[CPMD-list] free isolated atom energiesB

Eduardo Ariel Menendez P emenendez at macul.ciencias.uchile.cl
Fri Sep 17 01:14:47 CEST 2004


Hello everybody:

During last days I have been involved in generation and testing of
pseudopotentials for Cd and Te.  After having performed the tests
available in the pseudopp generation package (Giannozzi's) and convert the
pseudopotentials to CPMD format, I find that the energies of the isolated
atoms do not coincide precisely. The greatest difference betwwen CPMD and
the atomic
package is for the Te 5p level, where I found a difference of nearly
0.7eV, while 0.01 difference for Te 5s.  I have tried increasing the
cutoff and the lattice constant without improvement.
Hence, I decided to
use a database pseupotencial with the most common element on Earth: O.

Even so I have two problems

1) Using a supplied MT pseudopotential (O_MT_LDA.psp)
I have found .
EIGENVALUES(EV) AND OCCUPATION:
 1    -23.9467297NC   2.000        2     -8.7260317NC   2.000
 3     -8.7260316NC   2.000
 CHEMICAL POTENTIAL =                            -8.7260316211 EV

The energies are not precise, compared wih available references:

http://physics.nist.gov/PhysRefData/DFTdata/Tables/08O.html
2s     -0.871362 Ha= -23.70104 eV
2p     -0.338381 Ha = -9.20 eV

And the output of the atomic pp  generation package og Giannozzi
n l     nl            e(Ry)      (eV)
1 0     1S( 2.00)   -37.5178   -510.4594
2 0     2S( 2.00)    -1.7424    -23.7069
2 1     2P( 4.00)    -0.6766     -9.2055

E(2P)-E(2S)=14.50eV

CPMD: E(2P)-E(2S)=15.22eV.


Morevoer, if I calculate Kohn-Sham empty state energies I find

 EIGENVALUES(EV) AND OCCUPATION:
 1    -23.9412023     2.000        2    -10.3153247     2.000
 3     -8.7206696     1.000        4     -8.7206695     1.000
 5     -0.5820744     0.000
CHEMICAL POTENTIAL =                            -8.7206708302 EV

I would expect that the energies of the states 2,3 and 4 be equal, corresponding to the
three 2p levels. However, the state 2 has a differente.  It is interesting that the
occupation factors of 3 and 4 are 1, even when I am using LDA and not LSD. I guess  it may be
associated to the quasi-degeneracy.
Here is the input file of the last calculation

&CPMD
  RESTART DENSITY
  KOHN-SHAM ENERGIES
   2
  MAXSTEP
  150
  CENTER MOLECULE ON
&END

&DFT
  NEWCODE
  FUNCTIONAL LDA
  LDA CORRELATION PZ
  SLATER
    0.666667
  GC-CUTOFF
  0.1E-07
&END

&SYSTEM
  SYMMETRY
  0
  ANGSTROM
  CELL
    8.0  1.0  1.0  0  0  0
  CUTOFF SPHERICAL
    95.0
&END

&ATOMS
*O_MT_LDA.psp KLEINMAN-BYLANDER
   LMAX=D LOC=D     #Also tried with LOC=P and LOC=S
   1
    0.000000    0.000000    0.000000
&END




2) SECOND PROBLEM
The second test I did was using ultrasoft pp.
For example,
performing optimization of the wavefunction  for one O in a box of 8 Angstroms, and then calculating the Khon-Sham energies I found striking diferences:

With this entry
&CPMD
  RESTART DENSITY
  KOHN-SHAM ENERGIES
     0
output:
 EIGENVALUES(EV) AND OCCUPATION:
 1    -11.2781946     2.000        2      0.7058206     2.000
 3      0.7065389NC   2.000
 CHEMICAL POTENTIAL =                             0.7065371502 EV
*********************************
With the same RESTART file and this  input
&CPMD
 RESTART DENSITY
 KOHN-SHAM ENERGIES
   2
y get this outpput:
EIGENVALUES(EV) AND OCCUPATION:
 1    -11.2781946     2.000        2     -0.3815193     2.000
 3     -0.2300328     2.000        4      0.7065208     0.000
 5      0.7065390     0.000
 CHEMICAL POTENTIAL =                            -0.2300326449 EV

First problem: The energies do not seem to be correct. Now the "P energy is terribly wrong

http://physics.nist.gov/PhysRefData/DFTdata/Tables/08O.html
2s     -0.871362 Ha= -23.70104 eV
2p     -0.338381 Ha = -9.20 eV

Also, the states 2,3,and 4 have all diferent energies.


Follow full input and output  files with the USPP.

1) Optimization
&CPMD
  INITIALIZE WAVEFUNCTION RANDOM
  OPTIMIZE WAVEFUNCTION
  MAXSTEP
  150
  CENTER MOLECULE ON
&END


&DFT
  NEWCODE
  FUNCTIONAL LDA
  LDA CORRELATION PZ
  SLATER
    0.666667
  GC-CUTOFF
  0.1E-07
&END

&SYSTEM
  SYMMETRY
  0
  ANGSTROM
  CELL
    8.0  1.0  1.0  0  0  0
  CUTOFF SPHERICAL
    55.0
&END

&ATOMS
*O_VDB_LDA.psp FORMATTED
   LMAX=P LOC=P
   1
    0.000000    0.000000    0.000000
&END

2) KS orbitals. Only occ states

&CPMD
  RESTART DENSITY
  KOHN-SHAM ENERGIES
   0
  MAXSTEP
  150
  CENTER MOLECULE ON
&END


&DFT
  NEWCODE
  FUNCTIONAL LDA
  LDA CORRELATION PZ
  SLATER
    0.666667
  GC-CUTOFF
  0.1E-07
&END

&SYSTEM
  SYMMETRY
  0
  ANGSTROM
  CELL
    8.0  1.0  1.0  0  0  0
  CUTOFF SPHERICAL
    55.0
&END

&ATOMS
*O_VDB_LDA.psp FORMATTED
   LMAX=D LOC=D
   1
    0.000000    0.000000    0.000000
&END
 PROGRAM CPMD STARTED AT: Fri Sep 17 00:46:21 2004



               ******  ******    ****  ****  ******
              *******  *******   **********  *******
             ***       **   ***  ** **** **  **   ***
             **        **   ***  **  **  **  **    **
             **        *******   **      **  **    **
             ***       ******    **      **  **   ***
              *******  **        **      **  *******
               ******  **        **      **  ******

                          VERSION 3.9.1

                            COPYRIGHT
                      IBM RESEARCH DIVISION
                MPI FESTKOERPERFORSCHUNG STUTTGART

                       The CPMD consortium
                    WWW:   http://www.cpmd.org
                 Mailinglist:   cpmd-list at cpmd.org
                     E-mail:   cpmd at cpmd.org


                  ***  Aug 13 2004 -- 13:52:08  ***

 THE INPUT FILE IS:                                         o.inp
 THIS JOB RUNS ON:
 THE CURRENT DIRECTORY IS:
                                            /home/eariel/mycpmd/O
 THE TEMPORARY DIRECTORY IS:
                                            /home/eariel/mycpmd/O
 THE PROCESS ID IS:                                          2530
 THE JOB WAS SUBMITTED BY:                                 eariel


