies in QM/MM simulations. Recently I
> have tried to use the keyword LR-TDDFT to perform the "exact" calculation
> without the Tamm-Dancoff approximation.
> What I don't understand is the fact that in the output file I cannot find
> the oscillator strength (the "f") together with the value of the excitation
> energies. What is the reason? How can I have a measure of the intensity of
> excitation transitions? How is calculate the oscillator strength in the
> default setup with the Tamm-Dancoff approximation?
> Below, I report an example of output file.
>
> Best regards,
> Emiliano
>
>
> ...
>
>
> ****************************************************************************
> **
> **                              INPUT FILE
> **
>
> ****************************************************************************
> **
> ** &QMMM
> **
> ** TOPOLOGY
> **
> ** gromos.top
> **
> ** COORDINATES
> **
> ** gromos.g96
> **
> ** INPUT
> **
> ** gromos.inp
> **
> ** ELECTROSTATIC COUPLING LONG RANGE
> **
> ** RCUT_NN
> **
> ** 10
> **
> ** RCUT_MIX
> **
> ** 15
> **
> ** RCUT_ESP
> **
> ** 20
> **
> ** UPDATE LIST
> **
> ** 100
> **
> ** SPLIT
> **
> ** SAMPLE_INTERACTING
> **
> ** 1000
> **
> ** AMBER
> **
> ** ARRAYSIZES
> **
> **
> **
> **  MAXATT 17
> **
> **  MAXAA2 11
> **
> **  MAXNRP 26
> **
> **  MAXNBT 21
> **
> **  MAXBNH 17
> **
> **  MAXBON 20
> **
> **  MAXTTY 23
> **
> **  MXQHEH 24
> **
> **  MAXTH  23
> **
> **  MAXQTY 10
> **
> **  MAXHIH 10
> **
> **  MAXQHI 10
> **
> **  MAXPTY 15
> **
> **  MXPHIH 38
> **
> **  MAXPHI 27
> **
> **  MAXCAG 16
> **
> **  MAXAEX 20044
> **
> **  MXEX14 42
> **
> **
> **
> ** END ARRAYSIZES
> **
> ** &END
> **
> **
> **
> ** &CPMD
> **
> **  RESTART WAVEFUNCTION COORDINATES
> **
> **  QMMM
> **
> **  ELECTRONIC SPECTRA
> **
> **  LANCZOS DIAGONALIZATION
> **
> **  LANCZOS PARAMETER
> **
> **   3000 8 0 1E-6
> **
> **  MAXSTEP
> **
> **   999999
> **
> **  COMPRESS WRITE32
> **
> **  MIRROR
> **
> **  RESTFILE
> **
> **   3
> **
> ** &END
> **
> **
> **
> ** &TDDFT
> **
> **  STATES SINGLET
> **
> **   5
> **
> **  tAMM-DANCOFF
> **
> **  LR-TDDFT
> **
> **  DAVIDSON PARAMETER
> **
> **   200 1.D-7 69
> **
> ** &END
> **
> **
> **
> ** &SYSTEM
> **
> **  POISSON SOLVER TUCKERMAN
> **
> **  SYMMETRY
> **
> **   0
> **
> **  CELL
> **
> **   22.282343   .9144899  1.0576992  0  0  0
> **
> **  CUTOFF
> **
> **   70.
> **
> **  CHARGE
> **
> **   0.0
> **
> ** &END
> **
> **
> **
> ** &ATOMS
> **
> **
> **
> ** *H_MT_PBE.psp KLEINMAN-BYLANDER
> **
> **    LMAX=P
> **
> **      7
> **
> ** 2   4   6   9  11  13  15
> **
> **
> **
> ** *N_MT_PBE.psp KLEINMAN-BYLANDER
> **
> **    LMAX=D
> **
> **      1
> **
> ** 5
> **
> **
> **
> ** *C_MT_PBE.psp KLEINMAN-BYLANDER
> **
> **    LMAX=D
> **
> **      8
> **
> ** 1   3   7   8  10  12  14  16
> **
> **
> **
> ** &END
> **
> **
> **
> ** &DFT
> **
> **   FUNCTIONAL PBE
> **
> **   GC-CUTOFF
> **
> **   1.0E-06
> **
> ** &END
> **
>
> ****************************************************************************
> **
>
> ****************************************************************************
> **
>
> CALCULATE ELECTRONIC SPECTRA
> PATH TO THE RESTART FILES:                                    ./
> RESTART WITH OLD ORBITALS
> RESTART WITH OLD ION POSITIONS
> GRAM-SCHMIDT ORTHOGONALIZATION
> MAXIMUM NUMBER OF STEPS:                            999999 STEPS
> WRITE WAVEFUNCTIONS IN COMPRESSED FORM TO FILE
>   COMPRESSION FACTOR IS   2
> PRINT INTERMEDIATE RESULTS EVERY                   1000000 STEPS
> STORE INTERMEDIATE RESULTS EVERY                   1000000 STEPS
> NUMBER OF DISTINCT RESTART FILES:                              3
> TEMPERATURE IS CALCULATED ASSUMING EXTENDED BULK BEHAVIOR
> FICTITIOUS ELECTRON MASS:                               400.0000
> TIME STEP FOR ELECTRONS:                                  5.0000
> TIME STEP FOR IONS:                                       5.0000
> CONVERGENCE CRITERIA FOR WAVEFUNCTION OPTIMIZATION:   1.0000E-05
> WAVEFUNCTION OPTIMIZATION BY PRECONDITIONED DIIS
> THRESHOLD FOR THE WF-HESSIAN IS                            .5000
> MAXIMUM NUMBER OF VECTORS RETAINED FOR DIIS:                  10
> STEPS UNTIL DIIS RESET ON POOR PROGRESS:                      10
> FULL ELECTRONIC GRADIENT IS USED
> SPLINE INTERPOLATION IN G-SPACE FOR PSEUDOPOTENTIAL FUNCTIONS
>    NUMBER OF SPLINE POINTS:                                 5000
>
> EXCHANGE CORRELATION FUNCTIONALS
>    LDA EXCHANGE:                                            NONE
>    LDA XC THROUGH PADE APPROXIMATION
>    S.GOEDECKER, J.HUTTER, M.TETER PRB 54 1703 (1996)
>    GRADIENT CORRECTED FUNCTIONAL
>    DENSITY THRESHOLD:                                1.00000E-06
>    EXCHANGE ENERGY
>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>    CORRELATION ENERGY
>       [PBE: J.P. PERDEW ET AL. PRL 77, 3865 (1996)]
>
>  WARNING: ISOLATED CLUSTER OPTION NEEDED IN QMMM
>           NOW TCLUST WILL BE SET TO .TRUE.
