[CPMD-list] Adapted geometry optimization went abnormally after several thousands steps..

osirixu-cpmd at yahoo.com.cn osirixu-cpmd at yahoo.com.cn
Tue Jun 20 19:19:33 CEST 2006


Dear Axel.

   Because KPOINTS cann't work with PCG MINIMIZE, I
tried with default ODIIS to do wavefunction
optimization. Though it is still running, it seems
hard to converge as I mentioned in the previous post
(the output file is appended below). I have selected
KPOINTS MONKHORST-PACK                                
             
  5  9  7                                             
                 
Other keywords are just the same as my previous post
(including the adapted convergence).
   
   Any suggestions?
   
   Sinverely yours,
     Rex
   June 21, 2006

--- Axel Kohlmeyer <akohlmey at cmm.upenn.edu> wrote:

> On 6/17/06, osirixu-cpmd at yahoo.com.cn
> <osirixu-cpmd at yahoo.com.cn> wrote:
> > Dear cpmders,
> 
> dear rex,
> 
> > steps with adapted convergence criteria, the
> > optimzatio went abnormally and reported many "NaN"
> > strings (the output file is also appended below).
> It
> > seems the LAMBDA was going bigger and bigger. Is
> it
> > because of the using of PCG MINIMIZE and LBFGS?
> 
> unlikely. that is usually only an indicator that
> something
> has gone wrone before.
> 
> >       Well, I have tried with ODIIS, but I find it
> is
> > also too hard to reach a convergence. In addition,
> I
> 
> this is strange, you don't have any complicated
> elements
> in there, so DIIS should work fine.
> 
> > also encountered the same problem when running
> BOMD
> > after several hundreds of md-steps.
> >
> >       Any suggestions?
> 
> does the same happen when you keep the supercell
> size fixed?
> 
> please look closer at the output. basically, your
> supercell is
> exploding (in y-direction).
> 
> >
> >     greetings,
> >        Rex
> >     June 18, 2006
> >
> 
> 
> >  **   CELL ABSOLUTE                       **
> >  **     4.73030 4.31381 5.19292    0 0 0          
>             **
> >  **   REFERENCE CELL ABSOLUTE                     
>  **
> >  **      5 5 5.5   0 0 0                       **
> 
> this is a pretty small cell for a gamma point only
> run.
> 
> >  CELL PARAMETER (VOLUME=    675.4196):
> 
> >  CELL PARAMETER (VOLUME=    503.8368):
> 
> >  CELL PARAMETER (VOLUME=    794.8757):
> 
> >  CELL PARAMETER (VOLUME=   1027.5242):
> 
> >
> >  WARNING| SPLINE REGION SMALLER THAN MAXIMUM
> G-VALUE
> 
> at this point your cell is far to large to fit into
> the precalculated
> spline range from the reference cell in your input.
> the whole wavefunction optimization _cannot_ work
> properly anymore.
 






*******************************************************************
 **            SINGLE POINT DENSITY OPTIMIZATION      
           ** 

*******************************************************************
 NFI      GEMAX       CNORM           ETOT       
DETOT      TCPU
   1  6.943E-01   4.157E-02      -8.673401   
0.000E+00     16.36
   2  3.659E-01   2.089E-02     -24.905810  
-1.623E+01     16.69
   3  3.108E-01   1.516E-02     -28.255798  
-3.350E+00     16.93
   4  1.529E-01   1.253E-02     -29.575053  
-1.319E+00     17.17
   5  1.179E-01   9.946E-03     -30.216578  
-6.415E-01     17.45
   6  8.472E-02   5.920E-03     -30.726577  
-5.100E-01     17.77
   7  3.593E-02   3.424E-03     -30.918736  
-1.922E-01     18.07
   8  3.180E-02   2.849E-03     -30.988090  
-6.935E-02     18.34
   9  3.488E-02   2.882E-03     -31.024208  
-3.612E-02     18.64
  10  3.612E-02   2.796E-03     -31.052822  
-2.861E-02     18.87
 ODIIS| Insufficient progress for K =        2; reset!
  11  3.707E-02   2.812E-03     -31.065785  
-1.296E-02     18.91
  12  3.232E-02   4.017E-03     -31.064428   
1.357E-03     16.44
  13  3.422E-02   2.654E-03     -31.102840  
-3.841E-02     16.68
  14  3.790E-02   2.539E-03     -31.123030  
-2.019E-02     16.92
  15  3.827E-02   2.507E-03     -31.130312  
-7.282E-03     17.28
  16  1.030E+00   9.467E-02     -30.994095   
1.362E-01     17.57
  17  4.387E-01   5.147E-02     -30.998463  
-4.368E-03     17.79
  18  1.493E+00   9.632E-02     -30.441610   
5.569E-01     18.03
  19  1.651E+00   1.178E-01     -30.110753   
3.309E-01     18.32
  20  3.015E-01   4.699E-02     -30.996211  
-8.855E-01     18.63
  21  9.864E-02   2.344E-02     -31.066804  
-7.059E-02     18.93
 ODIIS| Insufficient progress for K =        2; reset!
  22  8.174E-02   2.166E-02     -30.992115   
7.469E-02     18.91
[...]
 ODIIS| Insufficient progress; reset!
 397  3.173E-03   8.100E-04     -31.495712  
-1.749E-06     16.27
 398  1.957E-03   2.843E-04     -31.495696   
1.579E-05     16.28
 399  9.875E-03   1.317E-03     -31.495200   
4.963E-04     16.54
 400  1.614E-03   2.822E-04     -31.495696  
-4.957E-04     16.82
 401  8.659E-04   1.159E-04     -31.495715  
-1.966E-05     17.11
 402  8.513E-04   1.283E-04     -31.495716  
-4.315E-07     17.37
 403  8.775E-04   1.106E-04     -31.495716  
-2.860E-07     17.66
 404  8.724E-04   1.042E-04     -31.495717  
-9.438E-07     17.92
 405  8.737E-04   9.729E-05     -31.495718  
-8.082E-07     18.19
 406  9.238E-04   1.189E-04     -31.495718  
-1.482E-07     18.48
 407  9.194E-04   1.233E-04     -31.495718   
2.530E-07     18.75
 408  9.165E-04   1.258E-04     -31.495717   
2.387E-07     18.77
 ODIIS| Insufficient progress; reset!
 409  9.240E-04   1.195E-04     -31.495717   
4.006E-07     16.26
 410  8.401E-04   1.219E-04     -31.495713   
3.490E-06     16.27
 411  1.511E-03   2.251E-04     -31.495704   
9.721E-06     16.55
 412  9.186E-04   1.230E-04     -31.495716  
-1.173E-05     16.82
 413  8.745E-04   1.114E-04     -31.495716  
-8.744E-07     17.10
 414  8.972E-04   1.057E-04     -31.495716  
-8.434E-08     17.36
 415  9.027E-04   9.728E-05     -31.495717  
-2.354E-07     17.65
 416  8.814E-04   1.111E-04     -31.495716   
4.405E-07     17.93
 417  8.892E-04   1.100E-04     -31.495715   
1.068E-06     18.20
 418  9.152E-04   1.893E-04     -31.495714   
1.493E-06     18.48
 419  8.767E-04   1.723E-04     -31.495714  
-5.158E-07     18.74
 420  8.999E-04   1.296E-04     -31.495715  
-7.838E-07     18.76
 ODIIS| Insufficient progress; reset!
 421  2.475E-03   4.331E-04     -31.495715   
4.259E-07     16.27
 422  9.190E-04   1.437E-04     -31.495710   
4.782E-06     16.27
 423  4.926E-03   5.754E-04     -31.495619   
9.117E-05     16.55
 424  9.855E-04   1.434E-04     -31.495710  
-9.148E-05     16.83
 425  8.926E-04   1.351E-04     -31.495714  
-3.614E-06     17.09
 426  8.908E-04   1.007E-04     -31.495715  
-1.204E-06     17.37
 427  8.780E-04   1.209E-04     -31.495715   
4.031E-07     17.65
 428  8.985E-04   1.129E-04     -31.495715  
-4.574E-07     17.92
 429  9.107E-04   1.128E-04     -31.495714   
7.096E-07     18.21
 430  8.924E-04   1.139E-04     -31.495714   
5.289E-07     18.48
 431  9.227E-04   1.596E-04     -31.495712   
1.610E-06     18.75
 432  2.721E-03   6.160E-04     -31.495710   
1.937E-06     18.76
 ODIIS| Insufficient progress; reset!
 433  4.263E-03   9.657E-04     -31.495707   
3.424E-06     16.27
 434  1.027E-03   1.396E-04     -31.495711  
-4.087E-06     16.27
 435  3.810E-03   5.289E-04     -31.495638   
7.307E-05     16.55
 436  1.039E-03   1.491E-04     -31.495711  
-7.329E-05     16.82
 437  9.886E-04   1.215E-04     -31.495713  
-2.418E-06     17.09
 438  1.009E-03   1.154E-04     -31.495714  
-2.368E-07     17.37
 439  9.963E-04   1.186E-04     -31.495713   
6.766E-07     17.65
 440  9.862E-04   1.237E-04     -31.495713   
4.261E-07     17.93
 441  1.010E-03   2.965E-04     -31.495711   
1.950E-06     18.20
 442  3.195E-03   9.061E-04     -31.495703   
7.540E-06     18.48
 443  3.383E-03   9.448E-04     -31.495702   
8.926E-07     18.76
 444  2.836E-03   7.839E-04     -31.495701   
1.602E-06     18.76
 ODIIS| Insufficient progress; reset!
 445  3.098E-03   6.660E-04     -31.495700   
6.254E-07     16.26
 446  1.657E-03   1.969E-04     -31.495690   
9.561E-06     16.27
 447  8.821E-03   1.005E-03     -31.495398   
2.926E-04     16.55
 448  1.162E-03   1.785E-04     -31.495692  
-2.943E-04     16.83
 449  5.527E-04   8.128E-05     -31.495701  
-8.480E-06     17.09
 450  5.193E-04   9.136E-05     -31.495701   
6.176E-08     17.37
 451  5.717E-04   8.333E-05     -31.495700   
4.150E-07     17.66
 452  5.420E-04   7.101E-05     -31.495700   
2.370E-07     17.92
 453  5.584E-04   7.625E-05     -31.495700   
3.551E-07     18.20
 454  5.627E-04   6.958E-05     -31.495698   
1.294E-06     18.48
 455  5.513E-04   7.155E-05     -31.495696   
2.544E-06     18.75
 456  5.485E-04   9.026E-05     -31.495694   
1.586E-06     18.75
 ODIIS| Insufficient progress; reset!
 457  5.463E-04   8.908E-05     -31.495694   
4.567E-07     16.27
 458  1.002E-03   1.349E-04     -31.495688   
5.308E-06     16.26
 459  4.659E-03   5.629E-04     -31.495605   
8.349E-05     16.53
 460  5.837E-04   1.132E-04     -31.495687  
-8.207E-05     16.82
 461  6.426E-04   9.172E-05     -31.495689  
-2.128E-06     17.10
 462  6.672E-04   1.057E-04     -31.495691  
-1.735E-06     17.37
 463  6.515E-04   7.918E-05     -31.495691  
-5.965E-07     17.65
 464  5.718E-04   7.441E-05     -31.495691   
6.798E-07     17.94
 465  6.301E-04   9.570E-05     -31.495690   
9.640E-07     18.20
 466  9.299E-04   2.391E-04     -31.495689   
9.677E-07     18.48
 467  1.257E-03   3.257E-04     -31.495687   
1.759E-06     18.75
 468  1.283E-03   3.119E-04     -31.495687   
4.487E-08     18.76
 ODIIS| Insufficient progress; reset!
 469  1.176E-03   2.906E-04     -31.495684   
2.659E-06     16.28
 470  4.629E-04   9.937E-05     -31.495684   
3.160E-07     16.27
 471  2.175E-03   3.155E-04     -31.495660   
2.437E-05     16.55
 472  4.641E-04   9.177E-05     -31.495684  
-2.385E-05     16.81
 473  4.636E-04   6.971E-05     -31.495684  
-9.539E-07     17.10
 474  4.642E-04   8.572E-05     -31.495685  
-4.443E-07     17.38
 475  4.641E-04   6.045E-05     -31.495685  
-2.978E-07     17.65
 476  4.766E-04   9.770E-05     -31.495685  
-2.428E-07     17.93
 477  4.972E-04   1.019E-04     -31.495685   
2.676E-07     18.20
 478  1.895E-03   5.063E-04     -31.495668   
1.765E-05     18.47
 479  2.518E-03   5.995E-04     -31.495672  
-4.586E-06     18.75
 480  1.612E-03   4.203E-04     -31.495676  
-4.097E-06     18.76
 ODIIS| Insufficient progress; reset!