 SINGLE POINT DENSITY OPTIMIZATION


 EXACT DIAGONALIZATION OF KOHN-SHAM MATRIX

 PATH TO THE RESTART FILES:                                    ./
 RESTART WITH OLD DENSITY
 GRAM-SCHMIDT ORTHOGONALIZATION
 MAXIMUM NUMBER OF STEPS:                                 1 STEPS
 MAXIMUM NUMBER OF ITERATIONS FOR SC:                     1 STEPS
 PRINT INTERMEDIATE RESULTS EVERY                     10001 STEPS
 STORE INTERMEDIATE RESULTS EVERY                     10001 STEPS
 STORE ELECTRONIC DENSITY IN RESTART FILE
 NUMBER OF DISTINCT RESTART FILES:                              1
 TEMPERATURE IS CALCULATED ASSUMING EXTENDED BULK BEHAVIOR
 TIME STEP FOR ELECTRONS:                                  5.0000
 TIME STEP FOR IONS:                                       5.0000
 CONVERGENCE CRITERIA FOR WAVEFUNCTION OPTIMIZATION:   1.0000E-03
 LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
    MAX. FRIESNER ITERATIONS                                  200
    MAX. KRYLOV SUBSPACE                                        6
    MAX. KRYLOV BLOCK SIZE       FIXED LATER (WAITING FOR NSTATE)
    MAX. BETA^2                                        1.0000E-08
 ANDERSON MIXING PARAMETER:                            2.0000E-01
 BROYDEN MIXING PARAMETER [BROYMIX]                    1.5000E-01
 BROYDEN CUTOFF [ECUTBROY]            EQUAL TO THE DENSITY CUTOFF
 BROYDEN MIXING STARTS [NFRBROY] AFTER                    0 STEPS
 BROYDEN MIXING RESET [IBRESET] AFTER                     8 STEPS
 BROYDEN MIXING W02                                    1.0000E-02
 ALEXANDER MIXING:                                         0.9000
 SPLINE INTERPOLATION IN G-SPACE FOR PSEUDOPOTENTIAL FUNCTIONS
    NUMBER OF SPLINE POINTS:                                 5000

 EXCHANGE CORRELATION FUNCTIONALS
    LDA EXCHANGE:                        SLATER (ALPHA = 0.66667)
    LDA CORRELATION:                              PERDEW & ZUNGER
       [J.P. PERDEW AND A ZUNGER, PRB 23 5048 (1981)]

 ***     DETSP| THE NEW SIZE OF THE PROGRAM IS    1940/  22060 kBYTES ***

 >>>>>>>> CENTER OF MASS HAS BEEN MOVED TO CENTER OF BOX <<<<<<<<


 ***************************** ATOMS ****************************
   NR   TYPE        X(bohr)        Y(bohr)        Z(bohr)     MBL
    1      O       7.558904       7.558904       7.558904       3
 ****************************************************************

 NUMBER OF STATES:                                              3
 NUMBER OF ELECTRONS:                                     6.00000
 CHARGE:                                                  0.00000
 ELECTRON TEMPERATURE(KELVIN):                            0.00000
 OCCUPATION
  2.0  2.0  2.0

 LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
    MAX. KRYLOV BLOCK SIZE                                      3

   ============================================================
   |  pseudopotential report: version  7.3.4 date  6-12-2003  |
   ------------------------------------------------------------
   |  oxygen                    ceperley-alder exchange-corr  |
   |  z =   8.00  zv =   6.00  exfact =   0.00000             |
   |                            etot  = -31.51046             |
   |  index    orbital      occupation    energy              |
   |    1        200           2.00       -1.74               |
   |    2        210           4.00       -0.68               |
   |  keyps = 3     ifpcor = 0                                |
   |  rinner =      0.80     for L=    1                      |
   |  rinner =      0.80     for L=    2                      |
   |  rinner =      0.80     for L=    3                      |
   |    new generation scheme:                                |
   |    nbeta =  4     kkbeta =  507     rcloc =    1.0000    |
   |    ibeta     l     epsilon   rcut iptype                 |
   |       1      0      -1.74   1.10      2                  |
   |       2      0      -0.20   1.10      2                  |
   |       3      1      -0.80   1.10      2                  |
   |       4      1       0.20   1.10      2                  |
   |  npf    = 8  ptryc =  10.000                             |
   |  lloc   = 2  eloc   =   0.000                            |
   |  ifqopt = 2  nqf    = 8  qtryc =  10.000                 |
   |  all electron calculation used schroedinger equation     |
   |         ************logarithmic mesh************         |
   ============================================================

 ****************************************************************
 *   ATOM       MASS   RAGGIO NLCC              PSEUDOPOTENTIAL *
 *     O     15.9994   1.2000   NO              VANDERBILT      *
 ****************************************************************


 OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
 NUMBER OF CPUS PER TASK                                        1
 OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN

 ***     RGGEN| THE NEW SIZE OF THE PROGRAM IS    8656/  36592 kBYTES ***

 ************************** SUPERCELL ***************************
 THIS IS AN ISOLATED SYSTEM CALCULATION
 POISSON EQUATION SOLVER  :                               HOCKNEY
 COULOMB SMOOTHING RADIUS :                                 1.080
 SYMMETRY:                                           SIMPLE CUBIC
 LATTICE CONSTANT(a.u.):                                 15.11781
 CELL DIMENSION:  15.1178  1.0000  1.0000  0.0000  0.0000  0.0000
 VOLUME(OMEGA IN BOHR^3):                              3455.14651
 LATTICE VECTOR A1(BOHR):           15.1178     0.0000     0.0000
 LATTICE VECTOR A2(BOHR):            0.0000    15.1178     0.0000
 LATTICE VECTOR A3(BOHR):            0.0000     0.0000    15.1178
 RECIP. LAT. VEC. B1(2Pi/BOHR):      0.0661     0.0000     0.0000
 RECIP. LAT. VEC. B2(2Pi/BOHR):      0.0000     0.0661     0.0000
 RECIP. LAT. VEC. B3(2Pi/BOHR):      0.0000     0.0000     0.0661
 REAL SPACE MESH:                    72           72           72
 WAVEFUNCTION CUTOFF(RYDBERG):                           55.00000
 DENSITY CUTOFF(RYDBERG):          (DUAL= 4.00)         220.00000
 NUMBER OF PLANE WAVES FOR WAVEFUNCTION CUTOFF:             11924
 NUMBER OF PLANE WAVES FOR DENSITY CUTOFF:                  95160
 NUMBER OF PLANE WAVES FOR BROYDEN MIXING:                  95160
 ****************************************************************

 ***  RINFORCE| THE NEW SIZE OF THE PROGRAM IS   19336/  48876 kBYTES ***
 ***    FFTPRP| THE NEW SIZE OF THE PROGRAM IS   30400/  50196 kBYTES ***
 ***   CLUSTER| THE NEW SIZE OF THE PROGRAM IS   34304/  53980 kBYTES ***

 GENERATE ATOMIC BASIS SET
      O        SLATER ORBITALS
        2S        ALPHA=   2.2458      OCCUPATION= 2.00
        2P        ALPHA=   2.2266      OCCUPATION= 4.00


 INITIALIZATION TIME:                               13.06 SECONDS

 ***    WFOPTS| THE NEW SIZE OF THE PROGRAM IS   34520/  60124 kBYTES ***
 RV30| WARNING! NO DENSITY INFORMATION

 RESTART INFORMATION READ ON FILE                       ./RESTART
 ***     PHFAC| THE NEW SIZE OF THE PROGRAM IS   34780/  89428 kBYTES ***
 ***    ATOMWF| THE NEW SIZE OF THE PROGRAM IS   34984/  90924 kBYTES ***
  ATRHO| CHARGE(R-SPACE):    6.000000      (G-SPACE):    6.000000

 ****************************************************************
 *                      ATOMIC COORDINATES                      *
 ****************************************************************
       1       O           7.558904       7.558904       7.558904
 ****************************************************************

  !! WARNING FROM DETDOF: WHY IS GLIB LESS THAN UNITY !!
  !! WARNING FROM DETDOF: NOW IT IS SET EQUAL TO UNITY !!