>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>  qmmm by Alessandro Laio,
>  qmmm    Joost VandeVondele, and
>  qmmm    Ursula Rothlisberger
>  qmmm
>  qmmm Revised DYNA version:
>  qmmm                    Tsukuba, 20 November 2005
>  qmmm        Bochum/Philadelphia, 27 November 2005
>  qmmm (Rewritten and vectorized for ES & Co.)
>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>  qmmm
>  qmmm GROMOS TOPOLOGY FILE    : gromos.top
>  qmmm GROMOS COORDINATES FILE : gromos.g96
>  qmmm GROMOS INPUT FILE       : gromos.inp
>  qmmm
>  qmmm USING AMBER FUNCTIONAL FORM
>  qmmm
>  qmmm QM AND MM TASKS PERFORMED IN THE SAME GROUP
>  qmmm
>  qmmm ELECTROSTATIC COUPLING WITH THE NN ATOMS
>  qmmm MULTIPOLE COUPLING WITH THE FAR MM ATOMS
>  qmmm
>  qmmm CUTOFFS FOR THE ELECTROSTATIC COUPLING [A.U.]:
>  qmmm {RCUT_NN}  RCUT_NN  =   10.00
>  qmmm {RCUT_MIX} RCUT_MIX =   15.00
>  qmmm {RCUT_ESP} RCUT_ESP =   20.00
>  qmmm
>  qmmm {UPDATE LIST} NN LIST UPDATED EVERY    100 STEPS
>  qmmm {MAXNN} MAXIMUM NUMBER OF NN ATOMS   5000
>  qmmm {ESPWEIGHT} WEIGHT FOR THE ESP FIT =      .1000
>  qmmm {SAMPLE INTERACTING} DATA SAVED EVERY   1000 STEPS
>  qmmm
>  qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm qmmm
>
> ***     DETSP| SIZE OF THE PROGRAM IS  7640 KBytes ***
> ***ALLOC_GROM| SIZE OF THE PROGRAM IS  7800 KBytes ***
> promd.f,v 1.55 1996/11/25 14:49:50 wscott Exp
> Present revision: Tsukuba, 13 July 2005
>
> PROGRAM PROMD PERFORMS EITHER
>   AN ENERGY MINIMISATION,
>   A MOLECULAR DYNAMICS RUN,
>   OR A STOCHASTIC DYNAMICS RUN
> IN THREE OR FOUR DIMENSIONS FOR A NUMBER OF SOLUTE
> (PROTEIN) MOLECULES PLUS SOLVENT MOLECULES, USING:
>
>  A: SPECIFICATION DATA
> -----------------------
>  1. A MOLECULAR TOPOLOGY FILE
>  2. DATA CHARACTERIZING THE RUN
>  3. DATA DETERMINING THE FREE ENERGY PERTURBATION (IF NTG>0)
>  4. RE(CON)STRAINED ATOM SEQUENCE NUMBERS (IF NTR>0)
>  5. DISTANCE RESTRAINT ATOM PAIRS (IF NTDR>0)
>  6. RESTRAINED DIHEDRALS (IF NTDLR>0)
>  7. J-VALUE RESTRAINING DIHEDRALS (IF NTJR >0)
>  8. LOCAL ELEVATION DIHEDRALS (IF NTLE > 0)
>  9. 4th DIMENSION ATOM INDICATORS (IF NT4DIM >0)
>
>  B: STARTUP DATA
> -----------------
> 10. INITIAL ATOMIC COORDINATES AND VELOCITIES
> 11. ATOMIC FRICTION COEFFICIENTS (IF NTFR=2)
> 12. REFERENCE ATOM COORDINATES FOR RE(CON)STRAINING (IF NTR>0)
>
>
>
> 1. M O L E C U L A R   T O P O L O G Y
>
> TOPOLOGY TITLE
> IND
>
>
>
> 2. D A T A   C H A R A C T E R I Z I N G   T H E   RUN
>
> TITLE
>  Input generated by QMMM interface
>
> SYSTEM
>       NPM       NSM
>         1      1376
> START
>       NTX      INIT        IG     TEMPI      HEAT NTXO       BOLTZ
>         1         1    210185   300.000      .000    1  .83144E-02
>    INITIAL COORDINATES ARE READ FROM FILE
>    INITIAL VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>       WITH TEMPERATURE TEMPI
>    INITIAL COORDINATES ARE SHAKEN
>    INITIAL VELOCITIES ARE SHAKEN
>    FORMATTED OUTPUT OF:
>       FINAL COORDINATES AND VELOCITIES
>    BOLTZ VALUE IS IN KJ/MOL
>
> STEP
>    NSTLIM         T        DT
>        10    .00000    .00200
>
> BOUNDARY
>       NTB    BOX(1)    BOX(2)    BOX(3)      BETA    NRDBOX
>         0  3.368147  3.510064  3.559402    90.000         0
>    NO PERIODICITY IS APPLIED
>
> SUBMOLECULES
>      NSPM
>         1
>        NSP(1..NSPM)
>        16
>
> TCOUPLE
>       NTT     TEMP0      TAUT
>         0   300.000      .100
>         0   300.000      .100
>         0   300.000      .100
>
>    NO PRESSURE COUPLING
>
> CENTREOFMASS
>    NDFMIN      NTCM      NSCM
>         0         0   1000000
>    INITIAL C.O.M. MOTION IS NOT REMOVED
>
> PRINT
>      NTPR      NTPL      NTPP
>        20       100         0
>    NO DIHEDRAL ANGLE MONITORING
>
> SHAKE
>       NTC       TOL
>         1 .1000E-03
>    NO SHAKE IS PERFORMED
>
> FORCE
>          NTF(1..10)
>     BONDS  BND-ANGL  IMP-DIHE  DIHEDRAL   NONBOND
>     H         H         H         H       CHG ALL
>     1   1     1   1     1   1     1   1     1   1
>      NEGR        NRE(1..NEGR)
>         2        16      4144
>    FORCE CALCULATION
>    INCLUDES         BOND FORCES INVOLVING H-ATOMS
>    INCLUDES         BOND FORCES NOT INVOLVING H-ATOMS
>    INCLUDES         BOND ANGLE FORCES INVOLVING H-ATOMS
>    INCLUDES         BOND ANGLE FORCES NOT INVOLVING H-ATOMS
>    INCLUDES         IMPROPER DIHEDRAL FORCES INVOLVING H-ATOMS
>    INCLUDES         IMPROPER DIHEDRAL FORCES NOT INVOLVING H-ATOMS
>    INCLUDES         DIHEDRAL ANGLE FORCES INVOLVING H-ATOMS
>    INCLUDES         DIHEDRAL ANGLE FORCES NOT INVOLVING H-ATOMS
>    INCLUDES         CHARGES IN NON-BONDED INTERACTION
>    INCLUDES         NON-BONDED INTERACTION
>
> PLIST
>      NTNB      NSNB     RCUTP     RCUTL
>         1        10     1.000     1.000
>    A PAIRLIST IS CONSTRUCTED IN THE FIRST STEP
>    NO LONGRANGE CONTRIBUTION IS CALCULATED ON PL CONSTRUCTION
>
> LONGRANGE
>     EPSRF     APPAK      RCRF
>    50.000      .000  .700E+10
>    A REACTION FIELD CORRECTION IS APPLIED
>
> POSREST
>       NTR       CHO     NRDRX
>         0 .2500E+05         1
>    NO POSITION RESTRAINING
>    ATOM RESTRAINING REFERENCE POSITIONS ARE READ FROM FILE
>
>    NO DISTANCE RESTRAINING
>
>    NO DIHEDRAL RESTRAINING
>
>    NO J-VALUE RESTRAINING
>
>    NO LOCAL ELEVATION INTERACTION
>
>    SIMULATION PERFORMED IN 3 DIMENSIONS
>
>    NO PERTURBATION PERFORMED
>
> LATSUM
>    NLATSM     KXMAX     KYMAX     KZMAX     K2MAX     ALPHA     PBETA
> NGHTUP
>         2        32        32        32         0      .800     1.330
> 100000
>     THE PPPM METHOD WILL BE USED
>
>
>
> 3. O P T I O N A L   D A T A   F I L E S
>
>
>
> 4. A T O M I C   C O O R D I N A T E S   A N D   V E L O C I T I E S
>
> SYSTEMBLOCK
>    NUMBER OF SOLUTE ATOMS         :      16
>    NUMBER OF SOLVENT ATOMS        :    4128
>    TOTAL NUMBER OF ATOMS          :    4144
>    NUMBER OF SOLUTE CHARGE GROUPS :       6
>    NUMBER OF SOLVENT CHARGE GROUPS:    1376