 481  4.656E-03   1.147E-03     -31.495632   
4.407E-05     16.28
 482  7.260E-04   1.741E-04     -31.495672  
-4.014E-05     16.26
 483  4.693E-03   6.017E-04     -31.495591   
8.130E-05     16.54
 484  5.360E-04   1.204E-04     -31.495670  
-7.858E-05     16.82
 485  4.770E-04   1.048E-04     -31.495674  
-4.878E-06     17.10
 486  5.238E-04   8.646E-05     -31.495676  
-1.412E-06     17.37
 487  4.670E-04   8.287E-05     -31.495676   
1.887E-07     17.66
 488  4.790E-04   7.016E-05     -31.495676  
-1.087E-07     17.93
 489  4.729E-04   7.744E-05     -31.495676   
2.455E-09     18.20
 490  4.765E-04   7.840E-05     -31.495676   
1.525E-07     18.48
 491  4.904E-04   8.177E-05     -31.495675   
6.106E-07     18.75
 492  5.513E-03   1.102E-03     -31.495567   
1.082E-04     18.77
 ODIIS| Insufficient progress for K =        1; reset!
 ODIIS| Insufficient progress; reset!
 493  2.299E-03   4.939E-04     -31.495664  
-9.706E-05     16.26
 494  5.516E-04   1.246E-04     -31.495669  
-5.390E-06     16.27
 495  2.175E-03   3.213E-04     -31.495637   
3.227E-05     16.55
 496  6.120E-04   1.255E-04     -31.495666  
-2.921E-05     16.82
 497  5.619E-04   8.793E-05     -31.495669  
-3.058E-06     17.10
 498  5.226E-04   9.503E-05     -31.495670  
-1.176E-06     17.37
 499  5.016E-04   7.269E-05     -31.495671  
-7.157E-07     17.65
 500  5.717E-04   7.913E-05     -31.495670   
6.671E-07     17.93
 501  5.839E-04   8.228E-05     -31.495670   
7.722E-08     18.20
 502  5.791E-04   7.814E-05     -31.495670   
8.968E-08     18.48
 503  5.689E-04   8.811E-05     -31.495670   
5.256E-08     18.76
 504  1.543E-03   3.881E-04     -31.495661   
8.814E-06     18.76
 ODIIS| Insufficient progress; reset!
 505  6.427E-04   1.207E-04     -31.495669  
-7.267E-06     16.27
 506  6.513E-04   1.183E-04     -31.495667   
1.332E-06     16.27
 507  1.170E-03   2.538E-04     -31.495648   
1.974E-05     16.54
 508  8.444E-04   1.998E-04     -31.495662  
-1.448E-05     16.83
 509  4.946E-04   7.128E-05     -31.495667  
-5.289E-06     17.10
 510  5.112E-04   6.471E-05     -31.495667   
5.145E-07     17.37
 511  5.126E-04   6.447E-05     -31.495666   
6.777E-07     17.65
 512  5.689E-04   6.553E-05     -31.495666   
3.599E-07     17.92
 513  8.051E-04   1.848E-04     -31.495663   
3.316E-06     18.21
 514  1.638E-03   3.620E-04     -31.495659   
3.615E-06     18.48
 515  9.369E-04   2.210E-04     -31.495658   
6.337E-07     18.76
 516  9.380E-04   2.256E-04     -31.495653   
5.791E-06     18.75
 ODIIS| Insufficient progress; reset!
 517  1.027E-03   2.324E-04     -31.495653  
-3.551E-07     16.27
 518  1.469E-03   2.158E-04     -31.495640   
1.238E-05     16.27
 519  7.587E-03   1.032E-03     -31.495348   
2.921E-04     16.54
 520  1.212E-03   1.888E-04     -31.495641  
-2.929E-04     16.83
 521  4.771E-04   7.352E-05     -31.495650  
-9.105E-06     17.09
 522  5.408E-04   7.262E-05     -31.495650  
-4.796E-08     17.38
 523  4.778E-04   6.909E-05     -31.495650   
3.421E-07     17.64
 524  5.439E-04   6.860E-05     -31.495650   
2.878E-07     17.93
 525  4.784E-04   6.718E-05     -31.495649   
1.151E-06     18.21
 526  4.795E-04   6.730E-05     -31.495645   
3.174E-06     18.47
 527  5.421E-04   6.998E-05     -31.495641   
4.047E-06     18.75
 528  5.485E-04   7.677E-05     -31.495636   
5.462E-06     18.75
 ODIIS| Insufficient progress; reset!
 529  4.813E-04   1.341E-04     -31.495635   
9.703E-07     16.27
 530  1.127E-03   1.473E-04     -31.495628   
6.737E-06     16.27
 531  6.864E-03   7.969E-04     -31.495448   
1.805E-04     16.55
 532  8.478E-04   1.460E-04     -31.495627  
-1.798E-04     16.82
 533  5.063E-04   8.560E-05     -31.495632  
-4.265E-06     17.10
 534  5.102E-04   7.427E-05     -31.495632  
-5.361E-07     17.38
 535  4.907E-04   7.839E-05     -31.495632   
6.820E-07     17.64
 536  4.841E-04   6.479E-05     -31.495630   
1.409E-06     17.92
 537  4.913E-04   7.488E-05     -31.495630   
3.922E-07     18.21
 538  8.911E-04   2.450E-04     -31.495625   
4.610E-06     18.48
 539  5.794E-03   1.458E-03     -31.495611   
1.378E-05     18.75
 540  6.976E-03   1.750E-03     -31.495608   
3.430E-06     18.75
 ODIIS| Insufficient progress; reset!
 541  2.011E-03   5.110E-04     -31.495630  
-2.232E-05     16.27
 542  9.733E-04   1.825E-04     -31.495625   
5.362E-06     16.27
 543  6.279E-03   7.922E-04     -31.495475   
1.496E-04     16.54
 544  6.132E-04   1.324E-04     -31.495626  
-1.509E-04     16.83
 545  4.865E-04   8.124E-05     -31.495629  
-2.317E-06     17.09
 546  4.866E-04   7.590E-05     -31.495629  
-4.180E-07     17.38
 547  4.864E-04   6.970E-05     -31.495629  
-1.019E-07     17.66
 548  4.865E-04   6.618E-05     -31.495629   
1.846E-08     17.93
 549  4.863E-04   7.979E-05     -31.495629   
3.515E-07     18.21
 550  4.864E-04   8.131E-05     -31.495628   
6.424E-07     18.47
 551  4.864E-04   8.508E-05     -31.495627   
1.158E-06     18.75
 552  4.861E-04   1.065E-04     -31.495624   
2.655E-06     18.76
 ODIIS| Insufficient progress; reset!
 553  4.938E-04   1.260E-04     -31.495622   
2.303E-06     16.26
 554  4.875E-04   1.088E-04     -31.495620   
2.279E-06     16.28
 555  1.622E-03   2.659E-04     -31.495599   
2.059E-05     16.54
 556  4.879E-04   1.036E-04     -31.495614  
-1.521E-05     16.84
 557  4.912E-04   1.037E-04     -31.495617  
-2.148E-06     17.10
 558  4.890E-04   8.082E-05     -31.495618  
-1.695E-06     17.36
 559  4.890E-04   6.286E-05     -31.495618  
-1.173E-07     17.65
 560  4.893E-04   7.568E-05     -31.495618   
4.770E-07     17.93
 561  4.893E-04   8.231E-05     -31.495618   
8.603E-08     18.20
 562  1.402E-03   3.072E-04     -31.495613   
4.754E-06     18.48
 563  4.452E-03   9.436E-04     -31.495579   
3.390E-05     18.77
 564  4.900E-04   9.448E-05     -31.495617  
-3.749E-05     18.74
 ODIIS| Insufficient progress; reset!
 565  6.182E-04   1.567E-04     -31.495615   
1.591E-06     16.28
 566  7.684E-04   1.717E-04     -31.495602   
1.272E-05     16.26
 567  1.724E-03   2.715E-04     -31.495588   
1.429E-05     16.55
 568  6.726E-04   1.256E-04     -31.495605  
-1.661E-05     16.83
 569  5.128E-04   1.118E-04     -31.495607  
-2.484E-06     17.09
 570  4.918E-04   6.104E-05     -31.495609  
-1.697E-06     17.38
 571  4.921E-04   6.942E-05     -31.495608   
5.155E-07     17.65
 572  4.924E-04   5.656E-05     -31.495608   
2.378E-07     17.93
 573  4.926E-04   5.696E-05     -31.495607   
6.975E-07     18.21
 574  4.930E-04   6.622E-05     -31.495605   
1.966E-06     18.48
 575  4.931E-04   6.926E-05     -31.495604   
1.141E-06     18.76
 576  4.928E-04   7.408E-05     -31.495600   
4.212E-06     18.77
 ODIIS| Insufficient progress; reset!
 577  5.225E-04   1.122E-04     -31.495599   
1.371E-06     16.27
 578  7.400E-04   1.426E-04     -31.495595   
3.429E-06     16.26
 579  3.555E-03   4.781E-04     -31.495527   
6.861E-05     16.55
 580  9.450E-04   1.864E-04     -31.495589  
-6.287E-05     16.82
 581  4.958E-04   8.934E-05     -31.495595  
-5.841E-06     17.09
 582  4.950E-04   9.717E-05     -31.495596  
-6.297E-07     17.38
 583  4.952E-04   6.831E-05     -31.495596  
-3.239E-07     17.64
 584  4.954E-04   7.407E-05     -31.495596   
5.417E-07     17.94
 585  4.957E-04   6.204E-05     -31.495595   
7.434E-07     18.20
 586  5.109E-04   1.278E-04     -31.495593   
1.981E-06     18.48
 587  3.963E-03   1.006E-03     -31.495589   
4.380E-06     18.76
 588  6.754E-04   1.691E-04     -31.495587   
1.970E-06     18.75
 ODIIS| Insufficient progress; reset!
 589  8.787E-04   2.121E-04     -31.495585   
1.929E-06     16.27
 590  5.609E-04   1.006E-04     -31.495579   
5.690E-06     16.28
 591  3.220E-03   4.397E-04     -31.495533   
4.602E-05     16.55
 592  4.959E-04   7.867E-05     -31.495580  
-4.670E-05     16.82
 593  4.981E-04   4.725E-05     -31.495580  
-6.246E-07     17.10
 594  4.988E-04   6.464E-05     -31.495579   
1.299E-06     17.36
 595  4.985E-04   5.700E-05     -31.495579   
4.552E-07     17.65
 596  4.987E-04   6.315E-05     -31.495578   
7.054E-07     17.92
 597  4.988E-04   6.804E-05     -31.495576   
1.687E-06     18.20
 598  4.987E-04   6.725E-05     -31.495574   
2.329E-06     18.48
 599  4.983E-04   7.300E-05     -31.495568   
5.807E-06     18.76
 600  4.979E-04   7.982E-05     -31.495563   
5.324E-06     18.77
 ODIIS| Insufficient progress; reset!
 601  5.062E-04   1.260E-04     -31.495556   
6.389E-06     16.27
 602  5.708E-04   1.338E-04     -31.495549   
7.117E-06     16.27
 603  3.155E-03   4.638E-04     -31.495496   
5.288E-05     16.55
 604  5.179E-04   9.524E-05     -31.495550  
-5.319E-05     16.82
 605  5.096E-04   7.771E-05     -31.495551  
-1.287E-06     17.09
 606  5.099E-04   7.399E-05     -31.495552  
-6.925E-07     17.37
 607  5.091E-04   6.226E-05     -31.495551   
2.188E-07     17.66
 608  5.096E-04   7.667E-05     -31.495550   
8.909E-07     17.92
 609  5.102E-04   5.852E-05     -31.495549   
1.090E-06     18.21
 610  5.103E-04   6.171E-05     -31.495547   
1.857E-06     18.49
 611  5.104E-04   7.557E-05     -31.495546   
1.624E-06     18.75
 612  1.243E-03   3.223E-04     -31.495541   
4.435E-06     18.75
 ODIIS| Insufficient progress; reset!