 DEGREES OF FREEDOM FOR SYSTEM:                                 1

 CPU TIME FOR WAVEFUNCTION INITIALIZATION:           3.44 SECONDS
 ***    RWFOPT| THE NEW SIZE OF THE PROGRAM IS   64920/  89564 kBYTES ***
  EWALD| SUM IN REAL SPACE OVER                     1* 1* 1 CELLS

 <<<<<<<<<<<<<<<<<<< LANCZOS DIAGONALIZATION <<<<<<<<<<<<<<<<<<<<
 >> TIME FOR INITIAL SUBSPACE DIAGONALIZATION:               0.32
 >> CYCLE     NCONV        B2MAX        B2MIN     #HPSI      TIME
        1         0    1.561E-01    4.184E-02      6.00      1.58
        2         0    1.562E-01    8.824E-03      5.00      1.57
        3         0    6.681E-02    2.637E-03      5.00      1.58
        4         0    5.009E-02    8.258E-04      5.00      1.57
        5         0    2.734E-02    2.903E-04      5.00      1.58
        6         0    2.382E-02    1.033E-04      5.00      1.57
        7         0    1.440E-02    3.971E-05      5.00      1.58
        8         0    1.340E-02    1.528E-05      5.00      1.57
        9         0    8.514E-03    4.825E-06      5.00      1.58
       10         0    8.230E-03    2.850E-06      5.00      1.57
       11         0    5.415E-03    1.034E-06      5.00      1.57
       12         0    5.390E-03    6.196E-07      5.00      1.57
       13         0    3.644E-03    2.334E-07      5.00      1.58
       14         0    3.711E-03    1.416E-07      5.00      1.57
       15         0    2.561E-03    5.407E-08      5.00      1.57
       16         0    2.654E-03    3.308E-08      5.00      1.58
       17         0    1.859E-03    1.274E-08      5.00      1.57
       18         1    1.950E-03    9.159E-09      4.00      1.13
       19         1    1.380E-03    9.159E-09      3.33      0.82
       20         1    1.459E-03    9.159E-09      3.33      0.83
       21         1    1.039E-03    9.159E-09      3.33      0.83
       22         1    1.104E-03    9.159E-09      3.33      0.82
       23         1    7.904E-04    9.159E-09      3.33      0.83
       24         1    8.425E-04    9.159E-09      3.33      0.82
       25         1    6.047E-04    9.159E-09      3.33      0.83
       26         1    6.459E-04    9.159E-09      3.33      0.83
       27         1    4.644E-04    9.159E-09      3.33      0.82
       28         1    4.966E-04    9.159E-09      3.33      0.83
       29         1    3.574E-04    9.159E-09      3.33      0.83
       30         1    3.824E-04    9.159E-09      3.33      0.82
       31         1    2.754E-04    9.159E-09      3.33      0.83
       32         1    2.948E-04    9.159E-09      3.33      0.83
       33         1    2.124E-04    9.159E-09      3.33      0.82
       34         1    2.274E-04    9.159E-09      3.33      0.83
       35         1    1.639E-04    9.159E-09      3.33      0.82
       36         1    1.755E-04    9.159E-09      3.33      0.83
       37         1    1.265E-04    9.159E-09      3.33      0.83
       38         1    1.354E-04    9.159E-09      3.33      0.82
       39         1    9.763E-05    9.159E-09      3.33      0.83
       40         1    1.045E-04    9.159E-09      3.33      0.83
       41         1    7.535E-05    9.159E-09      3.33      0.82
       42         1    8.067E-05    9.159E-09      3.33      0.83
       43         1    5.816E-05    9.159E-09      3.33      0.82
       44         1    6.227E-05    9.159E-09      3.33      0.83
       45         1    4.489E-05    9.159E-09      3.33      0.83
       46         1    4.806E-05    9.159E-09      3.33      0.82
       47         1    3.465E-05    9.159E-09      3.33      0.83
       48         1    3.709E-05    9.159E-09      3.33      0.82
       49         1    2.675E-05    9.159E-09      3.33      0.82
       50         1    2.863E-05    9.159E-09      3.33      0.83
       51         1    2.064E-05    9.159E-09      3.33      0.82
       52         1    2.210E-05    9.159E-09      3.33      0.83
       53         1    1.593E-05    9.159E-09      3.33      0.83
       54         1    1.706E-05    9.159E-09      3.33      0.82
       55         1    1.230E-05    9.159E-09      3.33      0.83
       56         1    1.317E-05    9.159E-09      3.33      0.82
       57         1    9.494E-06    9.159E-09      3.33      0.83
       58         1    1.016E-05    9.159E-09      3.33      0.83
       59         1    7.329E-06    9.159E-09      3.33      0.82
       60         1    7.844E-06    9.159E-09      3.33      0.82
       61         1    5.657E-06    9.159E-09      3.33      0.83
       62         1    6.055E-06    9.159E-09      3.33      0.82
       63         1    4.367E-06    9.159E-09      3.33      0.83
       64         1    4.674E-06    9.159E-09      3.33      0.83
       65         1    3.371E-06    9.159E-09      3.33      0.82
       66         1    3.609E-06    9.159E-09      3.33      0.82
       67         1    2.603E-06    9.159E-09      3.33      0.82
       68         1    2.786E-06    9.159E-09      3.33      0.83
       69         1    2.010E-06    9.159E-09      3.33      0.83
       70         1    2.151E-06    9.159E-09      3.33      0.82
       71         1    1.552E-06    9.159E-09      3.33      0.83
       72         1    1.661E-06    9.159E-09      3.33      0.82
       73         1    1.198E-06    9.159E-09      3.33      0.83
       74         1    1.283E-06    9.159E-09      3.33      0.83
       75         1    9.256E-07    9.159E-09      3.33      0.83
       76         1    9.910E-07    9.159E-09      3.33      0.82
       77         1    7.151E-07    9.159E-09      3.33      0.83
       78         1    7.657E-07    9.159E-09      3.33      0.82
       79         1    5.526E-07    9.159E-09      3.33      0.83
       80         1    5.919E-07    9.159E-09      3.33      0.82
       81         1    4.273E-07    9.159E-09      3.33      0.83
       82         1    4.578E-07    9.159E-09      3.33      0.82
       83         1    3.307E-07    9.159E-09      3.33      0.82
       84         1    3.544E-07    9.159E-09      3.33      0.83
       85         1    2.561E-07    9.159E-09      3.33      0.82
       86         1    2.748E-07    9.159E-09      3.33      0.83
       87         1    1.987E-07    9.159E-09      3.33      0.83
       88         1    2.134E-07    9.159E-09      3.33      0.82
       89         1    1.545E-07    9.159E-09      3.33      0.83
       90         1    1.662E-07    9.159E-09      3.33      0.83
       91         1    1.205E-07    9.159E-09      3.33      0.82
       92         1    1.299E-07    9.159E-09      3.33      0.83
       93         1    9.449E-08    9.159E-09      3.33      0.82
       94         1    1.021E-07    9.159E-09      3.33      0.83
       95         1    7.456E-08    9.159E-09      3.33      0.83
       96         1    8.096E-08    9.159E-09      3.33      0.82