>    TOTAL NUMBER OF CHARGE GROUPS  :    1382
> END SYSTEMBLOCK
>
> 1021
> INITIAL CONFIGURATION TITLE
>  coordinates generated from amber coord file
>  rest_eq_reimaged.rst.1
>
> 3D VELOCITIES ARE TAKEN FROM A MAXWELLIAN DISTRIBUTION
>
>
>
> 5. I N I T I A L I Z E   R U N
>
> PERFORMING A MOLECULAR DYNAMICS RUN
>
> NDEGBLOCK
>    NUMBER OF POSITIONALLY CONSTRAINED ATOMS   :       0
>    NUMBER OF BONDS BETWEEN POS. CONSTR. ATOMS :       0
>    NUMBER OF SOLUTE CONSTRAINTS               :       0
>    NUMBER OF 3D SOLUTE (INT+ROT) D.O.F        :      45
>    NUMBER OF 3D SOLUTE C.O.M. TRANSL. D.O.F   :       3
>    NUMBER OF SOLVENT CONSTRAINTS              :       3
>    NUMBER OF 3D SOLVENT D.O.F.                :    8256
>    NUMBER OF 3D D.O.F. TO SUBTRACT (NDFMIN)   :       0
>    NUMBER OF TOTAL D.O.F. IN 3D               :    8304
> END NDEGBLOCK
>
> BATHBLOCK
>    TEMPERATURE COUPLING TO  0 BATH(S)
> END BATHBLOCK
>
> mm_SHAKE Solvent Coordinates, NITS =    1
> mm_SHAKE Solvent Velocities,  NITS =   10
>
> INITIAL TEMPERATURES ARE :
>                           TOTAL  .30315128E+03
>  SOLUTE INTERNAL AND ROTATIONAL  .37959703E+03
>  SOLUTE C.O.M. TRANSLATIONAL     .67213419E+01
>                        SOLVENT   .30284232E+03
>                   4th DIMENSION  .00000000E+00
>
>
>   QUANTUM SYSTEM:
>   NAX: 8
>   NSX: 3
>   FULL SYSTEM:
>   NAX: 36
>   NSX: 119
> ***MM_QM_TOPO| SIZE OF THE PROGRAM IS 16692 KBytes ***
> THE FOLLOWING INTERACTIONS ARE EXCLUDED FROM THE MM HAMILTONIAN:
>
> BONDS INVOLVING HYDROGEN:
>      14        15
>      12        13
>      10        11
>       8         9
>       5         6
>       3         4
>       1         2
>
> BONDS NOT INVOLVING HYDROGEN:
>      14        16
>      12        14
>      10        12
>       8        10
>       7         8
>       7        16
>       5         7
>       3         5
>       1         3
>       1        16
>
> ANGLES INVOLVING HYDROGEN:
>      15        14        16
>      13        12        14
>      12        14        15
>      11        10        12
>      10        12        13
>       9         8        10
>       8        10        11
>       7         8         9
>       6         5         7
>       4         3         5
>       3         5         6
>       2         1         3
>       2         1        16
>       1         3         4
>
> ANGLES NOT INVOLVING HYDROGEN:
>      12        14        16
>      10        12        14
>       8         7        16
>       8        10        12
>       7         8        10
>       7        16        14
>       5         7         8
>       5         7        16
>       3         1        16
>       3         5         7
>       1         3         5
>       1        16         7
>       1        16        14
>
> PROPER DIHEDRALS INVOLVING HYDROGEN:
>      13        12        14        15
>      13        12        14        16
>      11        10        12        13
>      11        10        12        14
>      10        12        14        15
>       9         8         7        16
>       9         8        10        11
>       9         8        10        12
>       8        10        12        13
>       7         8        10        11
>       7        16        14        15
>       6         5         7         8
>       6         5         7        16
>       5         7         8         9
>      16         1         3         4
>       4         3         5         6
>       4         3         5         7
>       2         1         3         4
>       2         1         3         5
>       2         1        16         7
>       2         1        16        14
>       1         3         5         6
>       1        16        14        15
>      12        16        14        15
>      10        14        12        13
>       8        12        10        11
>       7        10         8         9
>       3         7         5         6
>
> PROPER DIHEDRALS NOT INVOLVING HYDROGEN:
>      10         8         7        16
>      10        12        14        16
>       8         7        16        14
>       8        10        12        14
>       7         8        10        12
>       7        16        14        12
>      16         1         3         5
>       5         7         8        10
>       5         7        16        14
>       3         1        16         7
>       3         1        16        14
>       3         5         7         8
>       3         5         7        16
>       1         3         5         7
>       1        16         7         5
>       1        16         7         8
>       1        16        14        12
>
> IMPROPER DIHEDRALS INVOLVING HYDROGEN:
>
> IMPROPER DIHEDRALS NOT INVOLVING HYDROGEN:
> NON BONDED INTERACTIONS EXCLUDED FROM THE MM HAMITONIAN
> NO ELECTROSTATIC EXCLUSION BETWEEN QM AND MM ATOMS
> best 1 1 677.212792866984046
> best 3 1 677.212792866983932
> Cell Volume 677.212792866983932
>
> NUMBER OF STATES:                                             22
> NUMBER OF ELECTRONS:                                    44.00000
> CHARGE:                                                   .00000
> ELECTRON TEMPERATURE(KELVIN):                             .00000
> OCCUPATION
>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0  2.0
>
> LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
>    MAX. KRYLOV BLOCK SIZE                                     22
>
>    ============================================================
>    |    Pseudopotential Report     Fri Feb 20 19:18:54 1998   |
>    ------------------------------------------------------------
>    |  Atomic Symbol                   :   H                   |
>    |  Atomic Number                   :   1                   |
>    |  Number of core states           :   0                   |
>    |  Number of valence states        :   1                   |
>    |  Exchange-Correlation Functional :                       |