 613  2.478E-03   6.674E-04     -31.495535   
6.456E-06     16.27
 614  6.778E-04   1.441E-04     -31.495532   
2.811E-06     16.26
 615  2.732E-03   4.031E-04     -31.495487   
4.562E-05     16.55
 616  5.150E-04   9.550E-05     -31.495528  
-4.185E-05     16.82
 617  5.147E-04   7.400E-05     -31.495530  
-1.625E-06     17.10
 618  5.148E-04   6.069E-05     -31.495531  
-8.512E-07     17.38
 619  5.152E-04   6.109E-05     -31.495531   
3.047E-07     17.66
 620  5.154E-04   5.712E-05     -31.495530   
3.682E-07     17.93
 621  5.154E-04   5.626E-05     -31.495530  
-9.293E-08     18.19
 622  8.276E-04   2.082E-04     -31.495533  
-3.193E-06     18.47
 623  6.357E-04   1.577E-04     -31.495527   
6.433E-06     18.76
 624  6.378E-04   1.639E-04     -31.495526   
9.275E-07     18.76
 ODIIS| Insufficient progress; reset!
 625  7.422E-04   1.621E-04     -31.495521   
4.958E-06     16.26
 626  5.250E-04   8.296E-05     -31.495517   
4.460E-06     16.27
 627  1.916E-03   3.112E-04     -31.495492   
2.499E-05     16.55
 628  5.236E-04   7.302E-05     -31.495516  
-2.452E-05     16.82
 629  5.253E-04   4.771E-05     -31.495517  
-4.388E-07     17.10
 630  5.270E-04   6.193E-05     -31.495515   
1.295E-06     17.38
 631  5.265E-04   5.596E-05     -31.495515   
2.652E-07     17.66
 632  5.263E-04   5.870E-05     -31.495515  
-7.796E-08     17.93
 633  5.263E-04   4.056E-05     -31.495515   
6.402E-07     18.20
 634  5.277E-04   6.319E-05     -31.495512   
2.758E-06     18.47
 635  5.293E-04   1.184E-04     -31.495508   
4.137E-06     18.75
 636  5.601E-04   1.309E-04     -31.495508  
-4.318E-07     18.76
 ODIIS| Insufficient progress; reset!
 637  1.086E-03   2.225E-04     -31.495501   
6.867E-06     16.26
 638  8.193E-04   1.429E-04     -31.495492   
9.182E-06     16.27
 639  4.405E-03   6.114E-04     -31.495390   
1.018E-04     16.54
 640  6.178E-04   1.180E-04     -31.495491  
-1.008E-04     16.83
 641  5.386E-04   9.097E-05     -31.495495  
-3.756E-06     17.10
 642  5.382E-04   6.703E-05     -31.495495  
-7.350E-08     17.37
 643  5.393E-04   6.613E-05     -31.495494   
8.243E-07     17.66
 644  5.392E-04   4.912E-05     -31.495494   
6.036E-08     17.92
 645  5.392E-04   4.640E-05     -31.495494   
7.777E-08     18.21
 646  5.402E-04   7.963E-05     -31.495492   
1.830E-06     18.48
 647  8.361E-04   2.194E-04     -31.495494  
-2.001E-06     18.76
 648  5.434E-04   8.970E-05     -31.495490   
4.292E-06     18.75
 ODIIS| Insufficient progress; reset!
 649  9.746E-04   2.690E-04     -31.495486   
3.402E-06     16.27
 650  5.426E-04   6.843E-05     -31.495487  
-2.413E-07     16.26
 651  1.043E-03   1.770E-04     -31.495475   
1.184E-05     16.54
 652  5.464E-04   1.318E-04     -31.495483  
-8.071E-06     16.82
 653  5.453E-04   4.509E-05     -31.495484  
-1.631E-06     17.10
 654  5.456E-04   4.511E-05     -31.495484   
5.853E-07     17.37
 655  5.456E-04   5.259E-05     -31.495483   
6.904E-07     17.65
 656  5.456E-04   4.817E-05     -31.495483   
3.892E-08     17.93
 657  5.458E-04   4.355E-05     -31.495483   
3.889E-07     18.20
 658  5.477E-04   8.353E-05     -31.495480   
2.578E-06     18.48
 659  8.207E-04   2.525E-04     -31.495462   
1.786E-05     18.76
 660  8.409E-04   1.836E-04     -31.495495  
-3.248E-05     18.75
 ODIIS| Insufficient progress; reset!
 661  7.250E-04   2.177E-04     -31.495466   
2.930E-05     16.27
 662  5.625E-04   7.156E-05     -31.495466  
-4.490E-07     16.28
 663  2.434E-03   3.187E-04     -31.495438   
2.791E-05     16.54
 664  5.598E-04   7.209E-05     -31.495463  
-2.535E-05     16.82
 665  5.618E-04   5.963E-05     -31.495464  
-4.751E-07     17.10
 666  5.619E-04   5.512E-05     -31.495464  
-1.020E-07     17.37
 667  5.619E-04   4.173E-05     -31.495464   
1.713E-07     17.65
 668  5.631E-04   6.691E-05     -31.495461   
2.584E-06     17.93
 669  5.632E-04   6.530E-05     -31.495461   
2.065E-07     18.21
 670  5.632E-04   4.490E-05     -31.495461   
4.244E-07     18.47
 671  5.631E-04   8.539E-05     -31.495460   
6.220E-07     18.75
 672  1.495E-03   2.930E-04     -31.495458   
2.038E-06     18.77
 ODIIS| Insufficient progress; reset!
 673  2.174E-03   3.982E-04     -31.495458   
3.275E-07     16.27
 674  5.645E-04   6.847E-05     -31.495456   
1.911E-06     16.27
 675  9.906E-04   1.342E-04     -31.495448   
8.159E-06     16.54
 676  5.651E-04   6.157E-05     -31.495452  
-4.379E-06     16.82
 677  5.653E-04   7.563E-05     -31.495452   
1.272E-07     17.08
 678  5.651E-04   7.384E-05     -31.495452   
5.344E-08     17.38
 679  5.660E-04   6.356E-05     -31.495450   
1.626E-06     17.66
 680  5.661E-04   5.749E-05     -31.495450   
5.535E-07     17.92
 681  5.678E-04   7.212E-05     -31.495447   
2.229E-06     18.20
 682  5.745E-04   7.895E-05     -31.495440   
7.329E-06     18.48
 683  5.760E-04   8.809E-05     -31.495437   
2.670E-06     18.77
 684  5.780E-04   9.075E-05     -31.495432   
5.449E-06     18.75
 ODIIS| Insufficient progress; reset!
 685  5.867E-04   9.470E-05     -31.495428   
4.330E-06     16.27
 686  5.826E-04   9.146E-05     -31.495423   
4.095E-06     16.26
 687  2.609E-03   3.820E-04     -31.495380   
4.366E-05     16.54
 688  5.881E-04   9.187E-05     -31.495421  
-4.100E-05     16.83
 689  5.876E-04   7.810E-05     -31.495422  
-1.316E-06     17.10
 690  5.880E-04   4.200E-05     -31.495422   
1.346E-07     17.37
 691  5.883E-04   4.606E-05     -31.495420   
1.631E-06     17.65
 692  5.885E-04   4.153E-05     -31.495420   
4.754E-07     17.93
 693  5.891E-04   3.802E-05     -31.495418   
1.436E-06     18.21
 694  5.915E-04   4.138E-05     -31.495414   
4.326E-06     18.47
 695  5.942E-04   6.145E-05     -31.495410   
4.174E-06     18.76
 696  2.963E-03   8.229E-04     -31.495403   
7.078E-06     18.76
 ODIIS| Insufficient progress; reset!
 697  5.321E-03   1.468E-03     -31.495399   
4.096E-06     16.26
 698  6.023E-04   1.101E-04     -31.495403  
-3.954E-06     16.28
 699  3.480E-03   5.095E-04     -31.495337   
6.561E-05     16.54
 700  5.956E-04   1.316E-04     -31.495400  
-6.312E-05     16.81
 701  5.978E-04   6.714E-05     -31.495403  
-2.331E-06     17.10
 702  5.978E-04   9.638E-05     -31.495402   
7.708E-07     17.37
 703  5.983E-04   8.500E-05     -31.495401   
1.015E-06     17.65
 704  5.983E-04   8.153E-05     -31.495401  
-7.211E-08     17.93
 705  5.984E-04   7.684E-05     -31.495400   
4.276E-07     18.20
 706  5.989E-04   8.622E-05     -31.495400   
8.005E-07     18.47
 707  8.278E-04   2.066E-04     -31.495397   
2.283E-06     18.76
 708  7.868E-03   1.711E-03     -31.495389   
8.076E-06     18.75
 ODIIS| Insufficient progress; reset!
 709  5.926E-04   1.222E-04     -31.495404  
-1.476E-05     16.27
 710  5.922E-04   1.324E-04     -31.495398   
5.700E-06     16.27
 711  6.508E-04   1.542E-04     -31.495388   
1.024E-05     16.54
 712  5.957E-04   1.096E-04     -31.495395  
-7.376E-06     16.82
 713  5.931E-04   7.431E-05     -31.495397  
-1.611E-06     17.10
 714  5.949E-04   6.197E-05     -31.495397   
6.114E-08     17.38
 715  5.950E-04   4.498E-05     -31.495397   
2.016E-07     17.66
 716  5.954E-04   4.870E-05     -31.495396   
1.131E-06     17.93
 717  5.957E-04   3.896E-05     -31.495395   
1.027E-06     18.20
 718  5.965E-04   4.176E-05     -31.495393   
1.506E-06     18.48
 719  6.027E-04   4.412E-05     -31.495385   
8.043E-06     18.74
 720  6.079E-04   6.496E-05     -31.495379   
6.193E-06     18.76
 ODIIS| Insufficient progress; reset!
 721  6.052E-04   1.588E-04     -31.495381  
-1.895E-06     16.28
 722  6.086E-04   7.949E-05     -31.495376   
4.482E-06     16.27
 723  2.544E-03   3.479E-04     -31.495342   
3.395E-05     16.54
 724  6.068E-04   7.224E-05     -31.495373  
-3.051E-05     16.82
 725  6.079E-04   5.209E-05     -31.495373  
-2.004E-07     17.10
 726  6.087E-04   7.517E-05     -31.495372   
1.276E-06     17.38
 727  6.087E-04   7.215E-05     -31.495371   
3.274E-07     17.65
 728  6.086E-04   6.957E-05     -31.495372  
-9.179E-08     17.92
 729  6.088E-04   9.948E-05     -31.495371   
6.407E-07     18.20
 730  9.320E-04   2.367E-04     -31.495361   
9.773E-06     18.47
 731  6.077E-04   1.017E-04     -31.495372  
-1.109E-05     18.75
 732  6.083E-04   1.192E-04     -31.495374  
-1.877E-06     18.77
 ODIIS| Insufficient progress; reset!
 733  7.261E-04   1.901E-04     -31.495368   
6.516E-06     16.27
 734  6.092E-04   4.773E-05     -31.495367   
1.574E-07     16.26
 735  6.629E-04   1.357E-04     -31.495361   
6.820E-06     16.55
 736  6.098E-04   5.566E-05     -31.495364  
-3.571E-06     16.83
 737  6.100E-04   3.754E-05     -31.495364   
8.036E-08     17.09
 738  6.099E-04   4.604E-05     -31.495363   
7.368E-07     17.38
 739  6.100E-04   5.316E-05     -31.495362   
1.299E-06     17.65
 740  6.101E-04   9.160E-05     -31.495360   
1.851E-06     17.93
 741  6.097E-04   1.336E-04     -31.495356   
3.929E-06     18.20
 742  2.486E-03   5.926E-04     -31.495283   
7.336E-05     18.48
 743  6.111E-04   1.123E-04     -31.495350  
-6.742E-05     18.76
 744  6.115E-04   8.674E-05     -31.495347   
3.345E-06     18.75
 ODIIS| Insufficient progress; reset!