       97         1    5.940E-08    9.159E-09      3.33      0.83
       98         1    6.490E-08    9.159E-09      3.33      0.83
       99         1    4.796E-08    9.159E-09      3.33      0.82
      100         1    5.283E-08    9.159E-09      3.33      0.83
      101         1    3.942E-08    9.159E-09      3.33      0.82
      102         1    4.391E-08    9.159E-09      3.33      0.83
      103         1    3.317E-08    9.159E-09      3.33      0.83
      104         1    3.747E-08    9.159E-09      3.33      0.82
      105         1    2.874E-08    9.159E-09      3.33      0.83
      106         1    3.302E-08    9.159E-09      3.33      0.83
      107         2    2.578E-08    9.159E-09      2.33      0.78
      108         2    3.019E-08    9.159E-09      1.67      0.75
      109         2    2.403E-08    9.159E-09      1.67      0.75
      110         2    2.871E-08    9.159E-09      1.67      0.75
      111         2    2.330E-08    9.159E-09      1.67      0.75
      112         2    2.838E-08    9.159E-09      1.67      0.76
      113         2    2.345E-08    9.159E-09      1.67      0.75
      114         2    2.906E-08    9.159E-09      1.67      0.75
      115         2    2.439E-08    9.159E-09      1.67      0.75
      116         2    3.066E-08    9.159E-09      1.67      0.75
      117         2    2.606E-08    9.159E-09      1.67      0.75
      118         2    3.313E-08    9.159E-09      1.67      0.75
      119         2    2.843E-08    9.159E-09      1.67      0.75
      120         2    3.644E-08    9.159E-09      1.67      0.76
      121         2    3.149E-08    9.159E-09      1.67      0.75
      122         2    4.062E-08    9.159E-09      1.67      0.75
      123         2    3.527E-08    9.159E-09      1.67      0.75
      124         2    4.569E-08    9.159E-09      1.67      0.75
      125         2    3.981E-08    9.159E-09      1.67      0.75
      126         2    5.172E-08    9.159E-09      1.67      0.75
      127         2    4.518E-08    9.159E-09      1.67      0.75
      128         2    5.880E-08    9.159E-09      1.67      0.76
      129         2    5.145E-08    9.159E-09      1.67      0.75
      130         2    6.705E-08    9.159E-09      1.67      0.75
      131         2    5.873E-08    9.159E-09      1.67      0.75
      132         2    7.660E-08    9.159E-09      1.67      0.75
      133         2    6.715E-08    9.159E-09      1.67      0.75
      134         2    8.763E-08    9.159E-09      1.67      0.75
      135         2    7.685E-08    9.159E-09      1.67      0.75
      136         2    1.003E-07    9.159E-09      1.67      0.74
      137         2    8.803E-08    9.159E-09      1.67      0.76
      138         2    1.150E-07    9.159E-09      1.67      0.75
      139         2    1.009E-07    9.159E-09      1.67      0.75
      140         2    1.317E-07    9.159E-09      1.67      0.75
      141         2    1.156E-07    9.159E-09      1.67      0.75
      142         2    1.510E-07    9.159E-09      1.67      0.75
      143         2    1.326E-07    9.159E-09      1.67      0.75
      144         2    1.732E-07    9.159E-09      1.67      0.75
      145         2    1.520E-07    9.159E-09      1.67      0.74
      146         2    1.986E-07    9.159E-09      1.67      0.75
      147         2    1.743E-07    9.159E-09      1.67      0.75
      148         2    2.277E-07    9.159E-09      1.67      0.75
      149         2    1.999E-07    9.159E-09      1.67      0.75
      150         2    2.611E-07    9.159E-09      1.67      0.75
      151         2    2.293E-07    9.159E-09      1.67      0.75
      152         2    2.995E-07    9.159E-09      1.67      0.75
      153         2    2.629E-07    9.159E-09      1.67      0.75
      154         2    3.434E-07    9.159E-09      1.67      0.75
      155         2    3.015E-07    9.159E-09      1.67      0.75
      156         2    3.939E-07    9.159E-09      1.67      0.75
      157         2    3.458E-07    9.159E-09      1.67      0.75
      158         2    4.517E-07    9.159E-09      1.67      0.75
      159         2    3.966E-07    9.159E-09      1.67      0.75
      160         2    5.181E-07    9.159E-09      1.67      0.75
      161         2    4.549E-07    9.159E-09      1.67      0.75
      162         2    5.941E-07    9.159E-09      1.67      0.75
      163         2    5.217E-07    9.159E-09      1.67      0.75
      164         2    6.814E-07    9.159E-09      1.67      0.75
      165         2    5.983E-07    9.159E-09      1.67      0.75
      166         2    7.815E-07    9.159E-09      1.67      0.75
      167         2    6.862E-07    9.159E-09      1.67      0.75
      168         2    8.963E-07    9.159E-09      1.67      0.75
      169         2    7.870E-07    9.159E-09      1.67      0.75
      170         2    1.028E-06    9.159E-09      1.67      0.75
      171         2    9.026E-07    9.159E-09      1.67      0.75
      172         2    1.179E-06    9.159E-09      1.67      0.75
      173         2    1.035E-06    9.159E-09      1.67      0.75
      174         2    1.352E-06    9.159E-09      1.67      0.76
      175         2    1.187E-06    9.159E-09      1.67      0.75
      176         2    1.551E-06    9.159E-09      1.67      0.75
      177         2    1.362E-06    9.159E-09      1.67      0.75
      178         2    1.778E-06    9.159E-09      1.67      0.75
      179         2    1.562E-06    9.159E-09      1.67      0.75
      180         2    2.039E-06    9.159E-09      1.67      0.75
      181         2    1.791E-06    9.159E-09      1.67      0.75
      182         2    2.339E-06    9.159E-09      1.67      0.76
      183         2    2.054E-06    9.159E-09      1.67      0.74
      184         2    2.682E-06    9.159E-09      1.67      0.74
      185         2    2.356E-06    9.159E-09      1.67      0.75
      186         2    3.076E-06    9.159E-09      1.67      0.75
      187         2    2.701E-06    9.159E-09      1.67      0.75
      188         2    3.528E-06    9.159E-09      1.67      0.74
      189         2    3.098E-06    9.159E-09      1.67      0.75
      190         2    4.046E-06    9.159E-09      1.67      0.75
      191         2    3.553E-06    9.159E-09      1.67      0.75
      192         2    4.639E-06    9.159E-09      1.67      0.75
      193         2    4.074E-06    9.159E-09      1.67      0.75
      194         2    5.320E-06    9.159E-09      1.67      0.75
      195         2    4.672E-06    9.159E-09      1.67      0.74
      196         2    6.101E-06    9.159E-09      1.67      0.75
      197         2    5.358E-06    9.159E-09      1.67      0.75
      198         2    6.996E-06    9.159E-09      1.67      0.76
      199         2    6.144E-06    9.159E-09      1.67      0.75
      200         2    8.023E-06    9.159E-09      1.67      0.75