>    |     Slater exchange :   .6667                            |
>    |     LDA correlation : Ceperley-Alder                     |
>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>    |  Electron Configuration :   N   L  Occupation            |
>    |                             1   S     .7000              |
>    |  Full Potential Total Energy     -.474341                |
>    |  Trouiller-Martins normconserving PP                     |
>    |     n    l        rc       energy                        |
>    |     1    S     .5000      -.37203                        |
>    |     2    P     .3828      -.37203                        |
>    |  Number of Mesh Points :   511                           |
>    |  Pseudoatom Total Energy    -.367794                     |
>    ============================================================
>
>    ============================================================
>    |    Pseudopotential Report                                |
>    ------------------------------------------------------------
>    |  Atomic Symbol                   :   N                   |
>    |  Atomic Number                   :   7                   |
>    |  Number of core states           :   1                   |
>    |  Number of valence states        :   2                   |
>    |  Exchange-Correlation Functional :                       |
>    |     Slater exchange :  0.6667                            |
>    |     LDA correlation : Ceperley-Alder                     |
>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>    |  Electron Configuration :   N   L  Occupation            |
>    |                             1   S    2.0000              |
>    |                             2   S    2.0000              |
>    |                             2   P    3.0000              |
>    |  Full Potential Total Energy =      -54.420394           |
>    |  Trouiller-Martins normconserving PP                     |
>    |     n    l        rc       energy                        |
>    |     2    S    1.1200     -0.68204                        |
>    |     2    P    1.1200     -0.26082                        |
>    |     3    D    0.6031     -0.26082                        |
>    |  Number of Mesh Points :   624                           |
>    |  Pseudoatom Total Energy =   -9.647042                   |
>    ============================================================
>
>    ============================================================
>    |    Pseudopotential Report                                |
>    ------------------------------------------------------------
>    |  Atomic Symbol                   :   C                   |
>    |  Atomic Number                   :   6                   |
>    |  Number of core states           :   1                   |
>    |  Number of valence states        :   2                   |
>    |  Exchange-Correlation Functional :                       |
>    |     Slater exchange :  0.6667                            |
>    |     LDA correlation : Ceperley-Alder                     |
>    |     Exchange GC     : Perdew-Burke-Ernzerhof             |
>    |     Correlation GC  : Perdew-Burke-Ernzerhof             |
>    |  Electron Configuration :   N   L  Occupation            |
>    |                             1   S    2.0000              |
>    |                             2   S    2.0000              |
>    |                             2   P    2.0000              |
>    |  Full Potential Total Energy   -37.748221                |
>    |  Trouiller-Martins normconserving PP                     |
>    |     n    l        rc       energy                        |
>    |     2    S    1.2300     -0.50506                        |
>    |     2    P    1.2300     -0.19451                        |
>    |     3    D    0.7159     -0.19451                        |
>    |  Number of Mesh Points :   615                           |
>    |  Pseudoatom Total Energy   -5.361882                     |
>    ============================================================
>
> ****************************************************************
> *   ATOM       MASS   RAGGIO NLCC              PSEUDOPOTENTIAL *
> *      H     1.0080   1.2000   NO    KLEINMAN      S  NONLOCAL *
> *                                                  P     LOCAL *
> *      N    14.0067   1.2000   NO    KLEINMAN      S  NONLOCAL *
> *                                                  P  NONLOCAL *
> *                                                  D     LOCAL *
> *      C    12.0112   1.2000   NO    KLEINMAN      S  NONLOCAL *
> *                                                  P  NONLOCAL *
> *                                                  D     LOCAL *
> ****************************************************************
>
>
> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>  NCPU     NGW     NHG  PLANES  GXRAYS  HXRAYS ORBITALS Z-PLANES
>     0   13225  105849      30     670    2674       5       1
>     1   13229  105829      30     670    2674       6       1
>     2   13224  105802      30     669    2673       5       1
>     3   13218  105844      30     672    2672       6       1
>                G=0 COMPONENT ON PROCESSOR :     2
> PARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARAPARA
>
> ***    LOADPA| SIZE OF THE PROGRAM IS 23728 KBytes ***
>
> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
> NUMBER OF CPUS PER TASK                                        1
> OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
>
> ***     RGGEN| SIZE OF THE PROGRAM IS 26348 KBytes ***
>
> ************************** SUPERCELL ***************************
> THIS IS AN ISOLATED SYSTEM CALCULATION
> POISSON EQUATION SOLVER  :                   TUCKERMAN & MARTYNA
> SHORT RANGE POTENTIAL LENGTH * BOX LENGTH                  7.000
> SYMMETRY:                                           ORTHORHOMBIC
> LATTICE CONSTANT(a.u.):                                 22.28234