 745  6.094E-04   8.802E-05     -31.495343   
3.745E-06     16.28
 746  6.138E-04   5.036E-05     -31.495340   
3.376E-06     16.26
 747  1.602E-03   2.183E-04     -31.495325   
1.500E-05     16.55
 748  6.106E-04   7.737E-05     -31.495337  
-1.180E-05     16.83
 749  6.121E-04   6.205E-05     -31.495337  
-4.317E-07     17.09
 750  6.123E-04   6.228E-05     -31.495336   
6.664E-07     17.37
 751  6.133E-04   5.811E-05     -31.495334   
2.141E-06     17.66
 752  6.134E-04   5.272E-05     -31.495334   
2.680E-07     17.91
 753  6.139E-04   5.600E-05     -31.495333   
1.338E-06     18.21
 754  6.153E-04   5.660E-05     -31.495331   
1.764E-06     18.49
 755  6.349E-04   1.059E-04     -31.495313   
1.765E-05     18.75
 756  8.434E-04   1.907E-04     -31.495294   
1.889E-05     18.76
 ODIIS| Insufficient progress; reset!
 757  6.554E-04   1.391E-04     -31.495296  
-1.302E-06     16.27
 758  8.103E-04   1.370E-04     -31.495289   
7.127E-06     16.27
 759  3.726E-03   6.414E-04     -31.495184   
1.050E-04     16.55
 760  6.551E-04   9.887E-05     -31.495286  
-1.023E-04     16.82
 761  6.582E-04   6.985E-05     -31.495288  
-2.021E-06     17.10
 762  6.593E-04   5.964E-05     -31.495287   
5.057E-07     17.37
 763  6.598E-04   6.143E-05     -31.495286   
1.069E-06     17.64
 764  6.597E-04   6.421E-05     -31.495286  
-3.977E-08     17.93
 765  6.598E-04   5.815E-05     -31.495286   
2.847E-07     18.20
 766  6.617E-04   1.168E-04     -31.495283   
3.515E-06     18.48
 767  6.587E-04   7.486E-05     -31.495285  
-2.252E-06     18.75
 768  6.598E-04   5.984E-05     -31.495284   
9.693E-07     18.76
 ODIIS| Insufficient progress; reset!
 769  1.925E-03   4.065E-04     -31.495272   
1.203E-05     16.26
 770  6.635E-04   8.718E-05     -31.495271   
5.123E-07     16.27
 771  6.555E-04   1.567E-04     -31.495264   
7.881E-06     16.55
 772  6.647E-04   7.445E-05     -31.495269  
-5.010E-06     16.82
 773  6.629E-04   6.128E-05     -31.495269  
-2.599E-07     17.10
 774  6.638E-04   4.433E-05     -31.495268   
7.959E-07     17.38
 775  6.642E-04   6.547E-05     -31.495267   
9.342E-07     17.65
 776  6.639E-04   7.085E-05     -31.495267  
-2.417E-07     17.92
 777  6.641E-04   8.297E-05     -31.495266   
9.490E-07     18.20
 778  9.656E-04   2.043E-04     -31.495264   
2.262E-06     18.49
 779  2.582E-03   4.870E-04     -31.495269  
-5.163E-06     18.76
 780  6.610E-04   8.395E-05     -31.495265   
4.057E-06     18.76
 ODIIS| Insufficient progress; reset!
 781  2.320E-03   4.876E-04     -31.495266  
-1.283E-06     16.28
 782  6.551E-04   1.490E-04     -31.495258   
8.585E-06     16.25
 783  2.685E-03   4.514E-04     -31.495212   
4.590E-05     16.55
 784  6.616E-04   8.990E-05     -31.495262  
-4.999E-05     16.82
 785  6.568E-04   1.047E-04     -31.495261   
8.430E-07     17.10
 786  6.580E-04   4.516E-05     -31.495261   
1.648E-07     17.38
 787  6.597E-04   4.109E-05     -31.495260   
6.598E-07     17.65
 788  6.601E-04   5.251E-05     -31.495259   
9.593E-07     17.93
 789  6.613E-04   4.218E-05     -31.495258   
1.503E-06     18.20
 790  6.642E-04   4.365E-05     -31.495254   
3.720E-06     18.48
 791  6.660E-04   5.023E-05     -31.495251   
3.496E-06     18.76
 792  6.690E-04   5.467E-05     -31.495245   
5.392E-06     18.76
 ODIIS| Insufficient progress; reset!
 793  9.656E-04   2.352E-04     -31.495242   
2.754E-06     16.27
 794  6.774E-04   7.591E-05     -31.495239   
3.502E-06     16.27
 795  1.665E-03   2.472E-04     -31.495220   
1.883E-05     16.54
 796  6.752E-04   9.166E-05     -31.495235  
-1.482E-05     16.82
 797  6.768E-04   6.047E-05     -31.495236  
-6.857E-07     17.11
 798  6.775E-04   6.773E-05     -31.495236  
-9.736E-08     17.37
 799  6.770E-04   5.427E-05     -31.495235   
3.612E-07     17.65
 800  6.781E-04   7.191E-05     -31.495231   
4.083E-06     17.92
 801  6.788E-04   7.457E-05     -31.495231  
-6.740E-08     18.20
 802  6.788E-04   7.593E-05     -31.495231   
2.152E-07     18.49
 803  6.791E-04   8.217E-05     -31.495230   
8.377E-07     18.75
 804  1.321E-03   2.050E-04     -31.495230   
6.428E-07     18.76
 ODIIS| Insufficient progress; reset!
 805  7.391E-03   1.097E-03     -31.495215   
1.421E-05     16.27
 806  6.899E-04   1.034E-04     -31.495216  
-6.904E-07     16.28
 807  7.294E-04   1.494E-04     -31.495208   
7.926E-06     16.53
 808  6.897E-04   1.045E-04     -31.495214  
-5.620E-06     16.83
 809  6.916E-04   7.331E-05     -31.495215  
-7.303E-07     17.10
 810  6.905E-04   5.564E-05     -31.495212   
2.127E-06     17.36
 811  6.917E-04   5.299E-05     -31.495212   
8.818E-07     17.65
 812  6.921E-04   5.412E-05     -31.495210   
1.068E-06     17.93
 813  6.921E-04   8.233E-05     -31.495210   
7.684E-07     18.20
 814  1.382E-03   3.802E-04     -31.495207   
2.950E-06     18.47
 815  1.406E-03   3.762E-04     -31.495206   
1.057E-06     18.75
 816  1.378E-03   3.733E-04     -31.495206  
-6.192E-07     18.76
 ODIIS| Insufficient progress; reset!
 817  1.647E-03   4.359E-04     -31.495202   
3.899E-06     16.28
 818  6.923E-04   7.743E-05     -31.495200   
2.642E-06     16.25
 819  1.767E-03   2.434E-04     -31.495182   
1.788E-05     16.53
 820  6.960E-04   9.858E-05     -31.495196  
-1.394E-05     16.83
 821  6.946E-04   8.132E-05     -31.495196   
1.454E-07     17.09
 822  6.954E-04   7.831E-05     -31.495196  
-5.491E-08     17.38
 823  6.955E-04   8.439E-05     -31.495195   
2.817E-07     17.66
 824  6.956E-04   8.358E-05     -31.495195   
7.282E-07     17.93
 825  6.957E-04   9.249E-05     -31.495195   
1.968E-07     18.21
 826  6.958E-04   1.320E-04     -31.495194   
9.631E-07     18.48
 827  6.960E-04   1.089E-04     -31.495193   
1.239E-07     18.75
 828  6.961E-04   9.754E-05     -31.495193   
5.334E-07     18.76
 ODIIS| Insufficient progress; reset!
 829  1.066E-03   1.722E-04     -31.495190   
2.477E-06     16.26
 830  6.965E-04   6.431E-05     -31.495187   
3.841E-06     16.28
 831  6.945E-04   1.188E-04     -31.495180   
6.720E-06     16.54
 832  6.981E-04   8.213E-05     -31.495183  
-2.795E-06     16.82
 833  6.975E-04   4.526E-05     -31.495183  
-4.218E-07     17.10
 834  6.977E-04   3.411E-05     -31.495183   
1.262E-07     17.38
 835  6.977E-04   3.710E-05     -31.495183   
1.387E-07     17.65
 836  6.978E-04   4.098E-05     -31.495183   
1.997E-07     17.93
 837  6.977E-04   9.467E-05     -31.495181   
1.696E-06     18.20
 838  2.527E-03   4.549E-04     -31.495156   
2.509E-05     18.47
 839  7.136E-04   1.444E-04     -31.495180  
-2.433E-05     18.77
 840  9.659E-04   1.847E-04     -31.495181  
-1.101E-06     18.74
 ODIIS| Insufficient progress; reset!
 841  2.217E-03   4.915E-04     -31.495168   
1.295E-05     16.27
 842  1.025E-03   2.087E-04     -31.495165   
3.035E-06     16.27
 843  7.707E-04   1.497E-04     -31.495157   
8.388E-06     16.54
 844  6.969E-04   1.123E-04     -31.495161  
-4.416E-06     16.83
 845  7.003E-04   6.648E-05     -31.495163  
-1.989E-06     17.10
 846  7.024E-04   5.122E-05     -31.495164  
-8.290E-07     17.38
 847  7.020E-04   5.615E-05     -31.495164   
1.084E-07     17.65
 848  7.021E-04   5.367E-05     -31.495164  
-5.519E-08     17.93
 849  7.021E-04   4.828E-05     -31.495164   
1.134E-07     18.20
 850  7.020E-04   5.779E-05     -31.495163   
9.529E-07     18.48
 851  7.024E-04   5.426E-05     -31.495161   
1.595E-06     18.76
 ODIIS| Insufficient progress for K =        2; reset!
 852  1.508E-03   3.502E-04     -31.495144   
1.738E-05     18.75
 853  3.353E-03   8.062E-04     -31.495111   
3.313E-05     16.26
 854  7.069E-04   1.058E-04     -31.495152  
-4.093E-05     16.55
 855  7.031E-04   1.337E-04     -31.495155  
-2.758E-06     16.82
 856  7.048E-04   3.546E-05     -31.495156  
-1.699E-06     17.10
 857  7.059E-04   6.155E-05     -31.495155   
1.712E-06     17.37
 858  7.058E-04   4.677E-05     -31.495154   
1.870E-07     17.66
 859  7.057E-04   4.505E-05     -31.495154   
2.011E-08     17.92
 860  7.059E-04   3.575E-05     -31.495154   
5.117E-07     18.20
 861  7.062E-04   3.571E-05     -31.495153   
1.194E-06     18.49
 862  7.066E-04   3.422E-05     -31.495150   
2.303E-06     18.76
 ODIIS| Insufficient progress for K =       16; reset!
 863  7.088E-04   4.090E-05     -31.495147   
2.989E-06     18.76
 864  4.565E-03   1.150E-03     -31.495071   
7.607E-05     16.27
 865  1.835E-03   3.368E-04     -31.495065   
6.197E-06     16.54
 866  8.341E-04   1.664E-04     -31.495092  
-2.720E-05     16.83
 867  7.720E-04   8.864E-05     -31.495093  
-3.366E-07     17.09
 868  7.726E-04   4.617E-05     -31.495091   
1.218E-06     17.38
 869  7.736E-04   4.423E-05     -31.495090   
1.535E-06     17.65
 870  7.747E-04   4.657E-05     -31.495089   
1.108E-06     17.92
 871  7.756E-04   4.158E-05     -31.495088   
3.848E-07     18.20
 872  7.773E-04   4.572E-05     -31.495086   
2.105E-06     18.48
 873  7.784E-04   4.981E-05     -31.495085   
1.609E-06     18.76
 ODIIS| Insufficient progress for K =       21; reset!
 874  7.800E-04   4.550E-05     -31.495082   
2.686E-06     18.76
 875  7.813E-04   8.307E-05     -31.495080   
2.445E-06     16.26
 876  7.829E-04   9.092E-05     -31.495075   
4.600E-06     16.56
 877  7.826E-04   3.695E-05     -31.495075  
-5.055E-07     16.82
 878  7.833E-04   5.566E-05     -31.495074   
1.323E-06     17.11
 879  7.834E-04   6.127E-05     -31.495074   
1.435E-07     17.37
 880  7.836E-04   6.776E-05     -31.495074   
4.609E-07     17.64
 881  7.840E-04   1.161E-04     -31.495071   
2.823E-06     17.94
 882  2.773E-03   6.413E-04     -31.495065   
5.717E-06     18.20
 883  1.119E-03   2.933E-04     -31.495066  
-1.099E-06     18.48
 884  1.101E-03   2.710E-04     -31.495066  
-2.325E-07     18.75
 885  2.463E-03   5.432E-04     -31.495074  
-7.824E-06     18.76
 ODIIS| Insufficient progress; reset!