 EIGENVALUES(EV) AND OCCUPATION:
     1    -11.2781946     2.000        2      0.7058206     2.000
     3      0.7065389NC   2.000
 CHEMICAL POTENTIAL =                             0.7065371502 EV

 TOTAL INTEGRATED ELECTRONIC DENSITY
    IN G-SPACE =                                         6.049092
    IN R-SPACE =                                         6.049092


 VANDERBILT AUGMENTATION CHARGES (MEAN VALUE PER ATOM)
 ATOM TYPE    NR. OF ATOMS        CHARGE
       O           1               0.049

 (B+E2+X-V)             TOTAL ENERGY =          -16.81175790 A.U.
 (B)                     BAND ENERGY =           -0.72510914 A.U.
 (E2=I-H-S+R)   ELECTROSTATIC ENERGY =          -17.33584728 A.U.
 (S)                           ESELF =           11.96826841 A.U.
 (R)                             ESR =            0.00000000 A.U.
 (X)     EXCHANGE-CORRELATION ENERGY =           -3.99099801 A.U.
 (V)     EXCHANGE-CORRELATION POTEN. =           -5.24019667 A.U.

 ==------------------------------------------------------------==
 ==     NFI=      1      ETOT=    -16.811758   TCPU=    173.96 ==
 == DRHOMAX= 1.407E-01  DETOT=     0.000E+00    THL= 0.000E+00 ==
 ==------------------------------------------------------------==

 RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.1
 ***    RWFOPT| THE NEW SIZE OF THE PROGRAM IS   75640/  95644 kBYTES ***

 ****************************************************************
 *                                                              *
 *                        FINAL RESULTS                         *
 *                                                              *
 ****************************************************************

 ****************************************************************
 *                      ATOMIC COORDINATES                      *
 ****************************************************************
       1       O           7.558904       7.558904       7.558904
 ****************************************************************


 EIGENVALUES(EV) AND OCCUPATION:
     1    -11.2781946     2.000        2      0.7058206     2.000
     3      0.7065389NC   2.000
 CHEMICAL POTENTIAL =                             0.7065371502 EV

 ****************************************************************


 ELECTRONIC GRADIENT:
    MAX. COMPONENT =    1.40719E-01         NORM =    6.04874E+00

 TOTAL INTEGRATED ELECTRONIC DENSITY
    IN G-SPACE =                                         6.049092
    IN R-SPACE =                                         6.049092


 VANDERBILT AUGMENTATION CHARGES (MEAN VALUE PER ATOM)
 ATOM TYPE    NR. OF ATOMS        CHARGE
       O           1               0.049

 (B+E2+X-V)             TOTAL ENERGY =          -16.81175790 A.U.
 (B)                     BAND ENERGY =           -0.72510914 A.U.
 (E2=I-H-S+R)   ELECTROSTATIC ENERGY =          -17.33584728 A.U.
 (S)                           ESELF =           11.96826841 A.U.
 (R)                             ESR =            0.00000000 A.U.
 (X)     EXCHANGE-CORRELATION ENERGY =           -3.99099801 A.U.
 (V)     EXCHANGE-CORRELATION POTEN. =           -5.24019667 A.U.

 ****************************************************************


 ================================================================
                      BIG MEMORY ALLOCATIONS
 SCR              1576657                PSI              1556068
 QRL               903600                YLMB              856440
 YF                778034                XF                778034
 SCR               613400                PME               429264
 RHOE              389017                HGPOT             389017
 ----------------------------------------------------------------
 [PEAK NUMBER   92]      PEAK MEMORY      9571930 =   76.6 MBytes
 ================================================================


 ****************************************************************
 *                                                              *
 *                            TIMING                            *
 *                                                              *
 ****************************************************************
 SUBROUTINE            CALLS         CPU TIME        ELAPSED TIME
    FFT-G/S             4372            39.07               38.96
       VPSI             1002            37.95               38.13
    S_FWFFT             1091            37.65               37.75
   S_INVFFT             1095            36.25               38.53
      QINIT                1            10.51               10.51
    FNONLOC             1002             8.31                8.30
       SPSI             1001             5.24                5.17
     RNLSM1             1006             3.48                3.46
   FRIESNER                1             2.61                2.65
    VDBINIT                1             1.54                1.54
       RHOV                2             1.08                1.09
        HIP                2             1.06                1.08
       NEWD                2             1.01                1.01
       HPSI             1001             0.80                0.80
      ATRHO                1             0.62                0.63
    HOCKNEY                1             0.60                0.63
      FWFFT                8             0.47                0.46
 ----------------------------------------------------------------
 TOTAL TIME                            188.25              190.71
 ****************************************************************

       CPU TIME :    0 HOURS  3 MINUTES 10.52 SECONDS
   ELAPSED TIME :    0 HOURS  3 MINUTES 13.71 SECONDS

 PROGRAM CPMD ENDED AT:   Fri Sep 17 00:49:35 2004

3) KS energies with empty states

&CPMD
  RESTART DENSITY
  KOHN-SHAM ENERGIES
   2
  MAXSTEP
  150
  CENTER MOLECULE ON
&END


&DFT
  NEWCODE
  FUNCTIONAL LDA
  LDA CORRELATION PZ
  SLATER
    0.666667
  GC-CUTOFF
  0.1E-07
&END

&SYSTEM
  SYMMETRY
  0
  ANGSTROM
  CELL
    8.0  1.0  1.0  0  0  0
  CUTOFF SPHERICAL
    55.0
&END

&ATOMS
*O_VDB_LDA.psp FORMATTED
   LMAX=D LOC=D
   1
    0.000000    0.000000    0.000000
&END
 PROGRAM CPMD STARTED AT: Fri Sep 17 00:51:40 2004



               ******  ******    ****  ****  ******
              *******  *******   **********  *******
             ***       **   ***  ** **** **  **   ***
             **        **   ***  **  **  **  **    **
             **        *******   **      **  **    **
             ***       ******    **      **  **   ***
              *******  **        **      **  *******
               ******  **        **      **  ******

                          VERSION 3.9.1

                            COPYRIGHT
                      IBM RESEARCH DIVISION
                MPI FESTKOERPERFORSCHUNG STUTTGART

                       The CPMD consortium
                    WWW:   http://www.cpmd.org
                 Mailinglist:   cpmd-list at cpmd.org
                     E-mail:   cpmd at cpmd.org


                  ***  Aug 13 2004 -- 13:52:08  ***

 THE INPUT FILE IS:                                      o.inp-ks
 THIS JOB RUNS ON:
 THE CURRENT DIRECTORY IS:
                                            /home/eariel/mycpmd/O
 THE TEMPORARY DIRECTORY IS:
                                            /home/eariel/mycpmd/O
 THE PROCESS ID IS:                                          2546
 THE JOB WAS SUBMITTED BY:                                 eariel