> CELL DIMENSION:  22.2823   .9145  1.0577   .0000   .0000   .0000
> VOLUME(OMEGA IN BOHR^3):                             10700.98252
> LATTICE VECTOR A1(BOHR):           22.2823      .0000      .0000
> LATTICE VECTOR A2(BOHR):             .0000    20.3770      .0000
> LATTICE VECTOR A3(BOHR):             .0000      .0000    23.5680
> RECIP. LAT. VEC. B1(2Pi/BOHR):       .0449      .0000      .0000
> RECIP. LAT. VEC. B2(2Pi/BOHR):       .0000      .0491      .0000
> RECIP. LAT. VEC. B3(2Pi/BOHR):       .0000      .0000      .0424
> REAL SPACE MESH:                   120          110          126
> WAVEFUNCTION CUTOFF(RYDBERG):                           70.00000
> DENSITY CUTOFF(RYDBERG):          (DUAL= 4.00)         280.00000
> NUMBER OF PLANE WAVES FOR WAVEFUNCTION CUTOFF:             52896
> NUMBER OF PLANE WAVES FOR DENSITY CUTOFF:                 423324
> ****************************************************************
>
> ***  RINFORCE| SIZE OF THE PROGRAM IS 39620 KBytes ***
> ***    FFTPRP| SIZE OF THE PROGRAM IS 53344 KBytes ***
> ***   CLUSTER| SIZE OF THE PROGRAM IS 61628 KBytes ***
>
> GENERATE ATOMIC BASIS SET
>      H        SLATER ORBITALS
>        1S        ALPHA=   1.0000      OCCUPATION= 1.00
>      N        SLATER ORBITALS
>        2S        ALPHA=   1.9237      OCCUPATION= 2.00
>        2P        ALPHA=   1.9170      OCCUPATION= 3.00
>      C        SLATER ORBITALS
>        2S        ALPHA=   1.6083      OCCUPATION= 2.00
>        2P        ALPHA=   1.5679      OCCUPATION= 2.00
>
>
> INITIALIZATION TIME:                                2.96 SECONDS
>
>
> *********************** LINEAR RESPONSE ************************
> Step size for numeric dmu/dn :                          .500E-03
> Number of calculations for dmu/dn :                            2
> Maximum number of optimisation steps:                       1000
> Threshold for Hessian (Preconditioner)                     .5000
> Optimizer for LR equations                             AUTOMATIC
>                    Size of ODIIS buffer                       10
>                    Size of ZDIIS buffer                        4
>                    Switch from PCG to ODIIS at         .1000E+00
>                    Switch to full preconditioning at   .1000E-02
> Step length                                                .1000
> Convergence criteria                                   .1000E-04
> ****************************************************************
>
> ***************************  TDDFT  ****************************
> Step size for numeric dmu/dn :                          .500E-03
> Number of calculations for dmu/dn :                            2
> Diagonalization Method                    NON-HERMITIAN DAVIDSON
>          Max. number of iterations                           200
>          Convergence criteria                           .100E-06
>          Max. size of Davidson matrix                         69
> Number of Singlet States                                       5
> Forces calculated for state                                    1
> ****************************************************************
> RV30! NUMBER OF STATES   HAS CHANGED                     22   27
>
> RESTART INFORMATION READ ON FILE                       ./RESTART
> ***     PHFAC| SIZE OF THE PROGRAM IS 85536 KBytes ***
> ATRHO| CHARGE(R-SPACE):   44.000000      (G-SPACE):   44.000000
> EWALD| SUM IN REAL SPACE OVER                      1* 1* 1 CELLS
>
> RE-CENTERING QM SYSTEM AT EVERY TIME STEP
>
>   BOX TOLERANCE [a.u.]   8.00000000000000000
>
> BOX SIZE [a.u.]                     QM SYSTEM SIZE [a.u.]
>  X DIRECTION:  CELLDIM =    22.2823; XMAX-XMIN=     4.3488
>  Y DIRECTION:  CELLDIM =    20.3770; YMAX-YMIN=    11.0220
>  Z DIRECTION:  CELLDIM =    23.5680; ZMAX-ZMIN=    10.3570
> ***   SPECTRA| SIZE OF THE PROGRAM IS 124624 KBytes ***
> ================================================================
> ==                        REFERENCE POINT                     ==
> ================================================================
> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124736 KBytes ***
>
>     !!!!!!!!!!!!!!!!!! WARNING !!!!!!!!!!!!!!!!!!!
>     THE QM SYSTEM DOES NOT HAVE AN INTEGER CHARGE.
>     A COMPENSATING CHARGE OF   -.000010 HAS BEEN
>     DISTRIBUTED OVER THE NN ATOMS.
>     !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>
> MM_ELSTAT: ELECTROSTATIC INTERACTION NN LIST UPDATED
> NN ATOMS =      496,  ESP COUPLED  ATOMS =      441
>
> *** MM_ELSTAT| SIZE OF THE PROGRAM IS 124920 KBytes ***
> ***MM_CHARGES| SIZE OF THE PROGRAM IS 125572 KBytes ***
> NBPML:     66387 ELEMENTS IN THE PAIRLIST
>
> PPPM USING NAG FFT ROUTINE , TWO real*8 GRIDS, PACKED GRID
> AND A SPHERICAL HAT FUNCTION
>
> GHAT FUNCTION HAS BEEN CALCULATED USING
> PBETA =     1.333 RESULTING IN Q =     .901232E-06
>
> A2 EVALUATED WITH LMAX =   44   TOL =  .00000047
> CONSTANT A1       =    -.01274135
> CONSTANT A2       =    1.69768358
> CONSTANT A3       =   -2.50000000
> CONSTANT XI       =   -2.74523413 = LX*(A1+A2+A3)
> EPSFAC*[SUM Q]**2 =   .138935E-07
> EPSFAC*SUM Q**2   =   .199556E+06
> ESELFL            =  -.813248E+05
>
>
> TOTAL INTEGRATED ELECTRONIC DENSITY
>    IN G-SPACE =                                        44.000000
>    IN R-SPACE =                                        44.000000
>
> (K+E1+L+N+X)           TOTAL ENERGY =          -63.33387972 A.U.
> (K)                  KINETIC ENERGY =           45.38116319 A.U.
> (E1=A-S+R)     ELECTROSTATIC ENERGY =          -49.67916341 A.U.
> (S)                           ESELF =           53.19230405 A.U.
> (R)                             ESR =            3.06373807 A.U.
> (L)    LOCAL PSEUDOPOTENTIAL ENERGY =          -41.17408788 A.U.
> (N)      N-L PSEUDOPOTENTIAL ENERGY =            4.84142028 A.U.
> (X)     EXCHANGE-CORRELATION ENERGY =          -18.95438051 A.U.
>         GRADIENT CORRECTION ENERGY =             -.28039967 A.U.