 886  2.349E-03   5.362E-04     -31.495055   
1.883E-05     16.27
 887  7.862E-04   1.254E-04     -31.495056  
-3.271E-07     16.27
 888  4.744E-03   5.245E-04     -31.494986   
6.962E-05     16.55
 889  7.898E-04   8.652E-05     -31.495054  
-6.810E-05     16.83
 890  7.881E-04   8.492E-05     -31.495055  
-1.148E-06     17.10
 891  7.888E-04   6.581E-05     -31.495055   
5.489E-07     17.37
 892  7.895E-04   7.035E-05     -31.495053   
1.746E-06     17.65
 893  7.898E-04   5.240E-05     -31.495052   
5.485E-07     17.93
 894  7.902E-04   4.349E-05     -31.495051   
1.529E-06     18.20
 895  7.906E-04   3.920E-05     -31.495049   
2.179E-06     18.49
 896  7.909E-04   4.064E-05     -31.495045   
4.057E-06     18.75
 897  7.716E-04   9.874E-05     -31.495046  
-9.983E-07     18.74
 ODIIS| Insufficient progress; reset!
 898  9.000E-04   1.612E-04     -31.495040   
5.884E-06     16.27
 899  7.892E-04   5.310E-05     -31.495036   
3.479E-06     16.26
 900  7.916E-04   1.318E-04     -31.495027   
9.583E-06     16.55
 901  7.910E-04   1.063E-04     -31.495030  
-3.660E-06     16.82
 902  7.910E-04   3.785E-05     -31.495032  
-1.261E-06     17.10
 903  7.914E-04   4.530E-05     -31.495031   
1.051E-06     17.38
 904  7.915E-04   4.714E-05     -31.495030   
4.605E-07     17.66
 905  7.910E-04   4.836E-05     -31.495031  
-3.437E-07     17.92
 906  7.920E-04   5.260E-05     -31.495030   
8.277E-07     18.21
 907  2.456E-03   5.251E-04     -31.495025   
4.370E-06     18.48
 908  4.303E-03   1.131E-03     -31.495010   
1.540E-05     18.75
 909  7.916E-04   1.914E-04     -31.495032  
-2.246E-05     18.76
 ODIIS| Insufficient progress; reset!
 910  2.052E-03   4.608E-04     -31.495013   
1.946E-05     16.27
 911  7.916E-04   6.149E-05     -31.495023  
-1.018E-05     16.27
 912  8.078E-04   1.487E-04     -31.495012   
1.134E-05     16.53
 913  7.944E-04   7.869E-05     -31.495016  
-4.194E-06     16.82
 914  7.939E-04   4.854E-05     -31.495017  
-1.049E-06     17.09
 915  7.946E-04   3.681E-05     -31.495016   
5.376E-07     17.38
 916  7.949E-04   6.164E-05     -31.495016   
8.658E-07     17.66
 917  7.949E-04   6.145E-05     -31.495016  
-2.023E-07     17.93
 918  7.951E-04   6.082E-05     -31.495016   
1.725E-07     18.19
 919  3.309E-02   7.067E-03     -31.493203   
1.813E-03     18.49
 920  2.760E-03   6.514E-04     -31.495008  
-1.805E-03     18.76
 921  2.758E-03   6.436E-04     -31.495013  
-5.134E-06     18.76
 ODIIS| Insufficient progress; reset!
 922  2.572E-03   5.912E-04     -31.495008   
5.619E-06     16.26
 923  7.980E-04   1.472E-04     -31.495002   
5.509E-06     16.27
 924  8.415E-04   1.872E-04     -31.494993   
9.512E-06     16.55
 925  8.023E-04   1.068E-04     -31.494997  
-4.003E-06     16.82
 926  7.979E-04   7.651E-05     -31.494997  
-6.008E-07     17.10
 927  7.998E-04   3.458E-05     -31.494997   
3.942E-08     17.38
 928  8.015E-04   5.310E-05     -31.494996   
1.839E-06     17.66
 929  8.012E-04   3.883E-05     -31.494994   
1.174E-06     17.92
 930  8.012E-04   4.026E-05     -31.494993   
8.882E-07     18.20
 931  8.016E-04   4.237E-05     -31.494992   
1.035E-06     18.48
 932  8.020E-04   3.542E-05     -31.494991   
1.111E-06     18.76
 933  9.245E-04   1.882E-04     -31.494985   
5.833E-06     18.76
 ODIIS| Insufficient progress; reset!
 934  8.097E-04   9.275E-05     -31.494991  
-5.276E-06     16.27
 935  8.094E-04   6.965E-05     -31.494986   
5.054E-06     16.27
 936  8.160E-04   1.713E-04     -31.494979   
6.663E-06     16.54
 937  8.111E-04   4.367E-05     -31.494985  
-5.650E-06     16.83
 938  8.123E-04   5.068E-05     -31.494983   
1.349E-06     17.10
 939  8.130E-04   4.635E-05     -31.494981   
1.980E-06     17.37
 940  8.130E-04   3.371E-05     -31.494980   
1.207E-06     17.64
 941  8.131E-04   3.413E-05     -31.494980   
5.715E-07     17.92
 942  8.131E-04   3.837E-05     -31.494979   
4.596E-07     18.21
 943  8.136E-04   5.429E-05     -31.494977   
2.187E-06     18.48
 944  8.187E-04   3.987E-05     -31.494969   
7.456E-06     18.75
 945  5.210E-03   1.123E-03     -31.495106  
-1.368E-04     18.76
 ODIIS| Insufficient progress; reset!
 946  8.117E-04   3.815E-05     -31.494978   
1.286E-04     16.27
 947  8.130E-04   6.787E-05     -31.494974   
4.081E-06     16.26
 948  8.143E-04   1.693E-04     -31.494961   
1.238E-05     16.55
 949  8.134E-04   9.559E-05     -31.494967  
-5.663E-06     16.82
 950  8.145E-04   6.455E-05     -31.494968  
-9.733E-07     17.10
 951  8.146E-04   8.461E-05     -31.494968  
-3.328E-08     17.37
 952  8.145E-04   6.763E-05     -31.494968  
-1.468E-07     17.65
 953  8.144E-04   8.713E-05     -31.494968  
-1.507E-07     17.92
 954  8.144E-04   7.713E-05     -31.494968  
-1.326E-07     18.20
 955  8.144E-04   5.552E-05     -31.494968  
-7.056E-08     18.49
 956  1.355E-03   2.873E-04     -31.494967   
1.505E-06     18.75
 957  2.300E-03   5.751E-04     -31.494954   
1.324E-05     18.76
 ODIIS| Insufficient progress; reset!
 958  4.879E-03   1.057E-03     -31.494910   
4.401E-05     16.26
 959  8.193E-04   6.749E-05     -31.494944  
-3.462E-05     16.27
 960  1.504E-03   2.112E-04     -31.494931   
1.304E-05     16.54
 961  8.174E-04   7.671E-05     -31.494942  
-1.084E-05     16.82
 962  8.192E-04   5.834E-05     -31.494942  
-4.981E-07     17.10
 963  8.190E-04   3.924E-05     -31.494942   
5.675E-07     17.38
 964  8.195E-04   4.850E-05     -31.494940   
2.266E-06     17.64
 965  8.195E-04   4.711E-05     -31.494940  
-3.134E-08     17.93
 966  8.201E-04   4.068E-05     -31.494938   
1.493E-06     18.20
 967  8.217E-04   3.802E-05     -31.494937   
1.339E-06     18.48
 968  8.180E-04   4.030E-05     -31.494935   
1.411E-06     18.75
 969  8.201E-04   6.382E-05     -31.494942  
-6.344E-06     18.76
 ODIIS| Insufficient progress; reset!
 970  8.192E-04   7.697E-05     -31.494928   
1.405E-05     16.27
 971  8.207E-04   6.576E-05     -31.494924   
3.681E-06     16.28
 972  1.348E-03   1.896E-04     -31.494910   
1.380E-05     16.54
 973  8.215E-04   9.363E-05     -31.494918  
-8.093E-06     16.83
 974  8.221E-04   5.356E-05     -31.494919  
-6.431E-07     17.10
 975  8.221E-04   6.187E-05     -31.494919   
1.893E-07     17.37
 976  8.221E-04   5.794E-05     -31.494919  
-2.751E-08     17.65
 977  8.192E-04   1.629E-04     -31.494919   
1.910E-09     17.92
 978  8.216E-04   9.321E-05     -31.494916   
2.737E-06     18.21
 979  8.215E-04   5.982E-05     -31.494915   
1.140E-06     18.48
 980  8.210E-04   1.075E-04     -31.494925  
-1.013E-05     18.76
 981  2.341E-03   6.084E-04     -31.494910   
1.522E-05     18.76
 ODIIS| Insufficient progress; reset!
 982  8.261E-03   1.694E-03     -31.494769   
1.404E-04     16.27
 983  1.209E-03   1.666E-04     -31.494864  
-9.417E-05     16.27
 984  4.723E-03   7.725E-04     -31.494714   
1.498E-04     16.55
 985  9.324E-04   1.250E-04     -31.494865  
-1.515E-04     16.81
 986  8.270E-04   6.687E-05     -31.494868  
-2.955E-06     17.10
 987  8.285E-04   4.774E-05     -31.494868   
2.779E-07     17.37
 988  8.283E-04   4.793E-05     -31.494866   
2.077E-06     17.65
 989  8.283E-04   4.689E-05     -31.494866   
4.108E-07     17.93
 990  8.281E-04   4.989E-05     -31.494865   
2.749E-07     18.21
 991  8.277E-04   3.386E-05     -31.494865   
6.785E-07     18.47
 992  6.227E-03   1.223E-03     -31.494811   
5.316E-05     18.76
 993  1.755E-03   3.940E-04     -31.494846  
-3.471E-05     18.73
 ODIIS| Insufficient progress; reset!
 994  8.294E-04   6.936E-05     -31.494861  
-1.452E-05     16.27
 995  8.303E-04   1.115E-04     -31.494854   
6.922E-06     16.27
 996  1.120E-03   2.231E-04     -31.494833   
2.058E-05     16.55
 997  8.306E-04   1.161E-04     -31.494846  
-1.297E-05     16.82
 998  8.323E-04   5.176E-05     -31.494849  
-2.451E-06     17.11
 999  8.330E-04   6.560E-05     -31.494847   
1.172E-06     17.36
1000  8.329E-04   4.954E-05     -31.494847   
7.226E-07     17.65
1001  8.330E-04   6.390E-05     -31.494846   
2.713E-07     17.91
1002  8.332E-04   4.367E-05     -31.494846   
8.745E-07     18.21
1003  8.335E-04   3.674E-05     -31.494844   
1.236E-06     18.49
1004  8.348E-04   4.115E-05     -31.494841   
3.019E-06     18.75
1005  9.549E-04   1.963E-04     -31.494838   
3.482E-06     18.76
 ODIIS| Insufficient progress; reset!
1006  1.449E-03   2.908E-04     -31.494834   
4.125E-06     16.27
1007  8.380E-04   6.811E-05     -31.494830   
3.846E-06     16.27
1008  1.256E-03   1.894E-04     -31.494817   
1.305E-05     16.54
1009  8.403E-04   7.276E-05     -31.494825  
-8.152E-06     16.83
1010  8.399E-04   6.206E-05     -31.494825  
-2.976E-07     17.10
1011  8.400E-04   6.100E-05     -31.494825  
-5.757E-08     17.37
1012  8.402E-04   5.903E-05     -31.494825   
4.709E-07     17.65
1013  8.404E-04   7.227E-05     -31.494824   
4.876E-07     17.92
1014  8.404E-04   7.305E-05     -31.494823   
1.137E-06     18.19
1015  8.398E-04   9.476E-05     -31.494824  
-8.770E-07     18.48
1016  1.600E-03   4.207E-04     -31.494817   
6.991E-06     18.76
1017  2.937E-03   7.068E-04     -31.494811   
6.529E-06     18.76
 ODIIS| Insufficient progress; reset!