 SINGLE POINT DENSITY OPTIMIZATION


 EXACT DIAGONALIZATION OF KOHN-SHAM MATRIX

 PATH TO THE RESTART FILES:                                    ./
 RESTART WITH OLD DENSITY
 GRAM-SCHMIDT ORTHOGONALIZATION
 MAXIMUM NUMBER OF STEPS:                                 1 STEPS
 MAXIMUM NUMBER OF ITERATIONS FOR SC:                     1 STEPS
 PRINT INTERMEDIATE RESULTS EVERY                     10001 STEPS
 STORE INTERMEDIATE RESULTS EVERY                     10001 STEPS
 STORE ELECTRONIC DENSITY IN RESTART FILE
 NUMBER OF DISTINCT RESTART FILES:                              1
 TEMPERATURE IS CALCULATED ASSUMING EXTENDED BULK BEHAVIOR
 TIME STEP FOR ELECTRONS:                                  5.0000
 TIME STEP FOR IONS:                                       5.0000
 CONVERGENCE CRITERIA FOR WAVEFUNCTION OPTIMIZATION:   1.0000E-03
 LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
    MAX. FRIESNER ITERATIONS                                  200
    MAX. KRYLOV SUBSPACE                                        6
    MAX. KRYLOV BLOCK SIZE       FIXED LATER (WAITING FOR NSTATE)
    MAX. BETA^2                                        1.0000E-08
 ANDERSON MIXING PARAMETER:                            2.0000E-01
 BROYDEN MIXING PARAMETER [BROYMIX]                    1.5000E-01
 BROYDEN CUTOFF [ECUTBROY]            EQUAL TO THE DENSITY CUTOFF
 BROYDEN MIXING STARTS [NFRBROY] AFTER                    0 STEPS
 BROYDEN MIXING RESET [IBRESET] AFTER                     8 STEPS
 BROYDEN MIXING W02                                    1.0000E-02
 ALEXANDER MIXING:                                         0.9000
 SPLINE INTERPOLATION IN G-SPACE FOR PSEUDOPOTENTIAL FUNCTIONS
    NUMBER OF SPLINE POINTS:                                 5000

 EXCHANGE CORRELATION FUNCTIONALS
    LDA EXCHANGE:                        SLATER (ALPHA = 0.66667)
    LDA CORRELATION:                              PERDEW & ZUNGER
       [J.P. PERDEW AND A ZUNGER, PRB 23 5048 (1981)]

 ***     DETSP| THE NEW SIZE OF THE PROGRAM IS    1940/  22060 kBYTES ***

 >>>>>>>> CENTER OF MASS HAS BEEN MOVED TO CENTER OF BOX <<<<<<<<


 ***************************** ATOMS ****************************
   NR   TYPE        X(bohr)        Y(bohr)        Z(bohr)     MBL
    1      O       7.558904       7.558904       7.558904       3
 ****************************************************************

 NUMBER OF STATES:                                              5
 NUMBER OF ELECTRONS:                                     6.00000
 CHARGE:                                                  0.00000
 ELECTRON TEMPERATURE(KELVIN):                            0.00000
 OCCUPATION
  2.0  2.0  2.0  0.0  0.0

 LANCZOS DIAGONALIZATION (KRYLOV SUBSPACE)
    MAX. KRYLOV BLOCK SIZE                                      5

   ============================================================
   |  pseudopotential report: version  7.3.4 date  6-12-2003  |
   ------------------------------------------------------------
   |  oxygen                    ceperley-alder exchange-corr  |
   |  z =   8.00  zv =   6.00  exfact =   0.00000             |
   |                            etot  = -31.51046             |
   |  index    orbital      occupation    energy              |
   |    1        200           2.00       -1.74               |
   |    2        210           4.00       -0.68               |
   |  keyps = 3     ifpcor = 0                                |
   |  rinner =      0.80     for L=    1                      |
   |  rinner =      0.80     for L=    2                      |
   |  rinner =      0.80     for L=    3                      |
   |    new generation scheme:                                |
   |    nbeta =  4     kkbeta =  507     rcloc =    1.0000    |
   |    ibeta     l     epsilon   rcut iptype                 |
   |       1      0      -1.74   1.10      2                  |
   |       2      0      -0.20   1.10      2                  |
   |       3      1      -0.80   1.10      2                  |
   |       4      1       0.20   1.10      2                  |
   |  npf    = 8  ptryc =  10.000                             |
   |  lloc   = 2  eloc   =   0.000                            |
   |  ifqopt = 2  nqf    = 8  qtryc =  10.000                 |
   |  all electron calculation used schroedinger equation     |
   |         ************logarithmic mesh************         |
   ============================================================

 ****************************************************************
 *   ATOM       MASS   RAGGIO NLCC              PSEUDOPOTENTIAL *
 *     O     15.9994   1.2000   NO              VANDERBILT      *
 ****************************************************************


 OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN
 NUMBER OF CPUS PER TASK                                        1
 OPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPENMPOPEN

 ***     RGGEN| THE NEW SIZE OF THE PROGRAM IS    8656/  36592 kBYTES ***

 ************************** SUPERCELL ***************************
 THIS IS AN ISOLATED SYSTEM CALCULATION
 POISSON EQUATION SOLVER  :                               HOCKNEY
 COULOMB SMOOTHING RADIUS :                                 1.080
 SYMMETRY:                                           SIMPLE CUBIC
 LATTICE CONSTANT(a.u.):                                 15.11781
 CELL DIMENSION:  15.1178  1.0000  1.0000  0.0000  0.0000  0.0000
 VOLUME(OMEGA IN BOHR^3):                              3455.14651
 LATTICE VECTOR A1(BOHR):           15.1178     0.0000     0.0000
 LATTICE VECTOR A2(BOHR):            0.0000    15.1178     0.0000
 LATTICE VECTOR A3(BOHR):            0.0000     0.0000    15.1178
 RECIP. LAT. VEC. B1(2Pi/BOHR):      0.0661     0.0000     0.0000
 RECIP. LAT. VEC. B2(2Pi/BOHR):      0.0000     0.0661     0.0000
 RECIP. LAT. VEC. B3(2Pi/BOHR):      0.0000     0.0000     0.0661
 REAL SPACE MESH:                    72           72           72
 WAVEFUNCTION CUTOFF(RYDBERG):                           55.00000
 DENSITY CUTOFF(RYDBERG):          (DUAL= 4.00)         220.00000
 NUMBER OF PLANE WAVES FOR WAVEFUNCTION CUTOFF:             11924
 NUMBER OF PLANE WAVES FOR DENSITY CUTOFF:                  95160
 NUMBER OF PLANE WAVES FOR BROYDEN MIXING:                  95160
 ****************************************************************

 ***  RINFORCE| THE NEW SIZE OF THE PROGRAM IS   19336/  48876 kBYTES ***
 ***    FFTPRP| THE NEW SIZE OF THE PROGRAM IS   30400/  50196 kBYTES ***
 ***   CLUSTER| THE NEW SIZE OF THE PROGRAM IS   34304/  53980 kBYTES ***

 GENERATE ATOMIC BASIS SET
      O        SLATER ORBITALS
        2S        ALPHA=   2.2458      OCCUPATION= 2.00
        2P        ALPHA=   2.2266      OCCUPATION= 4.00


 INITIALIZATION TIME:                               13.06 SECONDS

 ***    WFOPTS| THE NEW SIZE OF THE PROGRAM IS   34520/  63288 kBYTES ***
 RV30! NUMBER OF STATES   HAS CHANGED                      3    5
 RV30| WARNING! NO DENSITY INFORMATION

 RESTART INFORMATION READ ON FILE                       ./RESTART
 ***     PHFAC| THE NEW SIZE OF THE PROGRAM IS   34780/  92592 kBYTES ***
 ***    ATOMWF| THE NEW SIZE OF THE PROGRAM IS   34984/  94088 kBYTES ***
  ATRHO| WARNING! THE NUMBER OF GENERATED ATOMIC STATE (4)
  ATRHO| WARNING! IS LESS THAN THE NUMBER OF STATE (5)
  ATRHO| WARNING!     1 STATES ARE EQUAL TO ZERO
  ATRHO| USE SECTION BASIS TO SPECIFY ATOMIC BASIS
  ATRHO| CHARGE(R-SPACE):    6.000000      (G-SPACE):    6.000000
 ATOMWF| WARNING! RANDOMIZATION OF     1 STATES

 ****************************************************************
 *                      ATOMIC COORDINATES                      *
 ****************************************************************
       1       O           7.558904       7.558904       7.558904
 ****************************************************************

  !! WARNING FROM DETDOF: WHY IS GLIB LESS THAN UNITY !!
  !! WARNING FROM DETDOF: NOW IT IS SET EQUAL TO UNITY !!