>
> NFI      GEMAX       CNORM           ETOT        DETOT      TCPU
>   1  1.582E-03   1.941E-04     -63.333880    0.000E+00     11.46
>   2  7.736E-04   7.495E-05     -63.339037   -5.157E-03      1.28
>   3  5.034E-04   4.193E-05     -63.339617   -5.801E-04      1.29
>   4  3.197E-04   2.216E-05     -63.339799   -1.819E-04      1.30
>   5  1.613E-04   1.182E-05     -63.339857   -5.781E-05      1.31
>   6  8.951E-05   6.529E-06     -63.339877   -2.043E-05      1.32
>   7  5.419E-05   4.024E-06     -63.339885   -8.035E-06      1.32
>   8  3.332E-05   2.665E-06     -63.339888   -3.376E-06      1.33
>   9  1.798E-05   1.736E-06     -63.339890   -1.479E-06      1.34
>  10  1.145E-05   1.139E-06     -63.339891   -7.199E-07      1.35
>  11  8.176E-06   7.835E-07     -63.339891   -3.883E-07      1.34
>
> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.1
>
> TIME FOR MINIMUM STRUCTURE :                      28.598 SECONDS
> ***   SPECTRA| SIZE OF THE PROGRAM IS 152720 KBytes ***
> ================================================================
> ==                END OF REFERENCE CALCULATION                ==
> ==               GENERATE INITIAL GUESS VECTORS               ==
> ================================================================
>
> ***   SPECTRA| SIZE OF THE PROGRAM IS 152724 KBytes ***
>
> <<<<<<<<<<<<<<<<<<< LANCZOS DIAGONALIZATION <<<<<<<<<<<<<<<<<<<<
> >> TIME FOR INITIAL SUBSPACE DIAGONALIZATION:                .57
> >> CYCLE     NCONV        B2MAX        B2MIN     #HPSI      TIME
>        1        22    7.534E-02    4.315E-10      2.30       .83
>        2        22    6.405E-02    4.314E-10      1.30       .82
>        3        22    3.739E-02    4.312E-10      1.30       .82
>        4        22    3.703E-02    4.311E-10      1.30       .83
>        5        22    2.207E-02    4.309E-10      1.30       .83
>        6        22    2.649E-02    4.309E-10      1.30       .82
>        7        22    2.905E-02    4.308E-10      1.30       .82
>        8        22    3.196E-02    4.308E-10      1.30       .82
>        9        22    3.057E-02    4.307E-10      1.30       .82
>       10        22    2.965E-02    4.307E-10      1.30       .82
>       11        22    2.497E-02    4.306E-10      1.30       .82
>       12        22    2.201E-02    4.306E-10      1.30       .82
>       13        22    1.723E-02    4.306E-10      1.30       .83
>       14        22    1.456E-02    4.306E-10      1.30       .82
>       15        22    1.117E-02    4.305E-10      1.30       .82
>       16        22    8.860E-03    4.305E-10      1.30       .82
>       17        22    4.720E-03    4.305E-10      1.30       .82
>       18        22    6.282E-03    4.305E-10      1.30       .82
>       19        22    5.300E-03    4.305E-10      1.30       .82
>       20        22    4.964E-03    4.305E-10      1.30       .82
>       21        22    4.155E-03    4.305E-10      1.30       .82
>       22        22    3.913E-03    4.305E-10      1.30       .82
>       23        22    3.321E-03    4.305E-10      1.30       .82
>       24        22    3.148E-03    4.305E-10      1.30       .82
>       25        22    2.691E-03    4.305E-10      1.30       .82
>       26        22    2.556E-03    4.305E-10      1.30       .82
>       27        22    2.192E-03    4.305E-10      1.30       .82
>       28        22    2.081E-03    4.305E-10      1.30       .82
>       29        22    1.788E-03    4.305E-10      1.30       .82
>       30        22    1.695E-03    4.305E-10      1.30       .82
>       31        22    1.458E-03    4.305E-10      1.30       .82
>       32        22    1.381E-03    4.305E-10      1.30       .82
>       33        22    1.190E-03    4.305E-10      1.30       .82
>       34        22    1.127E-03    4.305E-10      1.30       .82
>       35        22    1.023E-03    4.305E-10      1.30       .82
>       36        22    9.216E-04    4.305E-10      1.30       .86
>       37        22    1.092E-03    4.305E-10      1.30       .82
>       38        22    9.192E-04    4.305E-10      1.30       .82
>       39        22    1.165E-03    4.305E-10      1.30       .82
>       40        22    9.791E-04    4.305E-10      1.30       .82
>       41        22    1.239E-03    4.305E-10      1.30       .82
>       42        23    1.039E-03    4.305E-10      1.11       .65
>       43        23    1.312E-03    4.305E-10      1.04       .58
>       44        23    1.097E-03    4.305E-10      1.04       .58
>       45        23    1.381E-03    4.305E-10      1.04       .58
>       46        23    1.150E-03    4.305E-10      1.04       .58
>       47        23    1.443E-03    4.305E-10      1.04       .58
>       48        23    1.197E-03    4.305E-10      1.04       .58
>       49        23    1.494E-03    4.305E-10      1.04       .58
>       50        23    1.233E-03    4.305E-10      1.04       .58
>       51        23    1.533E-03    4.305E-10      1.04       .58
>       52        23    1.258E-03    4.305E-10      1.04       .58
>       53        23    1.556E-03    4.305E-10      1.04       .59
>       54        23    1.270E-03    4.305E-10      1.04       .58
>       55        23    1.562E-03    4.305E-10      1.04       .58
>       56        23    1.267E-03    4.305E-10      1.04       .58
>       57        23    1.550E-03    4.305E-10      1.04       .58
>       58        23    1.249E-03    4.305E-10      1.04       .58
>       59        23    1.520E-03    4.305E-10      1.04       .58
>       60        23    1.218E-03    4.305E-10      1.04       .58
>       61        23    1.473E-03    4.305E-10      1.04       .58
>       62        23    1.173E-03    4.305E-10      1.04       .58
>       63        23    1.411E-03    4.305E-10      1.04       .58
>       64        24    1.117E-03    4.305E-10       .85       .59
>       65        24    1.337E-03    4.305E-10       .78       .59
>       66        24    1.052E-03    4.305E-10       .85       .58
>       67        24    1.254E-03    4.305E-10       .78       .59
>       68        24    9.810E-04    4.305E-10       .78       .59
>       69        24    1.164E-03    4.305E-10       .85       .58
>       70        24    9.057E-04    4.305E-10       .78       .59
>       71        24    1.070E-03    4.305E-10       .78       .59
>       72        24    8.286E-04    4.305E-10       .78       .59
>       73        24    9.758E-04    4.305E-10       .78       .59
>       74        24    7.518E-04    4.305E-10       .78       .59
>       75        24    8.826E-04    4.305E-10       .78       .59
>       76        24    6.769E-04    4.305E-10       .78       .59
>       77        24    7.926E-04    4.305E-10       .78       .61
>       78        24    6.053E-04    4.305E-10       .78       .60
>       79        24    7.073E-04    4.305E-10       .78       .59
>       80        24    5.380E-04    4.305E-10       .78       .59
>       81        24    6.276E-04    4.305E-10       .78       .59
>       82        24    4.756E-04    4.305E-10       .78       .59
>       83        24    5.542E-04    4.305E-10       .78       .59
>       84        24    4.186E-04    4.305E-10       .78       .59
>       85        24    4.873E-04    4.305E-10       .78       .59
>       86        24    3.669E-04    4.305E-10       .78       .59
>       87        24    4.271E-04    4.305E-10       .78       .59
>       88        24    3.207E-04    4.305E-10       .78       .59
>       89        24    3.733E-04    4.305E-10       .78       .59
>       90        24    2.797E-04    4.305E-10       .78       .59
>       91        24    3.257E-04    4.305E-10       .78       .59
>       92        24    2.435E-04    4.305E-10       .78       .59
>       93        24    2.838E-04    4.305E-10       .78       .59
>       94        24    2.118E-04    4.305E-10       .78       .59
>       95        24    2.471E-04    4.305E-10       .78       .59
>       96        24    1.842E-04    4.305E-10       .78       .59
>       97        24    2.152E-04    4.305E-10       .78       .59