1018  1.044E-03   2.604E-04     -31.494821  
-1.024E-05     16.26
1019  8.359E-04   1.049E-04     -31.494815   
5.526E-06     16.28
1020  1.390E-03   2.539E-04     -31.494799   
1.664E-05     16.55
1021  8.346E-04   8.289E-05     -31.494812  
-1.367E-05     16.83
1022  8.361E-04   9.359E-05     -31.494812   
2.231E-07     17.09
1023  8.360E-04   5.183E-05     -31.494811   
7.852E-07     17.39
1024  8.361E-04   3.382E-05     -31.494810   
1.258E-06     17.65
1025  8.363E-04   2.671E-05     -31.494810   
3.370E-07     17.93
1026  8.368E-04   2.707E-05     -31.494808   
1.228E-06     18.20
1027  8.373E-04   4.304E-05     -31.494803   
5.452E-06     18.48
1028  8.379E-04   3.015E-05     -31.494799   
3.679E-06     18.75
1029  9.373E-04   2.334E-04     -31.494792   
7.232E-06     18.76
 ODIIS| Insufficient progress; reset!
1030  8.477E-04   8.032E-05     -31.494794  
-1.518E-06     16.27
1031  8.498E-04   6.615E-05     -31.494789   
4.700E-06     16.27
1032  8.490E-04   1.360E-04     -31.494779   
1.027E-05     16.54
1033  8.498E-04   6.401E-05     -31.494782  
-3.117E-06     16.83
1034  8.519E-04   6.221E-05     -31.494782   
6.108E-09     17.09
1035  8.512E-04   3.339E-05     -31.494782   
2.011E-07     17.37
1036  8.515E-04   5.177E-05     -31.494778   
3.712E-06     17.66
1037  8.525E-04   3.608E-05     -31.494777   
1.304E-06     17.94
1038  8.529E-04   2.749E-05     -31.494776   
7.810E-07     18.20
1039  8.541E-04   2.623E-05     -31.494774   
1.862E-06     18.48
1040  8.759E-04   7.761E-05     -31.494759   
1.469E-05     18.75
1041  8.276E-04   7.506E-05     -31.494785  
-2.591E-05     18.76
 ODIIS| Insufficient progress; reset!
1042  8.363E-04   8.856E-05     -31.494763   
2.218E-05     16.26
1043  8.401E-04   5.852E-05     -31.494758   
4.954E-06     16.27
1044  2.357E-03   2.803E-04     -31.494732   
2.610E-05     16.54
1045  8.383E-04   9.664E-05     -31.494751  
-1.945E-05     16.81
1046  8.397E-04   5.467E-05     -31.494753  
-1.611E-06     17.11
1047  8.397E-04   3.977E-05     -31.494753   
3.371E-07     17.37
1048  8.399E-04   3.273E-05     -31.494752   
7.488E-07     17.65
1049  8.411E-04   4.442E-05     -31.494748   
3.800E-06     17.93
1050  8.426E-04   4.273E-05     -31.494745   
2.613E-06     18.20
1051  8.433E-04   4.647E-05     -31.494745   
7.316E-07     18.47
1052  8.542E-04   1.399E-04     -31.494740   
4.998E-06     18.76
1053  1.333E-03   3.055E-04     -31.494731   
9.116E-06     18.75
 ODIIS| Insufficient progress; reset!
1054  1.712E-03   3.815E-04     -31.494711   
1.973E-05     16.27
1055  9.059E-04   1.420E-04     -31.494707   
4.093E-06     16.27
1056  3.083E-03   5.800E-04     -31.494629   
7.751E-05     16.54
1057  9.075E-04   9.122E-05     -31.494707  
-7.752E-05     16.82
1058  9.079E-04   8.606E-05     -31.494707  
-5.766E-07     17.09
1059  9.084E-04   5.482E-05     -31.494707   
2.758E-07     17.39
1060  9.095E-04   3.637E-05     -31.494705   
1.756E-06     17.64
1061  9.097E-04   5.155E-05     -31.494704   
1.055E-06     17.93
1062  9.103E-04   5.336E-05     -31.494703   
1.571E-06     18.20
1063  9.101E-04   4.765E-05     -31.494703  
-6.604E-07     18.47
1064  9.102E-04   3.665E-05     -31.494703  
-7.303E-08     18.76
1065  9.106E-04   1.120E-04     -31.494699   
4.533E-06     18.75
 ODIIS| Insufficient progress; reset!
1066  9.120E-04   4.346E-05     -31.494700  
-8.623E-07     16.27
1067  9.126E-04   4.783E-05     -31.494695   
4.498E-06     16.26
1068  9.167E-04   1.293E-04     -31.494688   
7.223E-06     16.55
1069  9.148E-04   5.219E-05     -31.494690  
-2.022E-06     16.82
1070  9.149E-04   4.409E-05     -31.494690   
2.363E-07     17.11
1071  9.150E-04   5.405E-05     -31.494690   
3.002E-07     17.36
1072  9.151E-04   4.808E-05     -31.494690  
-1.881E-08     17.66
1073  9.153E-04   4.666E-05     -31.494689   
9.778E-07     17.93
1074  9.152E-04   5.084E-05     -31.494689  
-5.018E-07     18.20
1075  9.159E-04   1.557E-04     -31.494682   
6.883E-06     18.48
1076  9.140E-04   2.441E-04     -31.494682   
1.347E-07     18.75
1077  3.906E+00   1.433E-01     -31.350292   
1.444E-01     18.75
 ODIIS| Insufficient progress for K =        1; reset!
 ODIIS| Insufficient progress; reset!
1078  1.165E-03   3.216E-04     -31.494662  
-1.444E-01     16.27
1079  9.197E-04   1.549E-04     -31.494669  
-7.068E-06     16.27
1080  1.047E-03   2.241E-04     -31.494653   
1.635E-05     16.54
1081  9.198E-04   9.441E-05     -31.494663  
-1.033E-05     16.83
1082  9.228E-04   1.083E-04     -31.494664  
-2.996E-07     17.08
1083  9.235E-04   7.377E-05     -31.494664  
-6.564E-07     17.38
1084  9.229E-04   6.333E-05     -31.494664   
6.467E-07     17.65
1085  9.225E-04   7.007E-05     -31.494664  
-1.346E-07     17.94
1086  9.228E-04   6.771E-05     -31.494663   
3.207E-07     18.19
1087  9.235E-04   7.501E-05     -31.494662   
1.422E-06     18.48
1088  9.239E-04   9.492E-05     -31.494661   
5.161E-07     18.77
1089  1.526E-03   3.610E-04     -31.494661  
-9.956E-08     18.75
 ODIIS| Insufficient progress; reset!
1090  1.223E-03   2.655E-04     -31.494655   
6.979E-06     16.27
1091  9.301E-04   1.012E-04     -31.494648   
6.982E-06     16.27
1092  1.036E-03   1.848E-04     -31.494637   
1.017E-05     16.54
1093  9.286E-04   9.661E-05     -31.494646  
-8.943E-06     16.82
1094  9.308E-04   6.169E-05     -31.494647  
-1.147E-06     17.10
1095  9.296E-04   4.992E-05     -31.494647   
8.596E-07     17.38
1096  9.304E-04   6.554E-05     -31.494645   
1.326E-06     17.64
1097  9.304E-04   6.803E-05     -31.494645   
3.129E-07     17.93
1098  9.307E-04   5.341E-05     -31.494643   
1.657E-06     18.19
1099  9.319E-04   6.559E-05     -31.494639   
4.363E-06     18.48
1100  9.323E-04   1.609E-04     -31.494638   
1.221E-06     18.75
1101  9.322E-04   1.611E-04     -31.494638  
-3.654E-07     18.76
 ODIIS| Insufficient progress; reset!
1102  1.104E-03   2.006E-04     -31.494637   
1.098E-06     16.26
1103  9.338E-04   5.248E-05     -31.494632   
4.808E-06     16.27
1104  9.357E-04   1.383E-04     -31.494622   
1.052E-05     16.55
1105  9.352E-04   9.108E-05     -31.494625  
-2.966E-06     16.82
1106  9.357E-04   4.608E-05     -31.494626  
-1.019E-06     17.09
1107  9.360E-04   3.816E-05     -31.494625   
4.717E-07     17.37
1108  9.360E-04   3.736E-05     -31.494625   
2.514E-07     17.65
1109  9.360E-04   3.624E-05     -31.494624   
9.183E-07     17.93
1110  9.361E-04   1.045E-04     -31.494630  
-6.135E-06     18.21
1111  9.359E-04   4.783E-05     -31.494627   
3.338E-06     18.47
1112  9.408E-04   1.022E-04     -31.494626   
6.747E-07     18.75
1113  9.357E-04   6.473E-05     -31.494627  
-1.147E-06     18.76
 ODIIS| Insufficient progress; reset!
1114  9.376E-04   8.279E-05     -31.494617   
1.074E-05     16.27
1115  9.372E-04   1.038E-04     -31.494607   
9.369E-06     16.27
1116  9.470E-04   9.573E-05     -31.494602   
4.726E-06     16.55
1117  9.354E-04   9.386E-05     -31.494603  
-6.391E-07     16.82
1118  9.398E-04   6.907E-05     -31.494602   
8.009E-07     17.09
1119  9.418E-04   5.128E-05     -31.494601   
1.170E-06     17.38
1120  9.419E-04   4.861E-05     -31.494600   
7.493E-07     17.65
1121  9.419E-04   5.133E-05     -31.494600   
1.158E-07     17.92
1122  9.417E-04   5.225E-05     -31.494600  
-1.108E-07     18.20
1123  9.417E-04   1.331E-04     -31.494599   
1.032E-06     18.48
1124  9.418E-04   1.399E-04     -31.494599   
3.904E-07     18.76
 ODIIS| Insufficient progress for K =        2; reset!
1125  9.419E-04   8.678E-05     -31.494596   
2.863E-06     18.77
1126  4.798E-03   9.764E-04     -31.494546   
4.994E-05     16.28
1127  9.456E-04   9.564E-05     -31.494586  
-3.982E-05     16.53
1128  9.450E-04   8.884E-05     -31.494586  
-2.102E-07     16.82
1129  9.439E-04   5.501E-05     -31.494585   
8.122E-07     17.09
1130  9.455E-04   3.496E-05     -31.494585   
7.176E-07     17.37
1131  9.460E-04   3.364E-05     -31.494584   
4.256E-07     17.65
1132  9.464E-04   4.069E-05     -31.494581   
3.177E-06     17.92
1133  9.467E-04   3.255E-05     -31.494578   
2.533E-06     18.20
1134  9.471E-04   4.334E-05     -31.494578   
3.195E-07     18.48
1135  9.521E-04   3.683E-05     -31.494568   
9.912E-06     18.76
 ODIIS| Insufficient progress for K =       10; reset!
1136  1.315E-03   3.318E-04     -31.494624  
-5.552E-05     18.75
1137  8.221E-03   2.003E-03     -31.493917   
7.063E-04     16.26
1138  5.546E-03   6.541E-04     -31.493863   
5.480E-05     16.55
1139  1.188E-03   2.577E-04     -31.493972  
-1.092E-04     16.82
1140  1.218E-03   1.476E-04     -31.493978  
-6.346E-06     17.11
1141  1.222E-03   1.112E-04     -31.493978   
4.620E-07     17.38
1142  1.225E-03   9.870E-05     -31.493973   
4.518E-06     17.64
1143  1.226E-03   5.306E-05     -31.493971   
2.339E-06     17.93
1144  1.227E-03   6.004E-05     -31.493967   
3.936E-06     18.21
1145  1.228E-03   6.096E-05     -31.493961   
5.638E-06     18.48
1146  1.232E-03   4.942E-05     -31.493953   
8.539E-06     18.76
 ODIIS| Insufficient progress for K =       15; reset!
1147  1.235E-03   6.270E-05     -31.493941   
1.204E-05     18.76
1148  1.237E-03   7.196E-05     -31.493936   
4.619E-06     16.26
1149  1.239E-03   1.001E-04     -31.493925   
1.091E-05     16.56
1150  1.240E-03   1.018E-04     -31.493926  
-1.249E-06     16.83
1151  1.240E-03   4.239E-05     -31.493927  
-4.340E-07     17.09
1152  1.241E-03   3.909E-05     -31.493925   
1.778E-06     17.37
1153  1.245E-03   4.784E-05     -31.493918   
6.866E-06     17.65
1154  1.247E-03   1.202E-04     -31.493911   
6.790E-06     17.93
1155  2.892E-03   5.101E-04     -31.493899   
1.279E-05     18.22
1156  3.058E-03   5.383E-04     -31.493880   
1.871E-05     18.46
1157  3.479E-03   6.073E-04     -31.493981  
-1.010E-04     18.76
1158  3.152E-03   5.575E-04     -31.493930   
5.052E-05     18.74
 ODIIS| Insufficient progress; reset!