 DEGREES OF FREEDOM FOR SYSTEM:                                 1

 CPU TIME FOR WAVEFUNCTION INITIALIZATION:           3.41 SECONDS
 ***    RWFOPT| THE NEW SIZE OF THE PROGRAM IS   65308/  92728 kBYTES ***
  EWALD| SUM IN REAL SPACE OVER                     1* 1* 1 CELLS

 <<<<<<<<<<<<<<<<<<< LANCZOS DIAGONALIZATION <<<<<<<<<<<<<<<<<<<<
 >> TIME FOR INITIAL SUBSPACE DIAGONALIZATION:               0.49
 >> CYCLE     NCONV        B2MAX        B2MIN     #HPSI      TIME
        1         0    1.561E-01    4.181E-02      6.00      2.38
        2         0    1.563E-01    5.488E-03      5.00      2.39
        3         0    6.679E-02    2.159E-03      5.00      2.40
        4         0    5.013E-02    7.902E-04      5.00      2.39
        5         0    2.733E-02    3.050E-04      5.00      2.40
        6         0    2.384E-02    9.732E-05      5.00      2.40
        7         0    1.440E-02    3.847E-05      5.00      2.39
        8         0    1.341E-02    1.197E-05      5.00      2.39
        9         0    8.518E-03    5.429E-06      5.00      2.40
       10         0    8.238E-03    1.632E-06      5.00      2.39
       11         0    5.415E-03    8.208E-07      5.00      2.40
       12         0    5.396E-03    2.484E-07      5.00      2.39
       13         0    3.645E-03    1.290E-07      5.00      2.40
       14         0    3.716E-03    3.949E-08      5.00      2.39
       15         0    2.562E-03    2.070E-08      5.00      2.39
       16         1    2.657E-03    8.884E-09      4.40      1.96
       17         1    1.860E-03    8.884E-09      4.00      1.65
       18         1    1.952E-03    8.884E-09      4.00      1.66
       19         1    1.380E-03    8.884E-09      4.00      1.65
       20         1    1.460E-03    8.884E-09      4.00      1.65
       21         1    1.040E-03    8.884E-09      4.00      1.66
       22         1    1.106E-03    8.884E-09      4.00      1.65
       23         1    7.907E-04    8.884E-09      4.00      1.65
       24         1    8.436E-04    8.884E-09      4.00      1.65
       25         1    6.049E-04    8.884E-09      4.00      1.66
       26         1    6.467E-04    8.884E-09      4.00      1.65
       27         1    4.645E-04    8.884E-09      4.00      1.65
       28         1    4.972E-04    8.884E-09      4.00      1.65
       29         1    3.575E-04    8.884E-09      4.00      1.66
       30         1    3.830E-04    8.884E-09      4.00      1.65
       31         1    2.755E-04    8.884E-09      4.00      1.65
       32         1    2.953E-04    8.884E-09      4.00      1.66
       33         1    2.125E-04    8.884E-09      4.00      1.65
       34         1    2.278E-04    8.884E-09      4.00      1.65
       35         1    1.640E-04    8.884E-09      4.00      1.65
       36         1    1.758E-04    8.884E-09      4.00      1.66
       37         1    1.265E-04    8.884E-09      4.00      1.65
       38         1    1.356E-04    8.884E-09      4.00      1.65
       39         1    9.766E-05    8.884E-09      4.00      1.65
       40         1    1.047E-04    8.884E-09      4.00      1.66
       41         1    7.538E-05    8.884E-09      4.00      1.65
       42         1    8.081E-05    8.884E-09      4.00      1.65
       43         1    5.818E-05    8.884E-09      4.00      1.66
       44         1    6.237E-05    8.884E-09      4.00      1.65
       45         1    4.491E-05    8.884E-09      4.00      1.65
       46         1    4.814E-05    8.884E-09      4.00      1.65
       47         1    3.466E-05    8.884E-09      4.00      1.66
       48         1    3.716E-05    8.884E-09      4.00      1.65
       49         1    2.675E-05    8.884E-09      4.00      1.65
       50         2    2.868E-05    8.884E-09      3.80      1.64
       51         2    2.065E-05    8.884E-09      3.00      1.58
       52         2    2.214E-05    8.884E-09      3.00      1.57
       53         2    1.594E-05    8.884E-09      3.00      1.57
       54         2    1.709E-05    8.884E-09      3.00      1.58
       55         2    1.230E-05    8.884E-09      3.00      1.57
       56         2    1.319E-05    8.884E-09      3.00      1.57
       57         2    9.497E-06    8.884E-09      3.00      1.57
       58         2    1.018E-05    8.884E-09      3.00      1.58
       59         2    7.330E-06    8.884E-09      3.00      1.57
       60         2    7.860E-06    8.884E-09      3.00      1.58
       61         2    5.658E-06    8.884E-09      3.00      1.57
       62         2    6.067E-06    8.884E-09      3.00      1.58
       63         2    4.368E-06    8.884E-09      3.00      1.57
       64         2    4.684E-06    8.884E-09      3.00      1.58
       65         2    3.372E-06    8.884E-09      3.00      1.57
       66         2    3.616E-06    8.884E-09      3.00      1.57
       67         2    2.603E-06    8.884E-09      3.00      1.57
       68         2    2.791E-06    8.884E-09      3.00      1.57
       69         2    2.009E-06    8.884E-09      3.00      1.58
       70         2    2.155E-06    8.884E-09      3.00      1.57
       71         2    1.551E-06    8.884E-09      3.00      1.57
       72         2    1.664E-06    8.884E-09      3.00      1.57
       73         2    1.198E-06    8.884E-09      3.00      1.58
       74         2    1.284E-06    8.884E-09      3.00      1.57
       75         2    9.245E-07    8.884E-09      3.00      1.58
       76         3    9.915E-07    8.884E-09      2.40      1.13
       77         3    7.137E-07    8.884E-09      2.00      0.83
       78         3    7.655E-07    8.884E-09      2.00      0.84
       79         3    5.511E-07    8.884E-09      2.00      0.83
       80         3    5.910E-07    8.884E-09      2.00      0.83
       81         3    4.254E-07    8.884E-09      2.00      0.83
       82         3    4.563E-07    8.884E-09      2.00      0.83
       83         3    3.285E-07    8.884E-09      2.00      0.84
       84         3    3.523E-07    8.884E-09      2.00      0.83
       85         3    2.536E-07    8.884E-09      2.00      0.83
       86         3    2.721E-07    8.884E-09      2.00      0.84
       87         3    1.958E-07    8.884E-09      2.00      0.83
       88         3    2.101E-07    8.884E-09      2.00      0.83
       89         3    1.512E-07    8.884E-09      2.00      0.84
       90         3    1.622E-07    8.884E-09      2.00      0.83
       91         3    1.167E-07    8.884E-09      2.00      0.84
       92         3    1.252E-07    8.884E-09      2.00      0.83
       93         3    9.014E-08    8.884E-09      2.00      0.83
       94         3    9.671E-08    8.884E-09      2.00      0.84
       95         3    6.960E-08    8.884E-09      2.00      0.83
       96         3    7.468E-08    8.884E-09      2.00      0.84
       97         3    5.374E-08    8.884E-09      2.00      0.83
       98         3    5.766E-08    8.884E-09      2.00      0.83
       99         3    4.150E-08    8.884E-09      2.00      0.84
      100         3    4.453E-08    8.884E-09      2.00      0.83
      101         3    3.204E-08    8.884E-09      2.00      0.83
      102         3    3.439E-08    8.884E-09      2.00      0.84
      103         3    2.474E-08    8.884E-09      2.00      0.84
      104         3    2.655E-08    8.884E-09      2.00      0.83
      105         3    1.911E-08    8.884E-09      2.00      0.83
      106         3    2.050E-08    8.884E-09      2.00      0.83
      107         5    9.530E-09    8.884E-09      0.80      0.35