>       98        24    1.603E-04    4.305E-10       .78       .59
>       99        24    1.875E-04    4.305E-10       .78       .59
>      100        24    1.395E-04    4.305E-10       .78       .59
>      101        24    1.635E-04    4.305E-10       .78       .59
>      102        24    1.216E-04    4.305E-10       .78       .59
>      103        24    1.428E-04    4.305E-10       .78       .59
>      104        24    1.061E-04    4.305E-10       .78       .59
>      105        24    1.248E-04    4.305E-10       .78       .59
>      106        24    9.275E-05    4.305E-10       .78       .59
>      107        24    1.093E-04    4.305E-10       .78       .59
>      108        24    8.121E-05    4.305E-10       .78       .59
>      109        24    9.585E-05    4.305E-10       .78       .59
>      110        24    7.123E-05    4.305E-10       .78       .59
>      111        24    8.422E-05    4.305E-10       .78       .59
>      112        24    6.259E-05    4.305E-10       .78       .59
>      113        24    7.413E-05    4.305E-10       .78       .59
>      114        24    5.510E-05    4.305E-10       .78       .59
>      115        24    6.537E-05    4.305E-10       .78       .59
>      116        24    4.860E-05    4.305E-10       .78       .59
>      117        24    5.774E-05    4.305E-10       .78       .59
>      118        24    4.294E-05    4.305E-10       .78       .59
>      119        24    5.109E-05    4.305E-10       .78       .59
>      120        24    3.801E-05    4.305E-10       .78       .59
>      121        24    4.528E-05    4.305E-10       .78       .60
>      122        24    3.370E-05    4.305E-10       .78       .59
>      123        24    4.020E-05    4.305E-10       .78       .59
>      124        24    2.993E-05    4.305E-10       .78       .59
>      125        24    3.575E-05    4.305E-10       .78       .59
>      126        24    2.662E-05    4.305E-10       .78       .59
>      127        24    3.183E-05    4.305E-10       .78       .59
>      128        24    2.371E-05    4.305E-10       .78       .59
>      129        24    2.838E-05    4.305E-10       .78       .59
>      130        24    2.115E-05    4.305E-10       .78       .59
>      131        24    2.535E-05    4.305E-10       .78       .59
>      132        24    1.890E-05    4.305E-10       .78       .59
>      133        24    2.266E-05    4.305E-10       .78       .59
>      134        24    1.690E-05    4.305E-10       .78       .59
>      135        24    2.029E-05    4.305E-10       .78       .59
>      136        24    1.514E-05    4.305E-10       .78       .59
>      137        24    1.818E-05    4.305E-10       .78       .59
>      138        24    1.357E-05    4.305E-10       .78       .59
>      139        24    1.632E-05    4.305E-10       .78       .59
>      140        24    1.218E-05    4.305E-10       .78       .59
>      141        24    1.466E-05    4.305E-10       .78       .59
>      142        24    1.095E-05    4.305E-10       .78       .59
>      143        24    1.318E-05    4.305E-10       .78       .59
>      144        24    9.846E-06    4.305E-10       .78       .59
>      145        25    1.186E-05    4.305E-10       .63       .45
>      146        25    8.861E-06    4.305E-10       .52       .35
>      147        25    1.069E-05    4.305E-10       .52       .35
>      148        25    7.987E-06    4.305E-10       .52       .35
>      149        25    9.644E-06    4.305E-10       .52       .35
>      150        25    7.205E-06    4.305E-10       .52       .35
>      151        25    8.706E-06    4.305E-10       .52       .35
>      152        25    6.505E-06    4.305E-10       .52       .35
>      153        25    7.866E-06    4.305E-10       .52       .35
>      154        25    5.877E-06    4.305E-10       .52       .35
>      155        25    7.113E-06    4.305E-10       .52       .35
>      156        25    5.314E-06    4.305E-10       .52       .35
>      157        25    6.436E-06    4.305E-10       .52       .35
>      158        25    4.809E-06    4.305E-10       .52       .35
>      159        25    5.828E-06    4.305E-10       .52       .35
>      160        26    4.354E-06    4.305E-10       .33       .33
>      161        26    5.277E-06    4.305E-10       .26       .32
>      162        26    3.948E-06    4.305E-10       .26       .32
>      163        26    4.785E-06    4.305E-10       .26       .32
>      164        26    3.582E-06    4.305E-10       .26       .32
>      165        26    4.341E-06    4.305E-10       .26       .32
>      166        26    3.252E-06    4.305E-10       .26       .32
>      167        26    3.940E-06    4.305E-10       .26       .32
>      168        26    2.953E-06    4.305E-10       .26       .32
>      169        26    3.578E-06    4.305E-10       .26       .32
>      170        26    2.684E-06    4.305E-10       .26       .32
>      171        26    3.251E-06    4.305E-10       .26       .32
>      172        26    2.440E-06    4.305E-10       .26       .32
>      173        26    2.955E-06    4.305E-10       .26       .32
>      174        26    2.220E-06    4.305E-10       .26       .32
>      175        26    2.688E-06    4.305E-10       .26       .32
>      176        26    2.020E-06    4.305E-10       .26       .32
>      177        26    2.446E-06    4.305E-10       .26       .32
>      178        27    9.966E-07    4.305E-10       .19       .24
>
> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.2
>
> EIGENVALUES(EV) AND OCCUPATION:
>     1    -23.7335233       2.00000000        2    -19.9290529
> 2.00000000
>     3    -18.3902715       2.00000000        4    -17.2606686
> 2.00000000
>     5    -16.6676136       2.00000000        6    -14.4741075
> 2.00000000
>     7    -13.7418694       2.00000000        8    -13.2132617
> 2.00000000
>     9    -12.2511591       2.00000000       10    -10.7230135
> 2.00000000
>    11    -10.4904816       2.00000000       12     -9.8090984
> 2.00000000
>    13     -9.5347383       2.00000000       14     -9.4073271
> 2.00000000
>    15     -9.0064959       2.00000000       16     -8.5053970
> 2.00000000
>    17     -7.5545624       2.00000000       18     -7.3121930
> 2.00000000
>    19     -7.0592376       2.00000000       20     -5.9706919
> 2.00000000
>    21     -4.7579865       2.00000000       22     -4.1479453
> 2.00000000
>    23      -.5969499        .00000000       24      -.3720761
> .00000000
>    25       .3650124        .00000000       26       .3724612
> .00000000
>    27       .4402542        .00000000
> CHEMICAL POTENTIAL =                            -4.1479469673 EV
> ================================================================
> ==                END OF STATE INITIALIZATION                 ==
> ================================================================
>
> ***   SPECTRA| SIZE OF THE PROGRAM IS 161824 KBytes ***
> ==                      SINGLET STATES                        ==
> NUMBER OF STATES TO BE INITIALIZED                             5
> TOTAL NUMBER OF TEST VECTORS                                  10
> ***   SPECTRA| SIZE OF THE PROGRAM IS 207492 KBytes ***
> ================================================================
> ==   NON-HERMITIAN DAVIDSON DIAGONALISATION OF TDDFT MATRIX   ==
> ================================================================
> Number of states initialized                                  10
> Time for initialization                                    10.60
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           0            10        .15845565E-01       25.20
>     2           0            20        .11376972E-01       25.99
>     3           0            30        .86052357E-02       27.10
>     4           0            40        .28366033E-01       28.49
>     5           0            50        .86824638E-02       30.19
>     6           0            60        .47491577E-02       32.24
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           0            10        .32825954E-02       24.97