1159  4.369E-03   7.778E-04     -31.493878   
5.247E-05     16.27
1160  1.265E-03   1.391E-04     -31.493867   
1.120E-05     16.27
1161  2.959E-03   3.374E-04     -31.493831   
3.566E-05     16.55
1162  1.272E-03   1.053E-04     -31.493860  
-2.888E-05     16.81
1163  1.270E-03   1.230E-04     -31.493860  
-8.036E-08     17.11
1164  1.273E-03   7.303E-05     -31.493859   
1.527E-06     17.38
1165  1.273E-03   6.094E-05     -31.493856   
2.158E-06     17.65
1166  1.274E-03   5.753E-05     -31.493855   
1.840E-06     17.92
1167  1.275E-03   1.202E-04     -31.493850   
4.156E-06     18.20
1168  4.794E-03   1.129E-03     -31.493841   
9.700E-06     18.48
1169  5.085E-03   1.202E-03     -31.493838   
2.468E-06     18.75
1170  4.892E-03   1.160E-03     -31.493835   
3.468E-06     18.75
 ODIIS| Insufficient progress; reset!
1171  5.346E-03   1.210E-03     -31.493817   
1.753E-05     16.28
1172  1.283E-03   1.269E-04     -31.493813   
4.601E-06     16.26
1173  1.289E-03   1.661E-04     -31.493798   
1.463E-05     16.55
1174  1.281E-03   9.227E-05     -31.493804  
-5.696E-06     16.83
1175  1.290E-03   8.243E-05     -31.493803   
9.483E-07     17.10
1176  1.286E-03   6.151E-05     -31.493801   
1.926E-06     17.37
1177  1.287E-03   5.143E-05     -31.493799   
1.914E-06     17.65
1178  1.288E-03   6.262E-05     -31.493796   
2.398E-06     17.93
1179  1.288E-03   6.772E-05     -31.493795   
1.618E-06     18.20
1180  1.288E-03   6.314E-05     -31.493795   
5.038E-08     18.48
1181  1.489E-03   3.711E-04     -31.493763   
3.220E-05     18.75
1182  7.073E-03   1.771E-03     -31.493853  
-9.046E-05     18.76
 ODIIS| Insufficient progress; reset!
1183  3.490E-03   8.462E-04     -31.493749   
1.040E-04     16.27
1184  1.279E-03   2.005E-04     -31.493746   
3.078E-06     16.27
1185  4.048E-03   7.462E-04     -31.493602   
1.437E-04     16.55
1186  1.292E-03   1.804E-04     -31.493739  
-1.370E-04     16.82
1187  1.292E-03   1.041E-04     -31.493745  
-5.169E-06     17.09
1188  1.292E-03   1.001E-04     -31.493742   
2.093E-06     17.38
1189  1.294E-03   8.147E-05     -31.493741   
1.573E-06     17.65
1190  1.294E-03   6.664E-05     -31.493740   
1.304E-06     17.91
1191  1.295E-03   6.622E-05     -31.493736   
3.739E-06     18.21
1192  1.296E-03   7.825E-05     -31.493732   
3.941E-06     18.48
1193  1.944E-03   3.153E-04     -31.493726   
5.720E-06     18.76
1194  2.139E-03   3.497E-04     -31.493724   
2.069E-06     18.76
 ODIIS| Insufficient progress; reset!
1195  1.556E-03   2.677E-04     -31.493720   
4.346E-06     16.28
1196  1.301E-03   8.746E-05     -31.493713   
6.787E-06     16.26
1197  1.290E-03   2.091E-04     -31.493689   
2.408E-05     16.55
1198  1.305E-03   1.710E-04     -31.493701  
-1.249E-05     16.82
1199  1.302E-03   6.179E-05     -31.493704  
-2.800E-06     17.10
1200  1.303E-03   7.539E-05     -31.493704   
5.916E-07     17.38
1201  1.303E-03   6.967E-05     -31.493704   
1.775E-08     17.65
1202  1.303E-03   7.512E-05     -31.493702   
1.083E-06     17.93
1203  1.303E-03   5.733E-05     -31.493703  
-5.431E-07     18.20
1204  1.304E-03   1.593E-04     -31.493698   
4.565E-06     18.47
1205  1.303E-03   1.026E-04     -31.493702  
-3.609E-06     18.76
1206  1.303E-03   1.006E-04     -31.493696   
5.687E-06     18.76
 ODIIS| Insufficient progress; reset!
1207  1.305E-03   1.927E-04     -31.493692   
4.838E-06     16.27
1208  1.308E-03   1.876E-04     -31.493678   
1.386E-05     16.26
1209  1.309E-03   1.722E-04     -31.493662   
1.591E-05     16.54
1210  1.309E-03   1.150E-04     -31.493668  
-5.847E-06     16.82
1211  1.310E-03   8.973E-05     -31.493670  
-2.085E-06     17.11
1212  1.312E-03   5.897E-05     -31.493670  
-4.091E-07     17.36
1213  1.310E-03   6.021E-05     -31.493669   
1.441E-06     17.65
1214  1.311E-03   3.901E-05     -31.493668   
6.745E-07     17.94
1215  1.313E-03   6.222E-05     -31.493664   
4.296E-06     18.20
1216  1.313E-03   5.068E-05     -31.493661   
2.982E-06     18.48
1217  1.313E-03   9.600E-05     -31.493658   
2.620E-06     18.75
 ODIIS| Insufficient progress for K =        2; reset!
1218  1.314E-03   1.834E-04     -31.493655   
3.253E-06     18.76
1219  1.315E-03   1.138E-04     -31.493643   
1.187E-05     16.27
1220  1.321E-03   6.870E-05     -31.493635   
7.549E-06     16.55
1221  1.318E-03   7.857E-05     -31.493635   
8.759E-07     16.83
1222  1.318E-03   4.472E-05     -31.493633   
1.313E-06     17.10
1223  1.319E-03   3.715E-05     -31.493629   
4.172E-06     17.38
1224  1.320E-03   2.888E-05     -31.493627   
1.806E-06     17.65
1225  1.320E-03   2.811E-05     -31.493625   
2.432E-06     17.93
1226  1.318E-03   4.175E-05     -31.493621   
4.257E-06     18.19
1227  1.319E-03   1.820E-04     -31.493607   
1.395E-05     18.48
1228  1.318E-03   1.972E-04     -31.493616  
-9.335E-06     18.76
 ODIIS| Insufficient progress for K =       30; reset!
1229  1.319E-03   1.942E-04     -31.493603   
1.281E-05     18.76
1230  1.319E-03   1.954E-04     -31.493606  
-2.893E-06     16.26
1231  1.326E-03   5.228E-05     -31.493598   
7.789E-06     16.56
1232  1.323E-03   4.886E-05     -31.493598   
6.056E-07     16.82
1233  1.323E-03   3.087E-05     -31.493595   
2.587E-06     17.10
1234  1.324E-03   2.095E-05     -31.493592   
2.841E-06     17.38
1235  1.325E-03   1.948E-05     -31.493588   
4.049E-06     17.65
1236  1.317E-03   2.708E-05     -31.493596  
-7.417E-06     17.92
1237  1.320E-03   2.802E-05     -31.493596   
4.974E-08     18.20
1238  1.319E-03   2.897E-05     -31.493593   
2.390E-06     18.48
1239  1.321E-03   1.846E-04     -31.493595  
-2.278E-06     18.75
 ODIIS| Insufficient progress for K =       30; reset!
1240  1.320E-03   9.160E-05     -31.493591   
4.385E-06     18.75
1241  5.694E-03   1.206E-03     -31.493740  
-1.493E-04     16.28
1242  1.593E-03   2.998E-04     -31.493736   
4.333E-06     16.54
1243  1.335E-03   1.818E-04     -31.493760  
-2.410E-05     16.81
1244  1.336E-03   1.172E-04     -31.493762  
-2.103E-06     17.10
1245  1.337E-03   8.619E-05     -31.493761   
1.408E-06     17.37
1246  1.339E-03   8.865E-05     -31.493760   
5.082E-07     17.65
1247  1.337E-03   7.233E-05     -31.493757   
3.536E-06     17.92
1248  1.339E-03   3.421E-05     -31.493751   
5.322E-06     18.20
1249  1.340E-03   5.930E-05     -31.493749   
2.184E-06     18.48
1250  1.340E-03   5.060E-05     -31.493748   
1.251E-06     18.75
 ODIIS| Insufficient progress for K =       21; reset!
1251  1.340E-03   3.692E-05     -31.493743   
5.198E-06     18.75
1252  1.338E-03   2.741E-05     -31.493741   
1.999E-06     16.27
1253  1.343E-03   8.292E-05     -31.493733   
7.676E-06     16.55
1254  1.341E-03   2.459E-05     -31.493733   
5.650E-07     16.82
1255  1.342E-03   2.145E-05     -31.493730   
2.478E-06     17.10
1256  1.343E-03   1.840E-05     -31.493727   
3.525E-06     17.37
1257  1.345E-03   1.954E-05     -31.493721   
5.962E-06     17.65
1258  1.348E-03   2.150E-05     -31.493712   
8.887E-06     17.93
1259  1.351E-03   5.312E-05     -31.493705   
7.153E-06     18.21
1260  1.354E-03   4.978E-05     -31.493697   
7.857E-06     18.47
1261  1.346E-03   3.837E-05     -31.493695   
1.396E-06     18.75
1262  1.347E-03   3.462E-05     -31.493716  
-2.040E-05     18.76
 ODIIS| Insufficient progress; reset!
1263  1.347E-03   7.334E-05     -31.493720  
-4.317E-06     16.27
1264  1.345E-03   1.219E-04     -31.493708   
1.217E-05     16.28
1265  3.397E-03   3.831E-04     -31.493661   
4.651E-05     16.54
1266  1.349E-03   8.481E-05     -31.493701  
-3.922E-05     16.82
1267  1.351E-03   7.701E-05     -31.493699   
1.171E-06     17.09
1268  1.351E-03   4.744E-05     -31.493697   
2.168E-06     17.37
1269  1.352E-03   3.193E-05     -31.493695   
2.581E-06     17.65
1270  1.352E-03   3.093E-05     -31.493693   
1.747E-06     17.93
1271  1.352E-03   3.052E-05     -31.493693  
-1.094E-07     18.19
1272  1.352E-03   6.977E-05     -31.493693   
4.903E-08     18.48
1273  1.352E-03   5.607E-05     -31.493693  
-3.175E-07     18.75
1274  1.352E-03   8.471E-05     -31.493693   
3.100E-07     18.76
 ODIIS| Insufficient progress; reset!
1275  1.353E-03   1.798E-04     -31.493689   
4.411E-06     16.27
1276  1.355E-03   8.029E-05     -31.493681   
7.449E-06     16.27
1277  1.354E-03   1.357E-04     -31.493667   
1.357E-05     16.53
1278  1.357E-03   1.128E-04     -31.493671  
-3.298E-06     16.83
1279  1.358E-03   4.870E-05     -31.493671  
-6.074E-07     17.10
1280  1.358E-03   7.687E-05     -31.493669   
2.214E-06     17.38
1281  1.358E-03   6.868E-05     -31.493669  
-2.515E-07     17.65
1282  1.358E-03   5.033E-05     -31.493670  
-7.575E-07     17.92
1283  1.358E-03   5.774E-05     -31.493669   
9.177E-07     18.20
1284  1.358E-03   1.185E-04     -31.493669   
4.272E-07     18.48
1285  1.358E-03   2.883E-04     -31.493662   
7.062E-06     18.75
1286  1.365E-03   3.196E-04     -31.493663  
-1.711E-06     18.76
 ODIIS| Insufficient progress; reset!
1287  7.454E-03   1.485E-03     -31.493452   
2.110E-04     16.26
1288  1.360E-03   8.123E-05     -31.493653  
-2.003E-04     16.26
1289  1.370E-03   2.047E-04     -31.493638   
1.469E-05     16.54
1290  1.366E-03   8.379E-05     -31.493648  
-1.003E-05     16.82
1291  1.364E-03   9.611E-05     -31.493649  
-6.090E-07     17.10
1292  1.364E-03   7.658E-05     -31.493649  
-5.248E-07     17.37
1293  1.365E-03   7.425E-05     -31.493645   
4.370E-06     17.65
1294  1.367E-03   7.619E-05     -31.493642   
3.280E-06     17.92
1295  1.373E-03   1.307E-04     -31.493628   
1.352E-05     18.21
1296  1.358E-03   6.570E-05     -31.493650  
-2.160E-05     18.48
1297  1.361E-03   7.092E-05     -31.493645   
4.365E-06     18.76
1298  1.363E-03   1.861E-04     -31.493639   
6.368E-06     18.75
 ODIIS| Insufficient progress; reset!