 EIGENVALUES(EV) AND OCCUPATION:
     1    -11.2781946     2.000        2     -0.3815193     2.000
     3     -0.2300328     2.000        4      0.7065208     0.000
     5      0.7065390     0.000
 CHEMICAL POTENTIAL =                            -0.2300326449 EV

 TOTAL INTEGRATED ELECTRONIC DENSITY
    IN G-SPACE =                                         6.034344
    IN R-SPACE =                                         6.034344


 VANDERBILT AUGMENTATION CHARGES (MEAN VALUE PER ATOM)
 ATOM TYPE    NR. OF ATOMS        CHARGE
       O           1               0.034

 (B+E2+X-V)             TOTAL ENERGY =          -16.96050918 A.U.
 (B)                     BAND ENERGY =           -0.87386055 A.U.
 (E2=I-H-S+R)   ELECTROSTATIC ENERGY =          -17.33584728 A.U.
 (S)                           ESELF =           11.96826841 A.U.
 (R)                             ESR =            0.00000000 A.U.
 (X)     EXCHANGE-CORRELATION ENERGY =           -3.99099801 A.U.
 (V)     EXCHANGE-CORRELATION POTEN. =           -5.24019667 A.U.

 ==------------------------------------------------------------==
 ==     NFI=      1      ETOT=    -16.960509   TCPU=    162.84 ==
 == DRHOMAX= 1.439E-01  DETOT=     0.000E+00    THL= 0.000E+00 ==
 ==------------------------------------------------------------==

 RESTART INFORMATION WRITTEN ON FILE                  ./RESTART.1
 ***    RWFOPT| THE NEW SIZE OF THE PROGRAM IS   78992/  98804 kBYTES ***

 ****************************************************************
 *                                                              *
 *                        FINAL RESULTS                         *
 *                                                              *
 ****************************************************************

 ****************************************************************
 *                      ATOMIC COORDINATES                      *
 ****************************************************************
       1       O           7.558904       7.558904       7.558904
 ****************************************************************


 EIGENVALUES(EV) AND OCCUPATION:
     1    -11.2781946     2.000        2     -0.3815193     2.000
     3     -0.2300328     2.000        4      0.7065208     0.000
     5      0.7065390     0.000
 CHEMICAL POTENTIAL =                            -0.2300326449 EV

 ****************************************************************


 ELECTRONIC GRADIENT:
    MAX. COMPONENT =    1.43915E-01         NORM =    6.89928E+00

 TOTAL INTEGRATED ELECTRONIC DENSITY
    IN G-SPACE =                                         6.034344
    IN R-SPACE =                                         6.034344


 VANDERBILT AUGMENTATION CHARGES (MEAN VALUE PER ATOM)
 ATOM TYPE    NR. OF ATOMS        CHARGE
       O           1               0.034

 (B+E2+X-V)             TOTAL ENERGY =          -16.96050918 A.U.
 (B)                     BAND ENERGY =           -0.87386055 A.U.
 (E2=I-H-S+R)   ELECTROSTATIC ENERGY =          -17.33584728 A.U.
 (S)                           ESELF =           11.96826841 A.U.
 (R)                             ESR =            0.00000000 A.U.
 (X)     EXCHANGE-CORRELATION ENERGY =           -3.99099801 A.U.
 (V)     EXCHANGE-CORRELATION POTEN. =           -5.24019667 A.U.

 ****************************************************************


 ================================================================
                      BIG MEMORY ALLOCATIONS
 SCR              1576657                PSI              1556068
 QRL               903600                YLMB              856440
 YF                778034                XF                778034
 PME               715440                SCR               613400
 RHOE              389017                HGPOT             389017
 ----------------------------------------------------------------
 [PEAK NUMBER   92]      PEAK MEMORY      9977414 =   79.8 MBytes
 ================================================================


 ****************************************************************
 *                                                              *
 *                            TIMING                            *
 *                                                              *
 ****************************************************************
 SUBROUTINE            CALLS         CPU TIME        ELAPSED TIME
    FFT-G/S             3972            35.52               35.46
       VPSI              534            33.82               33.85
    S_FWFFT              991            33.41               33.52
   S_INVFFT              995            32.97               32.92
    FNONLOC              534            11.30               11.34
      QINIT                1            10.55               10.55
       SPSI              533             5.33                5.38
     RNLSM1              538             3.45                3.43
   FRIESNER                1             3.23                3.24
    VDBINIT                1             1.41                1.41
       RHOV                2             1.08                1.07
       HPSI              533             1.03                1.01
        HIP                2             1.02                1.03
       NEWD                2             0.98                0.98
    HOCKNEY                1             0.66                0.67
      ATRHO                1             0.57                0.59
      FWFFT                8             0.45                0.46
     OVLAP2              110             0.45                0.42
     INVFFT                7             0.40                0.40
 ----------------------------------------------------------------
 TOTAL TIME                            177.63              177.74
 ****************************************************************

       CPU TIME :    0 HOURS  2 MINUTES 59.40 SECONDS
   ELAPSED TIME :    0 HOURS  3 MINUTES  1.25 SECONDS

 PROGRAM CPMD ENDED AT:   Fri Sep 17 00:54:41 2004

Other options that I have tried:

&CPMD
  OPTIMIZE WAVEFUNCTION
  #  PCG MINIMIZE
  #  TIMESTEP
  #   5
  RESTART ALL
  LANCZOS DIAGONALISATION ALL

  &DFT
  GC-CUTOFF
    0.1E-05  # Sugeted for ultrasoft PP

 POISSON SOLVER TUCKERMAN

What is wrong?

Thank you

Eduardo A. Menendez Proupin
Department of Physics
Faculty of Science
University of Chile
Las Palmeras 3425
Ñuñoa, Santiago
Chile
Phone: 56+2+678 74 11
http://fisica.ciencias.uchile.cl/~emenendez/




More information about the CPMD-list mailing list