>     2           0            20        .12877815E-02       25.77
>     3           0            30        .12378764E-02       26.84
>     4           0            40        .86346371E-03       28.24
>     5           0            50        .63720455E-03       29.94
>     6           0            60        .47484767E-03       32.01
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           0            10        .38477936E-03       24.96
>     2           0            20        .34007730E-03       25.76
>     3           0            30        .33896785E-03       26.84
>     4           0            40        .33335272E-03       28.25
>     5           0            50        .32908877E-03       29.98
>     6           0            60        .32421071E-03       32.03
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           0            10        .32168820E-03       24.94
>     2           0            20        .31938491E-03       25.73
>     3           0            30        .31889769E-03       26.82
>     4           0            40        .31755839E-03       28.23
>     5           0            50        .31660912E-03       29.93
>     6           0            60        .31638267E-03       32.05
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           0            10        .13172735E-02       24.97
>     2           0            20        .38287214E-03       25.75
>     3           0            30        .37349499E-03       26.85
>     4           0            40        .31639432E-03       28.22
>     5           0            50        .31617519E-03       29.93
>     6           0            60        .31599779E-03       32.01
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
>     1           1            10        .31589822E-03       24.97
>     2           2            18        .31586838E-03       20.56
>     3           3            24        .82191816E-04       16.06
>     4           3            28        .91936763E-04       11.39
>     5           3            32        .10357358E-03       11.81
>     6           3            36        .10676478E-03       12.30
>     7           3            40        .14164920E-03       12.80
>     8           3            44        .21147763E-03       13.39
>     9           3            48        .14641292E-03       13.98
>    10           3            52        .11876749E-03       14.70
>    11           3            56        .94534219E-04       15.42
>    12           3            60        .71650384E-04       16.20
>    13           3            64        .59567744E-04       17.03
>    14           3            68        .51910420E-04       17.89
> Number of states initialized                                  10
> Time for initialization                                      .30
>
>  ITER      STATES      SUBSPACE             RESIDUAL        TCPU
> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
> !! DAVIDSON| NOT ALL ROOTS ARE CONVERGED                      !!
> !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
>
>
> STATE=  1                               EIGENVALUE=     3.725 eV
>
>
> STATE=  2                               EIGENVALUE=     4.108 eV
>
>
> STATE=  3                               EIGENVALUE=     4.346 eV
>
>
> STATE=  4                               EIGENVALUE=     4.485 eV
>
>
> STATE=  5                               EIGENVALUE=     4.508 eV
> ***   SPECTRA| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>
> RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.3
>
> ================================================================
>                      BIG MEMORY ALLOCATIONS
> PME              3570830                CB              40733000
> CSCR             4655200                C1               5819000
> CATOM            1137350                CSP             40733000
> GDE               892707                CSM             40733000
> SCR              3482773                CR               1163800
> ----------------------------------------------------------------
> [PEAK NUMBER  110]      PEAK MEMORY    144366981 = 1154.9 MBytes
> ================================================================
>
>
> ****************************************************************
> *                                                              *
> *                            TIMING                            *
> *                                                              *
> ****************************************************************
> SUBROUTINE            CALLS         CPU TIME        ELAPSED TIME
>     GCENER              883           191.15              191.15
>    FFT-G/S           142837           141.20              141.21
>     FWFFTN            12010           136.94              136.94
>   S_INVFFT            14045           127.79              127.78
>    INVFFTN            12153           110.91              110.91
>      FWFFT             3981            75.31               75.31
>       VPSI             2553            53.65               53.66
>    S_FWFFT             4685            53.23               53.23
>     INVFFT             3098            46.18               46.18
>    FNONLOC             2118            42.13               42.13
>     XCENER              883            35.73               35.73
>     RNLSM1             2118            27.13               27.13
>     FFTCOM            25809            26.48               26.48
>    RHO1OFR              435            25.46               25.46
>   N-FFTCOM            24163            17.30               17.30
>     GRADEN              883            12.82               12.82
>      OVLAP             1288            11.13               11.13
> MM_ELSTAT_                1             8.58                8.58
>     ROTATE             1287             7.41                7.41
>      PHASE             7079             7.29                7.30
>      DD_XC              435             5.70                5.70
>   FRIESNER                1             4.99                4.99
>  VTDOFRHO1              435             4.82                4.82
>     GLOSUM            30274             3.66                3.65
>     OVLAP2              383             2.93                2.93
>       HPSI             2090             2.33                2.33
> ----------------------------------------------------------------
> TOTAL TIME                           1182.25             1182.25
> ****************************************************************
>
>       CPU TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
>   ELAPSED TIME :    0 HOURS 24 MINUTES  6.90 SECONDS
> ***      CPMD| SIZE OF THE PROGRAM IS 1162208 KBytes ***
>
> PROGRAM CPMD ENDED AT:   Mon Oct  1 22:52:38 2007
>
>
> ================================================================
> = COMMUNICATION TASK  AVERAGE MESSAGE LENGTH  NUMBER OF CALLS  =
> = SEND/RECEIVE              133074. BYTES               2559.  =
> = BROADCAST                  21267. BYTES                639.  =
> = GLOBAL SUMMATION             591. BYTES              32713.  =
> = GLOBAL MULTIPLICATION          0. BYTES                  1.  =
> = ALL TO ALL COMM          1834756. BYTES              49972.  =
> =                             PERFORMANCE          TOTAL TIME  =
> = SEND/RECEIVE              897.740  MB/S            .379 SEC  =
> = BROADCAST                 432.366  MB/S            .031 SEC  =
> = GLOBAL SUMMATION            9.594  MB/S           4.032 SEC  =
> = GLOBAL MULTIPLICATION        .000  MB/S            .001 SEC  =
> = ALL TO ALL COMM          2101.717  MB/S          43.625 SEC  =
> = SYNCHRONISATION                                    .009 SEC  =
> ================================================================
>
> _______________________________________________
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> CPMD-list at cpmd.org
> http://cpmd.org/mailman/listinfo/cpmd-list
>


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