1299  1.364E-03   1.733E-04     -31.493638   
1.075E-06     16.27
1300  1.365E-03   1.853E-04     -31.493626   
1.232E-05     16.27
1301  1.371E-03   2.219E-04     -31.493608   
1.795E-05     16.54
1302  1.366E-03   9.813E-05     -31.493616  
-8.549E-06     16.82
1303  1.368E-03   6.851E-05     -31.493615   
1.224E-06     17.09
1304  1.370E-03   4.402E-05     -31.493614   
5.346E-07     17.38
1305  1.370E-03   4.581E-05     -31.493613   
1.248E-06     17.65
1306  1.370E-03   5.941E-05     -31.493612   
1.197E-06     17.92
1307  1.370E-03   5.499E-05     -31.493611   
4.827E-07     18.21
1308  1.370E-03   3.815E-05     -31.493609   
2.222E-06     18.47
1309  1.371E-03   3.647E-05     -31.493606   
2.992E-06     18.76
1310  1.371E-03   3.802E-05     -31.493606   
1.689E-07     18.75
 ODIIS| Insufficient progress; reset!
1311  1.373E-03   3.192E-05     -31.493601   
5.350E-06     16.27
1312  1.372E-03   8.282E-05     -31.493594   
6.385E-06     16.27
1313  1.387E-03   2.103E-04     -31.493575   
1.894E-05     16.55
1314  1.375E-03   9.692E-05     -31.493584  
-8.987E-06     16.82
1315  1.377E-03   4.400E-05     -31.493586  
-1.146E-06     17.10
1316  1.377E-03   3.550E-05     -31.493584   
1.202E-06     17.38
1317  1.378E-03   2.769E-05     -31.493583   
1.291E-06     17.64
1318  1.378E-03   2.539E-05     -31.493582   
1.557E-06     17.93
1319  1.382E-03   3.104E-05     -31.493572   
9.768E-06     18.20
1320  1.384E-03   3.667E-05     -31.493568   
3.457E-06     18.48
1321  1.385E-03   6.021E-05     -31.493566   
2.048E-06     18.76
1322  1.386E-03   2.594E-04     -31.493565   
9.731E-07     18.75
 ODIIS| Insufficient progress; reset!
1323  1.380E-03   1.713E-04     -31.493573  
-7.251E-06     16.27
1324  1.382E-03   2.592E-05     -31.493565   
7.528E-06     16.27
1325  1.385E-03   6.427E-05     -31.493557   
8.451E-06     16.54
1326  1.385E-03   3.695E-05     -31.493555   
1.040E-06     16.83
1327  1.385E-03   3.364E-05     -31.493554   
1.804E-06     17.10
1328  1.385E-03   2.966E-05     -31.493554  
-1.080E-07     17.38
1329  1.385E-03   3.441E-05     -31.493551   
2.598E-06     17.66
1330  1.386E-03   3.121E-05     -31.493549   
2.000E-06     17.92
1331  1.386E-03   3.735E-05     -31.493549   
1.761E-07     18.19
1332  1.389E-03   2.901E-04     -31.493539   
1.007E-05     18.48
1333  1.385E-03   2.795E-04     -31.493554  
-1.494E-05     18.76
1334  1.389E-03   8.866E-05     -31.493543   
1.050E-05     18.76
 ODIIS| Insufficient progress; reset!
1335  1.389E-03   1.725E-04     -31.493543   
6.794E-07     16.27
1336  1.390E-03   9.493E-05     -31.493537   
5.643E-06     16.28
1337  1.390E-03   1.953E-04     -31.493512   
2.482E-05     16.54
1338  1.396E-03   1.463E-04     -31.493523  
-1.066E-05     16.83
1339  1.392E-03   1.067E-04     -31.493526  
-3.084E-06     17.10
1340  1.394E-03   3.900E-05     -31.493526  
-3.376E-07     17.37
1341  1.395E-03   2.718E-05     -31.493524   
2.427E-06     17.66
1342  1.395E-03   3.703E-05     -31.493520   
3.655E-06     17.93
1343  1.396E-03   2.395E-05     -31.493517   
2.993E-06     18.20
1344  1.396E-03   2.425E-05     -31.493516   
1.126E-06     18.48
1345  1.397E-03   2.742E-05     -31.493515   
6.898E-07     18.75
1346  1.399E-03   5.466E-05     -31.493501   
1.413E-05     18.76
 ODIIS| Insufficient progress; reset!
1347  1.396E-03   3.104E-04     -31.493475   
2.648E-05     16.26
1348  1.397E-03   8.567E-05     -31.493467   
8.253E-06     16.27
1349  1.401E-03   1.645E-04     -31.493448   
1.822E-05     16.54
1350  1.399E-03   1.249E-04     -31.493456  
-8.075E-06     16.83
1351  1.401E-03   4.887E-05     -31.493458  
-1.332E-06     17.09
1352  1.401E-03   3.030E-05     -31.493456   
2.264E-06     17.37
1353  1.402E-03   3.303E-05     -31.493451   
4.108E-06     17.65
1354  1.402E-03   2.854E-05     -31.493449   
1.958E-06     17.93
1355  1.403E-03   2.668E-05     -31.493447   
2.332E-06     18.21
1356  1.402E-03   1.303E-04     -31.493443   
4.286E-06     18.47
1357  1.400E-03   2.348E-04     -31.493407   
3.532E-05     18.76
1358  1.403E-03   2.441E-04     -31.493447  
-3.977E-05     18.75
 ODIIS| Insufficient progress; reset!
1359  1.403E-03   2.221E-04     -31.493440   
7.581E-06     16.27
1360  1.404E-03   1.033E-04     -31.493431   
8.986E-06     16.27
1361  1.409E-03   1.639E-04     -31.493405   
2.586E-05     16.55
1362  1.405E-03   1.587E-04     -31.493414  
-9.008E-06     16.81
1363  1.408E-03   5.719E-05     -31.493418  
-4.231E-06     17.09
1364  1.408E-03   4.542E-05     -31.493417   
1.402E-06     17.37
1365  1.408E-03   3.589E-05     -31.493415   
1.556E-06     17.65
1366  1.410E-03   2.834E-05     -31.493410   
5.597E-06     17.94
1367  1.410E-03   2.168E-05     -31.493409   
5.665E-07     18.21
1368  1.410E-03   2.470E-05     -31.493407   
2.408E-06     18.48
1369  1.411E-03   2.601E-05     -31.493403   
3.538E-06     18.75
1370  1.412E-03   5.138E-05     -31.493400   
3.125E-06     18.76
 ODIIS| Insufficient progress; reset!
1371  1.413E-03   1.680E-04     -31.493389   
1.075E-05     16.28
1372  1.415E-03   8.845E-05     -31.493380   
9.020E-06     16.26
1373  1.418E-03   1.819E-04     -31.493365   
1.483E-05     16.54
1374  1.418E-03   7.192E-05     -31.493371  
-5.672E-06     16.83
1375  1.418E-03   8.939E-05     -31.493368   
3.323E-06     17.10
1376  1.419E-03   3.537E-05     -31.493366   
1.777E-06     17.37
1377  1.419E-03   3.156E-05     -31.493364   
1.438E-06     17.66
1378  1.419E-03   3.026E-05     -31.493363   
1.268E-06     17.93
1379  1.420E-03   2.608E-05     -31.493361   
1.762E-06     18.19
1380  1.420E-03   2.393E-05     -31.493358   
3.510E-06     18.49
1381  1.419E-03   2.739E-05     -31.493360  
-1.837E-06     18.74
1382  1.420E-03   2.645E-05     -31.493357   
2.905E-06     18.76
 ODIIS| Insufficient progress; reset!
1383  1.422E-03   5.318E-05     -31.493355   
1.807E-06     16.26
1384  1.423E-03   8.874E-05     -31.493344   
1.080E-05     16.27
1385  1.427E-03   9.073E-05     -31.493333   
1.113E-05     16.55
1386  1.426E-03   9.194E-05     -31.493333  
-2.332E-07     16.82
1387  1.426E-03   5.728E-05     -31.493333   
7.188E-07     17.10
1388  1.427E-03   4.170E-05     -31.493332   
7.502E-07     17.43
1389  1.428E-03   4.980E-05     -31.493327   
5.193E-06     17.77
1390  1.429E-03   4.212E-05     -31.493323   
3.510E-06     18.06
1391  1.429E-03   3.240E-05     -31.493321   
1.801E-06     18.36
1392  1.431E-03   2.364E-05     -31.493317   
4.565E-06     18.60
1393  1.431E-03   5.618E-05     -31.493314   
2.528E-06     18.86
 ODIIS| Insufficient progress for K =        2; reset!
1394  1.430E-03   1.952E-04     -31.493306   
8.650E-06     18.85
1395  1.431E-03   1.562E-04     -31.493324  
-1.857E-05     16.33
1396  1.432E-03   5.405E-05     -31.493315   
8.801E-06     16.64
1397  1.432E-03   4.871E-05     -31.493315   
8.355E-07     16.91
1398  1.433E-03   2.630E-05     -31.493313   
1.964E-06     17.23
1399  1.434E-03   2.256E-05     -31.493309   
3.737E-06     17.53
1400  1.435E-03   2.171E-05     -31.493305   
3.973E-06     17.78
1401  1.439E-03   2.584E-05     -31.493294   
1.056E-05     18.02
1402  1.430E-03   1.978E-05     -31.493296  
-1.546E-06     18.32
1403  1.431E-03   3.466E-05     -31.493314  
-1.810E-05     18.61
1404  1.431E-03   2.281E-05     -31.493294   
1.943E-05     18.88
 ODIIS| Insufficient progress for K =       30; reset!
1405  1.430E-03   2.338E-05     -31.493286   
8.521E-06     18.89
1406  1.442E-03   7.486E-05     -31.493235   
5.085E-05     16.39
1407  1.452E-03   6.638E-05     -31.493226   
9.525E-06     16.67
1408  1.448E-03   3.923E-05     -31.493224   
1.221E-06     16.95
1409  1.448E-03   3.841E-05     -31.493221   
3.034E-06     17.22
1410  1.449E-03   2.329E-05     -31.493217   
4.622E-06     17.43
1411  1.450E-03   2.051E-05     -31.493213   
3.467E-06     17.76
1412  1.451E-03   2.437E-05     -31.493209   
4.303E-06     18.08
1413  1.452E-03   2.026E-05     -31.493203   
5.578E-06     18.33
1414  1.453E-03   3.001E-05     -31.493206  
-3.111E-06     18.63
1415  1.452E-03   3.898E-05     -31.493195   
1.175E-05     18.90
 ODIIS| Insufficient progress for K =       29; reset!
1416  1.452E-03   7.586E-05     -31.493177   
1.815E-05     18.90
1417  1.454E-03   3.044E-05     -31.493201  
-2.453E-05     16.40
1418  1.455E-03   4.867E-05     -31.493192   
8.782E-06     16.67
1419  1.456E-03   3.025E-05     -31.493190   
2.078E-06     16.97
1420  1.458E-03   2.110E-05     -31.493186   
3.827E-06     17.23
1421  1.459E-03   1.986E-05     -31.493182   
4.711E-06     17.51
1422  1.459E-03   1.963E-05     -31.493178   
3.835E-06     17.78
1423  1.459E-03   2.176E-05     -31.493174   
4.291E-06     18.07
1424  1.459E-03   5.193E-05     -31.493199  
-2.515E-05     18.30
1425  1.459E-03   4.353E-05     -31.493184   
1.494E-05     18.57
1426  1.458E-03   2.745E-05     -31.493175   
9.190E-06     18.91
1427  1.460E-03   3.166E-05     -31.493194  
-1.949E-05     18.87
 ODIIS| Insufficient progress; reset!
1428  1.457E-03   9.618E-05     -31.493169   
2.466E-05     16.41
1429  1.468E-03   1.275E-04     -31.493157   
1.247E-05     16.37
1430  3.578E-03   5.699E-04     -31.493069   
8.839E-05     16.64
1431  1.464E-03   9.134E-05     -31.493147  
-7.837E-05     16.96
[...]




		
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